Consider the reaction 2 SO2(g) + O2(g) <=> 2 SO3(g), which is exothermic as written. What would be the effect on the equilibrium position of removing O2(g)?

Answers

Answer 1

Answer:

Removing O₂, means removing one of the reactants and the system would counteract this effect by producing more O₂, thereby shifting the equilibrium position to the left and favouring the backward reaction.

Explanation:

The principle that explains how changes in temperature, Concentration and Pressure of reactants or products of a reaction at equilibrium affect the equilibrium position of the reaction is the Le Chatelier's principle.

The Principle explains that a system/process if a system/process which is at equilibrium is disturbed/perturbed/constrained by one or more changes (in concentration, pressure or temperature), the system would shift the equilibrium position to counteract the effects of this change.

Removing O₂, means removing one of the reactants (changing its concentration) and the system would counteract this effect by producing more O₂, thereby shifting the equilibrium position to the left and favouring the backward reaction.

Answer 2

Final answer:

Removing O₂(g) from the equilibrium of the exothermic reaction 2 SO₂(g) + O₂(g) <=> 2 SO₃(g) shifts the equilibrium towards the reactants' side, increasing the concentration of SO₂(g) and decreasing the concentration of SO₃(g).

Explanation:

The question revolves around the effect of removing O₂(g) from the equilibrium system of the reaction 2 SO₂(g) + O₂(g) ⇌ 2 SO₃(g), which is exothermic. According to Le Châtelier's Principle, when a change is made to a system in equilibrium, the system adjusts to counteract that change. In this case, removing O₂(g) (oxygen) would decrease its concentration, prompting the equilibrium to shift towards the reactants' side to increase the concentration of O₂(g) and restore equilibrium. This means that the concentration of SO₂(g) will increase, and the concentration of SO₃(g) will decrease as the reaction shifts left to form more reactants.


Related Questions

Quantum numbers arise naturally from the mathematics used to describe the possible states of an electron in an atom. The four quantum numbers, the principal quantum number (n), the angular momentum quantum number (????), the magnetic quantum number (m????), and the spin quantum number (ms) have strict rules which govern the possible values. Identify all allowable combinations of quantum numbers for an electron.
Select all that apply.

a) n= 3 l= -2 ml=-1 ms= +1/2
b) n=3 l= 2 ml= -1 ms= -1/2
c) n= 4 l=4 ml=-1 ms= +1/2
d) n=2 l=1 ml=-1 ms=1
e) n=4 l=1 ml=2 ms=-1/2
f) n=5 l=4 ml=4 ms=+1/2

Answers

Answer:

a), b), c) & f)

Explanation:

d) does not apply because Ms value can be either +½ or -½

e) does not apply because Ml - values range from -l to +l, hence l= 2 doesn't exist when l= 1

Final answer:

The four quantum numbers that govern the possible states of an electron in an atom are the principal quantum number (n), the angular momentum quantum number (l), the magnetic quantum number (ml), and the spin quantum number (ms). Allowable combinations of quantum numbers follow specific rules.

Explanation:

The four quantum numbers that govern the possible states of an electron in an atom are the principal quantum number (n), the angular momentum quantum number (l), the magnetic quantum number (ml), and the spin quantum number (ms).

Allowable combinations of quantum numbers for an electron can be determined according to the following rules:

The principal quantum number (n) can have values of 1, 2, 3, etc.The angular momentum quantum number (l) can have values from 0 to (n - 1).The magnetic quantum number (ml) can have values from -l to +l, including zero.The spin quantum number (ms) can have values of +1/2 or -1/2.

Acetic acid, ethanol, acetaldehyde and ethane form a series of 2-carbon molecules which differ in their extent of oxidation. Convert ethanol to the next more reduced form in that ordered series. HelpMarvin JS

Answers

[tex]CH_3CH_2OH[/tex]  →  [tex]CH_3CHO[/tex]

Explanation:

Ethanol can be oxidized to ethanal or acetaldehyde which is further oxidized to acid that is acetic acid.

[tex]CH_3CH_2OH[/tex]→  [tex]CH_3CHO[/tex] [oxidation by loss of hydrogen]

An oxidizing agent potassium dichromate(VI) solution is used to remove the hydrogen from the ethanol.  An oxidizing agent used along with dilute sulphuric acid for acidification.

Acetaldehyde can also be reduced back to ethanol again by adding hydrogen to it by using a reducing agent that is sodium tetrahydro borate, NaBH4.

The oxidation of aldehydes to carboxylic acids can be done by the two-step process.  In the first step, one molecule of water is added in the presence of a catalyst that is acidic. There is a generation of a hydrate. (geminal 1,1-diol).

     [tex]CH_3CHO[/tex]  →  [tex]CH_3CH_2COOH[/tex] [reduction by the gain of electrons]

Here, the oxidizing agent used is[tex]Cr_3O[/tex] in the presence of acetone.

Final answer:

To convert ethanol to the next more reduced form in the series, it will form an aldehyde called acetaldehyde.

Explanation:

To convert ethanol to the next more reduced form in the series, we need to consider the oxidation level of the molecules. Ethanol is an alcohol with the -OH group bonded to a carbon atom attached to two other carbon atoms, which means it will form an aldehyde upon oxidation. Acetaldehyde is the next more reduced form in the series. Acetaldehyde has a carbonyl group (C=O) instead of an -OH group.

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A mixture of hydrochloric and sulfuric acids is prepared so that it contains 0.315 M HCl and 0.125 M H2SO4. What volume of 0.55 M NaOH would be required to completely neutralize all of the acid in 503.4 mL of this solution?




hints

involves a solution that has 2 different acids in it. One way to do this is to imagine that you are neutralizing 2 solutions, one of each acid, and then just add the amounts of base needed. Another way is to think about how many moles of H3O+ are present in the mixed acids, and then figure out how much of the basic solution is needed to react with that amount of H3O+.

Answers

Answer: The volume of NaOH required is 402.9 mL

Explanation:

To calculate the number of moles for given molarity, we use the equation:

[tex]\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}[/tex]     .....(1)

For HCl:

Molarity of HCl solution = 0.315 M

Volume of solution = 503.4 mL = 0.5034 L   (Conversion factor: 1 L = 1000 mL)

Putting values in equation 1, we get:

[tex]0.315M=\frac{\text{Moles of HCl}}{0.5034L}\\\\\text{Moles of HCl}=(0.315mol/L\times 0.5034L)=0.1586mol[/tex]

For sulfuric acid:

Molarity of sulfuric acid solution = 0.125 M

Volume of solution = 503.4 mL = 0.5034 L

Putting values in equation 1, we get:

[tex]0.125M=\frac{\text{Moles of }H_2SO_4}{0.5034L}\\\\\text{Moles of }H_2SO_4=(0.125mol/L\times 0.5034L)=0.0630mol[/tex]

As, all of the acid is neutralized, so moles of NaOH = [0.1586 + 0.0630] moles = 0.2216 moles

Molarity of NaOH solution = 0.55 M

Moles of NaOH = 0.2216 moles

Putting values in equation 1, we get:

[tex]0.55M=\frac{0.2216}{\text{Volume of solution}}\\\\\text{Volume of solution}=\frac{0.2216}{0.55}=0.4029L=402.9mL[/tex]

Hence, the volume of NaOH required is 402.9 mL

Aqueous hydrochloric acid reacts with solid sodium hydroxide to produce aqueous sodium chloride and liquid water what is the terorectical yield of water formed from the reaction of 3.3 g of hydrocloric acid and 6.6g of sodium hydroxide?

Answers

Answer:

1.63 g of H₂O is the theoretical yield

Explanation:

We determine the reactants for the reaction:

HCl, NaOH

We determine the products for the reaction:

H₂O, NaCl

The equation for this neutralization reaction is:

HCl (aq) + NaOH(aq) → NaCl(aq) + H₂O(l)

We use both masses, from both reactants to determine the limiting.

First, we convert the mass to moles.

3.3 g . 1mol / 36.45 g = 0.090 moles of HCl

6.6 g . 1mol / 40 g = 0.165 moles of NaOH

Ratio is 1:1, so for 0.165 moles of hydroxide I need the same amount of acid. I have 0.090 HCl so the acid is the limiting reagent.

Let's work with stoichiometry. Ratio is 1:1, again.

1 mol of acid can produce 1 mol of water

Therefore, 0.090 moles of acid must produce 0.090 moles of H₂O

We convert the moles to mass, to define the theoretical yield

0.090 mol . 18g / 1 mol = 1.63 g

Answer:

The theoretical yield of H2O is 1.63 grams

Explanation:

Step 1: Data given

Mass of hydrochloric acid = 3.3 grams

Mass of sodium hydroxide = 6.6 grams

Molar mass hydrochloric acid (HCl) = 36.46 g/mol

Molar mass sodium hydroxide (NaOH) = 40.0 g/mol

Step 2: The balanced equation

HCl + NaOH → NaCl + H2O

Step 3: Calculate moles

Moles = mass / molar mass

Moles HCl = 3.3 grams / 36.46 g/mol

Moles HCl = 0.0905 moles

Moles NaOH = 6.6 grams / 40.0 g/mol

Moles NaOH = 0.165 moles

Step 4: Calculate the limiting reactant

HCl is the limiting reactant. There will react 0.0905 moles. NaOH is in excess. There will react 0.0905 moles moles. There will remain 0.165 - 0.0905 = 0.0745 moles

Step 5: Calculate moles H2O

For 1 mol HCl we need 1 mol NaOH to produce 1 mol NaCl and 1 mol H2O

For 0.0905 moles HCl we'll have 0.0905 moles H2O

Step 6: Calculate mass H2O

Mass H2O = moles * molar mass

Mass H2O = 0.0905 * 18.02 g/mol

Mass H2O = 1.63 grams

The theoretical yield of H2O is 1.63 grams

A solution of sodiumhydroxide (NaOH) was standardized against potassium hydrogenphthalate (KHP). A known mass of KHP was titrated with
the NaOH solution until a light pink color appeared usingphenolpthalein indicator. Using the volume of NaOH requiredto neutralize KHP and the
number of moles of KHP titrated, the concentration of the NaOHsolution was calculated.
A vinegar (acetic acid) solution of unknown concentration wastitrated to the light pink endpoint with the standardized NaOHsolution. The
molarity and weight\volume % of the vinegar solution werecalculated.
A vitamin C (ascorbic acid) tablet was dissolved in approximately50 mL of distilled water and titrated with the standardized NaOHsolution. From
the results of this titration, the mg of ascorbic acid in thetablet was calculated.

Molecular formulas:

Potassium hydrogen phthalate: HKC8H4O4
Acetic acid: C2H4O2
Ascorbic acid: C6H8O6
Assume that all 3 acids are monoprotic acids.
Mass of KHP used forstandardization (g) 0.5591
Volume of NaOH required to neutralize KHP (mL) 13.39
Volume of vinegar sample titrated (mL) 5.00
Volume of NaOH required to neutralize vinegar in(mL) 8.38
Molecular weight of ascorbic acid (g/mol) 176.1271
Volume of NaOH required to neutralize ascorbic acid in Vitamin Ctablet (mL) 13.56

Calculate thefollowing

A. What is the Molecular Weight of KHP (HKC8H4O4) in g/mol?
B. How many moles of KHP were used in the standardization of theNaOH solution?
C. Calculate the concentration of NaOH solution in (mol/L).
D. Calculate the molarity of the vinegar solution (mol/L).
E. Calculate the weight/volume percentage of the vinegar solution(g/100 mL).
F. Calculate the amount of ascorbic acid in the Vitamin C tablet in(mg).

Answers

Answer:

See explanation below

Explanation:

In order to solve this, we'll do it by parts, as this exercise takes some time to solve it, however, the procedure it's pretty easy to understand.

A. Molecular weight of the KHP

To do this, we need the atomic weight of each element of the KHP. These are the following:

H = 1 g/mol; K = 39 g/mol; C = 12 g/mol; O = 16 g/mol

Now, let's calculate the molecular weight. Remember to multiply the number of atoms by the atomic weight:

MM KHP = (1*5) + (39) + (4*16) + (12*8) = 204 g/mol

B. moles of KHP used

In this part, we already have the molecular weight, so, we can calculate the moles with the expression:

n = m/MM  (1)

The mass used of KHP is 0.5591 so the moles are:

n = 0.5591/204 = 2.74x10⁻³ moles

C. Concentration of NaOH

As the problem states, the KHP can be considered as a monoprotic acid, therefore, we can assume that the mole ratio between NaOH and KHP is 1:1 and we can use the following expression to calculate the concentration of the base:

MaVa = MbVb  (2)

But moles:

n = M*V  (3)

We have the moles of the KHP used, and the volume used to standarize the base, so we can solve for Molarity of the base:

Mb = na / Vb

Mb = 2.74x10⁻³ / 0.01339 = 0.2046 M

D. Molarity of vinegar solution

Using expression (2), we can calculate the vinegar solution, as we have the base volume used and volume of vinegar so:

MaVa = MbVb

Ma = MbVb/Va

Ma = 0.2046 * 8.38 / 5 = 0.3429 M

E. %W/V of vinegar

In this case, we use the following expression:

%W/V = mass solute / V solution * 100   (4)

The volume of solution would be the volume of the vinegar and volume of the base:

V solution = 8.38 + 5 = 13.38 mL

The mass of vinegar can be calculated, we have the concentration and volume, we can calculate the moles using expression (3):

n = 0.3429 * 0.005 = 1.71x10⁻³ moles

The mass of vinegar using the molecular weight of acetic acid (60 g/mol):

m = 1.71x10⁻³ * 60 = 0.1026 g

So the %:

%W/V = 0.1026/13.38 * 100 = 0.77%

F.  mg of ascorbic acid

We do the same thing as in part C and then, the mass of ascorbic acid can be calculated with the molecular weight:

MaVa = MbVb = na

na = 0.2046 * 0.01356 = 2,77x10⁻³  moles

m = 2.77x10⁻³ * 176.1271 = 0.4878 g or simply 487.8 mg

A) The Molecular Weight of KHP is 204.23 g/mol. B). Moles of KHP were used in the standardization of the NaOH solution .C) The concentration of NaOH is 0.2045 mol/L. D). The vinegar solution's molarity is 0.3426 mol/L, and E).it has a weight/volume percentage of 2.06%, while F). the Vitamin C tablet contains 487 mg of ascorbic acid.

Let's go step by step to find each required value:

A. The Molecular Weight of KHP (HKC₈H₄O₄) in g/mol :

The molecular formula of KHP (Potassium hydrogen phthalate) is HKC₈H₄O₄. Thus:

K: 39.10 g/molH₅: 5 × 1.01 g/mol = 5.05 g/molC₈: 8 × 12.01 g/mol = 96.08 g/molO₄: 4 × 16.00 g/mol = 64.00 g/mol

Adding these values gives us the Molecular Weight of KHP: 204.23 g/mol.

B. Moles of KHP were used in the standardization of the NaOH solution :

Moles of KHP = Mass of KHP / Molecular Weight of KHP

                       = 0.5591 g / 204.23 g/mol

                       = 0.002737 moles

                       = 2.74x10⁻³ moles

C. The concentration of NaOH solution in (mol/L) :

Molarity (M) = Moles of Solute / Volume of Solution in L
Volume of NaOH in L = 13.39 mL × (1 L / 1000 mL) = 0.01339 L
Thus, Molarity of NaOH = 0.002737 moles / 0.01339 L

                                       = 0.2045 mol/L

D. The molarity of the vinegar solution (mol/L) :

Firstly, we know the mole ratio between acetic acid (CH₃COOH) and NaOH is 1:1.
Moles of NaOH used for vinegar = Molarity of NaOH × Volume in L

                                                       = 0.2045 mol/L × 0.00838 L

                                                        = 0.001713 moles

Since it’s a 1:1 ratio, the moles of acetic acid (CH₃COOH) in the vinegar is 0.001713 moles
Molarity of vinegar = Moles of Acetic Acid / Volume of Vinegar Solution in L
Molarity of Vinegar = 0.001713 moles / 0.005 L

                                = 0.3426 mol/L

E. The weight/volume percentage of the vinegar solution (g/100 mL) :

Weight of Acetic Acid (CH₃COOH) in grams = Moles × Molecular Weight

                                     =  0.001713 moles × 60.05 g/mol = 0.1029 g
Since the vinegar sample was 5.00 mL, weight/volume %

                                     = (0.1029 g / 5.00 mL) × 100 = 2.06%

F) . The amount of ascorbic acid in the Vitamin C tablet in (mg) :

Moles of NaOH used = Molarity of NaOH × Volume in L

                                    = 0.2045 mol/L × 0.01356 L = 0.002774 moles
Since mole ratio between ascorbic acid and NaOH is 1:1, moles of ascorbic acid = 0.002774 moles
Mass of ascorbic acid = Moles × Molecular Weight = 0.002774 moles × 176.1271 g/mol = 0.487 grams
Thus, mass in mg = 0.487 g × 1000 = 487 mg

Determine if each of the statements is True or False regarding the First Law of Thermodynamics.
1. If the system loses energy to the surroundings, the surroundings could also lose energy to the system.
2. If the system gains thermal energy from the surroundings, the temperature of the surroundings decreases.
3 If the system gains 25 kJ of energy from the surroundings without doing any work on the surroundings, the surroundings could lose 20 kJ of energy.

Answers

Answer:

1. False, 2. True, 3. False.

Explanation:

1. False, if the system loses energy to the surroundings, the surroundings receive such energy.

[tex]\Delta U_{sys}<0[/tex]

[tex]\Delta U_{sys} + \Delta U_{surr} = 0[/tex]

[tex]\Delta U_{sys} = -\Delta U_{surr}[/tex]

[tex]\Delta U_{surr}>0[/tex]

2. True, if the system gains more thermal energy, the temperature of the surroundings decreases.

[tex]Q_{sys} = \Delta U_{sys}, Q_{sys}>0\\Q_{surr} =\Delta U_{surr}\\\Delta U_{sys} = -\Delta U_{surr}\\Q_{sys} =-Q_{surr}\\C_{sys} \cdot \Delta T_{sys} = - C_{surr} \cdot \Delta T_{surr}\\\Delta T_{sys}>0,\Delta T_{surr}<0[/tex]

3. False. The surroundings could lose 25 kJ of energy.

1. When the system loses energy, the surrounding should receive the energy. So, it is false.

2. When the system gains thermal energy so the temperature should increase. So, it is true.

3. The surrounding should lose 25 kJ of energy. So, it is false.

First Law of Thermodynamics:

a. When the system loses energy, the surrounding should receive the energy. So, it is false.

Like

[tex]\Delta U_{sys} <0\\\\\Delta U_{sys} + \Delta _{surr} = 0\\\\\Delta U_{sys} = -DeltaU_{surr}\\\\DeltaU_{surr} >0[/tex]

b. When the system gains thermal energy so the temperature should increase. So, it is true.

[tex]Q_{sys} = \Delta U_{sys}, Q_{sys}>0\\\\Q_{sys} = \Delta U_{surr}\\\\\Delta U_{sys} = - \Delta U_{surr}\\\\Q_{sys} = -Q{surr}\\\\C_{sys}.\Delta T_{sys} = -C_{surr}.\Delta T_{surr}\\\\\Delta T_{sys}>0,\Delta T_{surr}<0[/tex]

3. The surrounding should lose 25 kJ of energy. So, it is false.

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A 30.0-mL sample of an unknown strong base is neutralized after the addition of 12.0 mL of a 0.150 M HNO3 solution. If the unknown base concentration is 0.0300 M, give some possible identities for the unknown base.

Answers

The question is incomplete, here is the complete question:

A 30.0-mL sample of an unknown strong base is neutralized after the addition of 12.0 mL of a 0.150 M HNO₃ solution. If the unknown base concentration is 0.0300 M, give some possible identities for the unknown base.  (Select all that apply)

A.)  Ca(OH)₂

B.)  LiOH

C.)  Sr(OH)₂

D.)  Al(OH)₃

E.)  NaOH

F.)  Ba(OH)₂

Answer: The unknown base could be [tex]Ca(OH)_2,Sr(OH)_2\text{ or }Ba(OH)_2[/tex]

Explanation:

To calculate the number of moles for given molarity of solution, we use the equation:

       .......(1)

For nitric acid:

Molarity of solution = 0.150 M

Volume of solution = 12.0 mL

Putting values in equation 1, we get:

[tex]0.150M=\frac{\text{Moles of nitric acid}\times 1000}{12.00}\\\\\text{Moles of nitric acid}=\frac{0.150\times 12.00}{1000}=1.8\times 10^{-3}moles[/tex]

For unknown base:

Molarity of solution = 0.0300 M

Volume of solution = 30.0 mL

Putting values in equation 1, we get:

[tex]0.0300M=\frac{\text{Moles of unknown base}\times 1000}{30.00}\\\\\text{Moles of unknown base}=\frac{0.0300\times 30.00}{1000}=0.9\times 10^{-3}moles[/tex]

Mole ratio of acid and base is calculated as: [tex]\frac{\text{Moles of unknown base}}{\text{Moles of nitric acid}}=\frac{0.9\times 10^{-3}}{1.8\times 10^{-3}}=\frac{2}{1}[/tex]

Number of [tex]OH^-[/tex] = 2 × number of [tex]H^+[/tex] ions

So, the unknown base is diprotic in nature.

Hence, the unknown base could be [tex]Ca(OH)_2,Sr(OH)_2\text{ or }Ba(OH)_2[/tex]

Final answer:

The unknown base could be a strong base such as sodium hydroxide (NaOH), potassium hydroxide (KOH), barium hydroxide (Ba(OH)2), or calcium hydroxide (Ca(OH)2), as these compounds release two hydroxide ions per molecule.

Explanation:

To find the possible identities of the unknown strong base, we first need to understand the neutralization process which involves the reaction of an acid and a base to produce water and salts.

The neutralization reaction is given by: HNO3 + BOH -> H2O + BNO3 where B is the cation from the unknown base. From the stoichiometry of the reaction, we can see that 1 mole of HNO3 reacts with 1 mole of the unknown base.

The number of moles of HNO3 = volume (in L) x molarity = 0.012 L x 0.150 mol/L = 0.0018 mol. So, the number of moles of the unknown base would also be 0.0018 mol.

The molarity of the unknown base = number of moles / volume (in L) = 0.0018 mol / 0.030 L = 0.060 M. But the problem states that the concentration of the unknown base is 0.030 M, which means for every molecule of base, there are two hydroxide ions.

Therefore, the unknown base could be a strong base such as sodium hydroxide (NaOH), potassium hydroxide (KOH), barium hydroxide (Ba(OH)2), or calcium hydroxide (Ca(OH)2), etc., which are all examples of sets of strong bases that release two hydroxide ions per molecule.

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Insert the IF statement in cell I9 to determine if the % Down is greater than or equal to 20% Down Pmt Rate. If true, the PMI is 0. If false, the PMI is calculated by multiplying the Amount Financed by the PMI Rate divided by the # of Pmts Per Year. The function should be =IF(E9>=$B$7,0,D9*$B$6/$B$5).

Answers

Final answer:

To address a conditional situation in Excel, you would use the IF function. In this case, the asked function is =IF(E9>=$B$7, 0, D9*$B$6/$B$5), wherein a condition is evaluated and if true, returns 0, if false, conducts a specified calculation.

Explanation:

The question asked is about using the IF statement in Excel, which falls under the Computers and Technology topic. Excel's IF function is used to create conditional statements, where different calculations can be performed depending on whether a particular condition is met.

For the given question, you are asked to insert the IF function in cell I9. The condition to test is if the value in cell E9 is greater than or equal to the value in cell B7. If this condition is true, the function will return 0. If the condition is not met, the function will execute a calculation: it multiplies the values in cells D9 and B6, then divides the result by the value in cell B5.

Your final function should look like this: =IF(E9>=$B$7,0,D9*$B$6/$B$5).

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Ammonia will decompose into nitrogen and hydrogen at high temperature. An industrial chemist studying this reaction fills a 7.50 l tank with 29.0 mol of ammonia gas at 35.0 °C. She then raises the temperature, and when the mixture has come to equilibrium measures the amount of nitrogen gas to be 13.0 mol.
Calculate the concentration equilibrium constant for the decomposition of ammonia at the final temperature of the mixture. Round your answer to significant digits.

Answers

Answer: The equilibrium constant for the reaction is 2.47

Explanation:

We are given:

Initial moles of ammonia gas = 29.0 moles

Equilibrium moles of nitrogen gas = 13.0 moles

Volume of the tank = 7.50 L

Molarity is calculated by using the formula:

[tex]\text{Molarity}=\frac{\text{Number of moles}}{\text{Volume of tank}}[/tex]

[tex]\text{Initial molarity of ammonia}=\frac{29.0}{7.50}=3.87M[/tex]

[tex]\text{Equilibrium molarity of nitrogen gas}=\frac{13.0}{7.50}=1.73M[/tex]

The chemical equation for the decomposition of ammonia follows:

                      [tex]2NH_3\rightleftharpoons N_2+3H_2[/tex]

Initial:             3.87

At eqllm:       3.87-2x    x      3x

Evaluating the value of 'x'

[tex]\Rightarrow 3x=1.73\\\\x=\frac{1.73}{3}=0.577[/tex]

So, equilibrium concentration of ammonia = (3.87 - 2x) = [3.87 - 2(0.577)] = 2.716 M

Equilibrium concentration of nitrogen gas = x = 0.577 M

The expression of [tex]K_{eq}[/tex] for above equation follows:

[tex]K_{eq}=\frac{[N_2][H_2]^3}{[NH_3]^2}[/tex]

Putting values in above equation, we get:

[tex]K_{eq}=\frac{(2.716)^2}{0.577\times (1.73)^3}\\\\K_{eq}=2.47[/tex]

Hence, the equilibrium constant for the reaction is 2.47

A solution contains 35 g of NaCl per 100 g of water at 25 ∘C. Is the solution unsaturated, saturated, or supersaturated?

Answers

Final answer:

The solution described is saturated as it contains NaCl at a concentration equal to its solubility at 25°C, meaning water has dissolved the maximal amount of NaCl it can at that temperature.

Explanation:

The solution you've described is a saturated solution, as it contains NaCl at a concentration equal to its solubility at a given temperature, in this case 25°C. This means that the water has dissolved as much sodium chloride as it can at this temperature, and any additional NaCl would not dissolve.

A supersaturated solution, on the other hand, is a solution that contains more solute than is possible under stable equilibrium conditions. This state is achieved by adding excess solute, or by evaporation of the solvent. A supersaturated solution is unstable, and will return to its saturation point upon disturbance, causing the excess solute to precipitate out.

Lastly, an unsaturated solution contains less solute than the maximum amount that can be dissolved in the solvent at a given temperature. In this state, more solute can be added and dissolved.

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The solution containing 35 g of NaCl per 100 g of water at 25 °C is unsaturated.

To determine the saturation status of the solution, we need to compare the actual amount of solute (NaCl) dissolved in the solvent (water) with the maximum amount that can be dissolved at a given temperature, which is known as the solubility of the solute in the solvent.

The solubility of NaCl in water at 25 °C is approximately 36 g per 100 g of water. Since the given solution has 35 g of NaCl per 100 g of water, this is less than the solubility limit. Therefore, the solution can still dissolve more NaCl and is considered unsaturated.

 If the solution had exactly 36 g of NaCl per 100 g of water, it would be saturated, meaning it has reached its maximum capacity to dissolve NaCl at that temperature. If it had more than 36 g of NaCl per 100 g of water, it would be supersaturated, which is a state where the solution contains more solute than would normally be possible at equilibrium.

he rate constant for this zero‑order reaction is 0.0130 M ⋅ s − 1 at 300 ∘ C. A ⟶ products How long (in seconds) would it take for the concentration of A to decrease from 0.890 M to 0.280 M?

Answers

Answer:

188 s

Explanation:

We are told the reaction is second order respect to A so we know the expression for the rate law is

rate = - Δ[A]/Δt = k[A]²

where the symbol Δ stands for change, [A] is the concentration of A, and k is the rate constant.

The integrated rate law for this equation from calculus is

1 / [A]t = kt + 1/[A]₀

where  [A]t is the concentration of A at time t, k is the rate constant, and [A]₀ is the initial concentration.

Since we have all the information required to solve this equation lets plug our values

1 / 0.280= 0.0130x t  + 1 / 0.890

( 1 / 0.280 - 1 / 0.890)M⁻¹ = 0.0130 M⁻¹ ·s⁻¹t

t = 188 s

The chemical formula for beryllium sulfide is BeS. A chemist measured the amount of beryllium sulfide produced during an experiment. She finds that 8.31 g of beryllium sulfide is produced. Calculate the number of moles of beryllium sulfide produced. Be sure your answer has the correct number of significant digits

Answers

Answer:

The answer is 0.20231 mol BeS

Explanation:

we look for the molecular weight of beryllium and sulfur in the periodic table:

molecular weight of Be = 9.01 g/mol

molecular weight of S = 32.065 g/mol

therefore, the molecular weight of beryllium sulfide is equal to:

molecular weight of BeS = 9.01 + 32.065 = 41.075 g/mol

The number of moles will be equal to:

[tex]n BeS = 8.31 g BeS x\frac{1 mol BeS}{41.075 g BeS}=0.20231 mol BeS[/tex]

Final answer:

To find the number of moles of BeS produced in the experiment, we calculate the molar mass of BeS (41.077 g/mol) and use the formula mass divided by molar mass. The result is 0.202 moles of beryllium sulfide from 8.31 g.

Explanation:

The question asks us to calculate the number of moles of beryllium sulfide (BeS) produced when a chemist measures 8.31 g of it. First, we need to calculate the molar mass of beryllium sulfide. Beryllium (Be) has an atomic mass of 9.012 g/mol, and sulfur (S) has an atomic mass of 32.065 g/mol. Therefore, the molar mass of beryllium sulfide is 9.012 g/mol + 32.065 g/mol = 41.077 g/mol.

To find the number of moles of BeS, we use the formula:

molar mass = mass / number of moles. Rearranging this formula to solve for the number of moles gives number of moles = mass / molar mass. Substituting the given values, we get number of moles = 8.31 g / 41.077 g/mol = 0.202 moles. Therefore, 8.31 g of beryllium sulfide is equivalent to approximately 0.202 moles, with the answer rounded to three significant digits as per the given mass.

If the final pressure on the gas is 1.20 atm , calculate the entropy change for the process. Check lecture notes or textbook for the formula connecting the change of entropy and gas volume. Assume that neon behaves as an ideal gas in this experiment.

Answers

Answer: [tex]-2.34\frac{J}{K}[/tex]

Explanation:

In thermodynamics, entropy (symbolized as S) is a physical quantity for a thermodynamic system in equilibrium. It measures the number of micro states compatible with the macro state of equilibrium, it can also be said that it measures the degree of organization of the system, or that it is the reason for an increase in internal energy versus an increase in the temperature of the system.

If we assume we have 0.6 mol of an ideal gas at 350 K at an initial pressure of 0.75 atm, we calculate the entropy change as:

[tex]S=nRln\frac{P1}{P2}[/tex]

Where S is entropy, n is the number of moles, R is the gas constant R is 8.314 J / mol·K, P1 is the initial pressure and P2 is the final pressure. Then we substitute the values and solve for S.

[tex]S= (0.6 mol).(8.3145\frac{J}{mol.k})(ln\frac{0.75atm}{1.2atm})[/tex]

[tex]S= -2.34\frac{J}{K}[/tex]

The question is not complete and the complete question is ;

the pressure on 0.600 mol of an ideal gas at 350 K is increased isothermally from an initial pressure of 0.750 atm (b) If the final pressure on the gas is 1.20 atm, calculate the entropy change for the process.

Answer:

Entropy change = -2.34 J/k

Explanation:

In thermodynamics, the entropy of a system is expected to increase with increase in temperature, increase in volume, or increase in number of gas particles.

Now, the gas is expanded isothermally and so its temperature is constant. Thus, as pressure of an ideal gas increases, the number of microstates possible for a system decreases and this results in the decrease of reaction entropy and thus is negative.

Thus, ΔS = nRIn(P1/P2)

Now, from the question,

n = 0.06 moles

P1 = 0.75 atm and P1=1.2 atm

R is gas constant and is 8.3145 J/kg.mol

Thus, ΔS = 0.06 x 8.3145 x In(0.75/1.2) = -2.34 J/k

Two important indicators of stream pollution are high biological oxygen demand (BOD) and low pH. Of the more than 250 streams draining into a large lake, 30% have high BOD and 20% have low pH levels, with 10% having both characteristics.

Answers

Answer:

a) The Venn diagram is presented in the attached image to this answer.

b) Check Explanation.

c) 0.3333

d) 0.1429

e) 0.6

Explanation:

Let the probability of a lake having high BOD be P(B) = 30% = 0.3

Probability of a lake having low pH = P(P) = 20% = 0.2

Probability that a lake has high BOD and low pH = P(B n P) = 10% = 0.1

Then, probability that a lake has normal BOD = P(B') = 1 - P(B) = 1 - 0.3 = 0.7

Probability that a lake has normal pH = P(P') = 1 - P(P) = 1 - 0.2 = 0.8

Total probability = P(U) = 100% = 1

a) The Venn diagram is presented in the attached image to this answer.

b) Two events are independent if and only if, P(A|B) = P(A) or P(B|A) = P(B).

For this question,

P(B|P) = P(B n P)/P(P) = 0.1/0.2 = 0.5 ≠ P(B) (which is 0.3)

And P(P|B) = P(B n P)/P(B) = 0.1/0.3 = 0.333 ≠ P(P) (which is 0.2).

It is evident that the two events aren't independent of each other.

c) If a stream has high BOD, what is the probability it will also have low pH?

This probability is given as P(P|B) meaning that, the probability of a lake having low pH given that it has high BOD.

Mathematically, this conditional probability is given by

P(P|B) = P(B n P)/P(B) = 0.1/0.3 = (1/3) = 0.3333

d) If a stream has normal levels of BOD, what is the probability it will also have low pH.

This probability is given as P(P|B'); that is, the probability of a lake having low pH given that it has normal BOD.

Mathematically,

P(P|B') = P(B' n P)/P(B')

P(B') = 0.7 (already found above)

But P(B' n P) = ?

Mathematically,

P(B' n P) = P(P) - P(B n P) = 0.2 - 0.1 = 0.1

P(P|B') = 0.1/0.7 = 0.1429

e) What is the probability that a stream will not exhibit either pollution indicator, i.e., will have normal BOD and pH levels?

This is given as P(B' n P')

Mathematically, this represents the region in the Venn diagram outside of the circles representing P(B) and P(P) and it's given mathematically as,

P(B' n P') = P(U) - [P(B n P') + P(B' n P) + P(B n P)] = 1 - (0.2 + 0.1 + 0.1) = 1 - 0.4 = 0.6 or 60%

When the stream has high BOD the probability of low pH is 0.33 and 0.142 when it has normal BOD. 0.6 is the probability that a stream will exhibit neither indicator.

What is BOD?

BOD is the biological oxidation demand, that tells about the dissolved oxygen amount in the water body. BOD along with pH are the indicator of pollution.

The Venn diagram is attached in the image below.

The two indicators, high BOD and low pH are dependent on each other. It can be shown as:

[tex]\rm P(A|B) = P(A) \;or \;P(B|A) = P(B)[/tex]

But,

[tex]\begin{aligned}\rm P(B|P) &= \rm \dfrac{P(B \;n \;P)}{P(P)} \\\\&= \dfrac{0.1}{0.2} \\\\&= 0.5 \neq \rm P(B)\end{aligned}[/tex]

And  

[tex]\begin{aligned}\rm P(P|B) &=\rm \dfrac{P(B \;n \;P)}{P(B)} \\\\&= \dfrac{0.1}{0.3} \\\\&= 0.333 \neq \rm P(P) \end{aligned}[/tex]

Hence they are not independent of each other.

The probability of low pH at high BOD is given as P(P|B).

[tex]\begin{aligned}\rm P(P|B) &= \rm \dfrac{P(B \;n \;P)}{P(B)}\\\\ &= \dfrac{0.1}{0.3}\\\\&= 0.3333\end{aligned}[/tex]

Hence, 0.33 is the probability of low pH at high BOD.

The probability of low pH at normal BOD is given as P(P|B').

[tex]\begin{aligned}\rm P(P|B') &= \rm \dfrac{P(B' \;n\; P)}{P(B')}\\\\\rm P(P|B') &= \dfrac{0.1}{0.7} \\\\&= 0.1429\end{aligned}[/tex]

Hence,  0.1429 is the probability of low pH at normal BOD.

The probability that a stream will not exhibit any of the indicators is given by, P(B' n P').

[tex]\begin{aligned}\rm P(B' n P') &= \rm P(U) - [P(B n P') + P(B' n P) + P(B n P)]\\\\&= 1 - (0.2 + 0.1 + 0.1) \\\\&= 0.6\end{aligned}[/tex]

Hence, 0.6 is the probability that neither of the indicators will be expressed.

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Select the statements that are correct with respect to waste disposal in the Electrochemical Cells Experiment. (Select all that apply.)

a. Dilute copper and ascorbic acid solutions should be disposed of in the waste container in the hood.
b. Rinsings from the half-cell module can be flushed down the sink.
c. Metal and graphite electrodes should be rinsed with water, dried, and returned to their positions on the lab bench.
d. The contents of the half-cell module should be disposed of in the waste container in the hood.
e. No waste will be generated during this experiment.
f. The electrodes should be discarded in the proper jar.

Answers

Answer:A. Dilute copper and ascorbic acid solutions should be disposed of in the waste container in the hood.

C. Metal and graphite electrodes should be rinsed with water, dried, and returned to their positions on the lab bench.

D. The contents of the half-cell module should be disposed of in the waste container in the hood.

Explanation: An electrochemical cell is a cell that has the capability of producing Electric energy from chemical reaction (voltaic cells) or using Electric energy to make chemical reactions to take place(electrolytic cell). For a proper or effective waste disposal in an electrochemical cell the following options are correct.

Dilute copper and ascorbic acid solutions should be disposed of in the waste container in the hood.

Metal and graphite electrodes should be rinsed with water, dried, and returned to their positions on the lab bench.

The contents of the half-cell module should be disposed of in the waste container in the hood.

Final answer:

In the Electrochemical Cells Experiment, the correct statements regarding waste disposal include disposing copper and ascorbic acid solutions in the waste container, flushing rinsings from the half-cell module down the sink, and rinsing and drying the electrodes.

Explanation:

The correct statements with respect to waste disposal in the Electrochemical Cells Experiment are:

Dilute copper and ascorbic acid solutions should be disposed of in the waste container in the hood.Rinsings from the half-cell module can be flushed down the sink.Metal and graphite electrodes should be rinsed with water, dried, and returned to their positions on the lab bench.The contents of the half-cell module should be disposed of in the waste container in the hood.No waste will be generated during this experiment.The electrodes should be discarded in the proper jar.

Arrange the following aqueous solutions, all at 25 ∘C, in order of decreasing acidity. Rank from most acidic to most basic. To rank items as equivalent, overlap them.

Answers

Answer:

Rank from most acidic to most basic is

0.0023 M  HClpH = 5.45 and pOH = 8.550.0018 M  KOH

Explanation:

This question is missing options.

Options are

pOH = 8.55    pH= 5.45   0.0023 M HCl                    0.0018 M KOH

To rank these solutions first calculate either pH or pOH of these solutions.

We will use pH as an indicator to rank these.

Relation between pH and pOH is

    pH + pOH = 14    ................... Eq (A)

For pOH = 8.55

     use equation A

     pH + 8.55 = 14

     pH = 5.45

For pH = 5.45

     pH = 5.45

For 0.0023 M  HCl

HCl is a strong acid. It will ionize 100% in aqueous solution and produce Hydronium Ion. Formula to calculate pH of 0.0023 M  HCl is,

     pH = - log (Molarity)

     pH = - log (0.0023)

     pH = - (-2.64)

     pH = 2.64

For 0.0018 M  KOH

KOH is a base. It will produce Hydroxide Ion in aqueous solution. First calculate pOH and convert it into pH.

    pOH = - log (Molarity)

    pOH = - log (0.0018)

    pOH = 2.74

   use equation A

   pH + 2.74 = 14

   pH = 11.26

Lower the pH more acidic the solution is. Rank from most acidic to most basic is

0.0023 M  HClpH = 5.45 and pOH = 8.550.0018 M  KOH

   

Final answer:

The solutions, arranged from most acidic to most basic, are H₂SO₄, HCl, NH₄NO₃, NaCl, NaOH, and NaCN.

Explanation:

The arrangement of the given solutions in order of decreasing acidity is as follows:

H₂SO₄ (Strong acid)HCl (Strong acid)NH₄NO₃ (Neutral salt)NaCl (Neutral salt)NaOH (Strong base)NaCN (Weak base)

Strong acids completely dissociate in water, producing a large number of hydronium ions (H₃O⁺) and making the solution highly acidic. Neutral salts, such as NH₄NO₃ and NaCl, do not affect the pH of the solution. Strong bases, like NaOH, ionize completely and produce a high concentration of hydroxide ions (OH⁻), resulting in a basic solution. Weak bases, such as NaCN, only partially ionize, resulting in a lower concentration of OH⁻ ions and a slightly basic solution.

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The complete question is here:

Arrange the following aqueous solutions, all at 25 ∘C, in order of decreasing acidity. Rank from most acidic to most basic. To rank items as equivalent, overlap them.

H₂SO₄

HCl

NH₄NO₃

NaCl

NaOH

NaCN

how many moles of solute are in 300 mL of 1.5 M CaCl2? How many grams fo CaCl2 is this?

Answers

Answer:

1. 0.45 mole

2. 49.95g

Explanation:

The following were obtained from the question:

Volume of solution = 300mL = 300/1000 = 0.3L

Molarity = 1.5 M

Mole of CaCl2 =?

1. We can obtain the mole of the solute as follow:

Molarity = mole of solute /Volume of solution

1.5 = mole of solute/0.3

Mole of solute = 1.5 x 0.3

Mole of solute = 0.45 mole

2. The grams in 0.45 mole of CaCl2 can be obtained as follow:

Molar Mass of CaCl2 = 40 + (35.5 x 2) = 40 + 71 = 111g/mol

Mole of CaCl2 = 0.45 mole

Mass of CaCl2 =?

Mass = number of mole x molar Mass

Mass of CaCl2 = 0.45 x 111

Mass of CaCl2 = 49.95g

Answer:

We have 0.45 moles CaCl2 in this 1.5 M solution

This 49.9 grams of CaCl2

Explanation:

Step 1: data given

Volume of the CaCl2 solution = 300 mL = 0.300 L

Molarity of the CaCl2 solution = 1.5 M

Molar mass CaCl2 = 110.98 g/mol

Step 2: Calculate number of moles in the solution

Moles CaCl2 = molarity solution * volume of solution

Moles CaCl2 = 1.5 M * 0.300 L

Moles CaCl2 = 0.45 moles

Step 3: Calculate mass CaCl2

Mass CaCl2 = moles CaCl2 * molar mass CaCl2

Mass CaCl2 = 0.45 moles * 110.98 g/mol

Mass CaCl2 = 49.9 grams CaCl2

We have 0.45 moles CaCl2 in this 1.5 M solution

This 49.9 grams of CaCl2

What is the name of the product of the reaction of 1-pentyne with one equivalent of Br2? (that means that there is one mole of Br2 for each mole of 1-pentyne).

Answers

Final answer:

The product of the reaction of 1-pentyne with one equivalent of Br2 is called 1,2-dibromopentene, resulting from a halogen addition reaction.

Explanation:

The reaction of 1-pentyne with one equivalent of Br2 leads to the addition of bromine across the triple bond. Given that there is only one mole of Br2 for each mole of 1-pentyne, the bromine will add to the first and second carbons of the 1-pentyne chain, resulting in a dibromoalkene. Therefore, the name of the product is 1,2-dibromopentene. This product is the result of a typical halogen addition reaction to an alkyne, where the more substituted carbon atom gets the first bromine atom due to the Markovnikov's rule; however, in this case the symmetry of the starting alkyne makes that irrelevant since both terminal carbons are equivalent.

Which of the following statements about photosynthesis is correct? (multiple answers may be correct) A: Carbon dioxide serves as final acceptor of high energy electrons provided by the light reactions B: Water serves only as an electron donor in oxygenic photosynthesis C: The oxygen released by oxygenic photosynthesis originates from water D: Hydrogen sulfide can also serve as electron donor in oxygenic photosynthesis E: in anoxygenic photosynthesis carbon dioxide does not serve as final electron acceptor.

Answers

Final answer:

Statements B, C, and E are correct about photosynthesis. Water serves as an electron donor in oxygenic photosynthesis and the oxygen released by oxygenic photosynthesis does indeed come from water. In anoxygenic photosynthesis, carbon dioxide is not the end electron acceptor.

Explanation:

Among the listed statements about photosynthesis, B: Water serves only as an electron donor in oxygenic photosynthesis, and C: The oxygen released by oxygenic photosynthesis originates from water are correct. During photosynthesis, water is split, releasing electrons and protons, and providing the oxygen gas. In addition, statement E: in anoxygenic photosynthesis carbon dioxide does not serve as final electron acceptor is also correct. In anoxygenic photosynthesis, carried out by certain types of bacteria, something other than water provides the electrons, and carbon dioxide does not serve as the final electron acceptor.

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Final answer:

Statements B, C, and E are correct in regards to photosynthesis. In oxygenic photosynthesis, water acts as an electron donor, and oxygen is released as a byproduct, originating from water. In anoxygenic photosynthesis, carbon dioxide does not serve as the final electron acceptor.

Explanation:

Based on the provided information, statements B, C, and E are correct. Let's explain why.

B: In oxygenic photosynthesis, water indeed serves as an electron donor. It helps in replacing the reaction center electron, and as a byproduct, oxygen is formed.

C: The oxygen released by oxygenic photosynthesis indeed originates from water. When water serves as an electron donor and is split, oxygen is released.

E: In anoxygenic photosynthesis, carbon dioxide does not serve as the final electron acceptor. Instead, other reduced molecules like hydrogen sulfide or thiosulfate may be used as the electron donor. Here, oxygen is not formed as a byproduct.

Statements A and D are incorrect. In photosynthesis, Carbon dioxide does not serve as the final acceptor of high energy electrons -- NADP+ does. Besides, Hydrogen sulfide can serve as an electron donor, but not in oxygenic photosynthesis.

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In light of the nuclear model for the atom, which statement is true?

A) For a given element, the size of an isotope with more neutrons is larger than one with fewer neutrons.

B) For a given element, the size of an atom is the same for all of the element’s isotopes.

Answers

The true statement for nuclear model for the atom is B: For a given element, the size of an atom is the same for all of the element’s isotopes is

Explanation:

The isotopes are the atoms of an element that have different number of neutrons in their nuclei but same number of electrons.

The number of protons remains the same in isotopes.

the atomic mass of the isotope differ because the atomic mass is number of proton+ number of neutrons.

The atomic number remains the same since number of protons equals the number of protons.

The atomic radii does not change because the arrangement or number of electrons do not differ among the isotopes. Since there is no change in atomic radii the size remains same in isotopes of an element. Although the size of nucleus increases due to more protons.

The correct option is B). The true statement is For a given element, the size of an atom is the same for all of the element’s isotopes.

In the nuclear model of the atom, the size of an atom is primarily determined by the number of protons in the nucleus, which is the same for all isotopes of a given element. This is because the number of protons determines the atomic number, and thus the number of electrons in a neutral atom.

Isotopes of an element have the same number of protons but different numbers of neutrons. While the addition of neutrons does increase the mass of the atom, it does not significantly affect the size of the atom. The electron cloud is attracted to the positively charged protons in the nucleus, and since the number of protons remains constant for all isotopes of an element, the size of the electron cloud, and therefore the atomic radius, remains relatively constant.

 The presence of additional neutrons can have a very slight effect on the atomic radius due to the increased mass of the nucleus, which might lead to a slightly stronger attraction between the nucleus and the electrons.

When a diprotic acid, , is titrated with , the protons on the diprotic acid are generally removed one at a time, resulting in a pH curve that has the following generic shape: Notice that the plot has essentially two titration curves. If the first equivalence point occurs at 100.0 mL added, what volume of added corresponds to the second equivalence point? Volume = mL For the following volumes of added, list the major species present after the reacts completely.

Answers

Final answer:

In a titration involving a diprotic acid, the equivalence points occur when the acid has lost its protons. If the first equivalence point occurs at 100 mL, the second should occur at 200 mL. resultant species in the solution will vary based on the volume of NaOH added.

Explanation:

A diprotic acid has two protons to donate in a reaction. During titration, protons are removed one at a time, thus presenting two titration curves or equivalence points. If the first equivalence point occurs at 100.0 mL, the second equivalence point typically occurs at twice that volume because the second proton is just as readily removed as the first. Therefore, the second equivalence point will be at 200.0 mL.

Different volumes of added NaOH will result in different major species present. For example, before the equivalence point is reached (0 mL < V< 25 mL), the pH increases gradually as the diprotic acid reacts with the added NaOH to form its conjugate base. At the equivalence point (V = 25 mL), pH increases abruptly as the reaction transitions from acidic to either neutral or basic, depending on whether the diprotic acid is strong or weak, respectively. After the equivalence point (V > 25 mL), the pH is determined by the amount of added NaOH.

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Consider the nitration by electrophilic aromatic substitution of salicylamide to iodosalicylamide. Reaction scheme illustrating the iodination of salicylamide by sodium iodide and sodium hypochlorite via an electrophilic aromatic substitution to form iodo-salicylamide. The density of salicylamide, d = 1.09 g/mL. A reaction was performed in which 3.65 mL of salicylamide was reacted with a mixture of concentrated nitric and sulfuric acids to make 5.33 g of iodosalicylamide. Calculate the theoretical yield and percent yield for this reaction.

Answers

Answer: The percent yield of the reaction is 68.68%.

Explanation:

To calculate the mass of salicylamide, we use the equation:

[tex]\text{Density of substance}=\frac{\text{Mass of substance}}{\text{Volume of substance}}[/tex]

Density of salicylamide = 1.06 g/mL

Volume of salicylamide = 3.65 mL

Putting values in above equation, we get:

[tex]1.06g/mL=\frac{\text{Mass of salicylamide}}{3.65mL}\\\\\text{Mass of salicylamide}=(1.06g/mL\times 3.65mL)=3.869g[/tex]

To calculate the number of moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]     .....(1)

Given mass of salicylamide = 3.869 g

Molar mass of salicylamide = 137.14 g/mol

Putting values in equation 1, we get:

[tex]\text{Moles of salicylamide}=\frac{3.869g}{137.14g/mol}=0.0295mol[/tex]

The chemical equation for the conversion of salicylamide to iodo-salicylamide follows:

[tex]\text{salicylamide }+NaI+NaOCl+EtOH\rightarrow \text{iodo-salicylamide }[/tex]

By Stoichiometry of the reaction:

1 mole of salicylamide produces 1 mole of iodo-salicylamide

So, 0.0295 moles of salicylamide will produce = [tex]\frac{1}{1}\times 0.0295=0.0295moles[/tex] of iodo-salicylamide

Now, calculating the mass of iodo-salicylamide from equation 1, we get:

Molar mass of iodo-salicylamide = 263 g/mol

Moles of iodo-salicylamide = 0.0295 moles

Putting values in equation 1, we get:

[tex]0.0295mol=\frac{\text{Mass of iodo-salicylamide}}{263g/mol}\\\\\text{Mass of iodo-salicylamide}=(0.0295mol\times 263g/mol)=7.76g[/tex]

To calculate the percentage yield of iodo-salicylamide, we use the equation:

[tex]\%\text{ yield}=\frac{\text{Experimental yield}}{\text{Theoretical yield}}\times 100[/tex]

Experimental yield of iodo-salicylamide = 5.33 g

Theoretical yield of iodo-salicylamide = 7.76 g

Putting values in above equation, we get:

[tex]\%\text{ yield of iodo-salicylamide}=\frac{5.33g}{7.76g}\times 100\\\\\% \text{yield of iodo-salicylamide}=68.68\%[/tex]

Hence, the percent yield of the reaction is 68.68%.

Final answer:

In this case, we can calculate the mass of the salicylamide and use it to calculate the theoretical yield. Then, we can calculate the actual yield and percent yield which is 57.38%

Explanation:

To calculate the theoretical yield and percent yield of a reaction, we need to first determine the limiting reagent. From the given information, we know that 3.65 mL of salicylamide was reacted, which has a density of 1.09 g/mL. Therefore, the mass of salicylamide can be calculated as follows:

Mass = Volume x Density = 3.65 mL x 1.09 g/mL = 3.97 g

Next,

Moles of salicylamide used = mass / molar mass = 3.9825 g / 137.14 g/mol = 0.0291 mol

Moles of iodosalicylamide produced = Moles of salicylamide used = 0.0291 mol

Mass of iodosalicylamide produced = moles × molar mass = 0.0291 mol × 319.02 g/mol = 9.303 g

Therefore, the theoretical yield of iodosalicylamide is 9.303 g.

The percentage yield of the reaction can be calculated as follows:

= Actual yield / theoretical yield × 100

= (5.33 g / 9.303 g) × 100 = 57.38%

Therefore, the percentage yield of the reaction is 57.38%.

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Click in the answer box to activate the palette. List the following molecules in order of increasing dipole moment: H2O, CBr4, H2S, HF, NH3, CO2 < < < < Electronegativities H 2.1 C 2.5 N 3.0 O 3.5 F 4.0 S 2.5 Br 2.8

Answers

Answer:

HF > H2O > NH3 > H2S > CBr4=CO2=0

Explanation:

Dipole moment is a vector quantity. Its a measure of polarity of a bond in a molecule and also a meaure of separation of positive and negative charge in a system.It occurs due to electronegativity difference between the atoms in a molecule.

In order for a molecule to have dipole moment, a molecule must exhibit high electronegativity difference and the shape of the moloecule must be asymmetry

HF has the highest electronegativity difference among all the molecules listed above hence its dipole moment is the greatest.

[tex]H_{2}O[/tex] has a bent structure. There are two O-H bonds hence more charge dipoles. The dipole moment is less than HF molecule because of the net dipole moments of two O-H bonds.

[tex]CO_{2}[/tex] is a linear molecule.However it has polar bonds.But because of the shape of the molecule, the two C-O bond dipoles cancel out each other hence the overall dipole moment will be zero.

Similarly in [tex]CBr_{4}[/tex], ,since the molecule is symmetry, the bond dipole cancels each other out hence the overall dipole moment will be zero.  

The increasing order of the dipole moment will be:

[tex]\rm CO_2[/tex] < [tex]\rm CBr_4[/tex] < [tex]\rm H_2S[/tex] < [tex]\rm NH_3[/tex] < [tex]\rm H_2O[/tex] < HF.

Dipole moment can be described as the measure of the polarity of the molecule. The higher the electronegativity difference, the more polar the bond.

In the given molecules,

HF: The electronegativity difference is 1.9.

[tex]\rm H_2O[/tex] : The molecule is bend, and the difference in electronegativity is 1.4.

[tex]\rm CBr_4[/tex] : The molecule is symmetrical, which cancels the dipole. The net dipole is zero.

[tex]\rm H_2S[/tex] : The electronegativity difference is 0.4.

[tex]\rm NH_3[/tex] : The electronegativity difference is 0.9.

[tex]\rm CO_2[/tex]: The molecule has a symmetrical arrangement. Thus the net dipole of the molecule is 0.

The increasing order of the dipole moment will be:

[tex]\rm CO_2[/tex] < [tex]\rm CBr_4[/tex] < [tex]\rm H_2S[/tex] < [tex]\rm NH_3[/tex] < [tex]\rm H_2O[/tex] < HF.

The molecule with the highest dipole moment is HF.

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For this heterogeneous system 2 A ( aq ) + 3 B ( g ) + C ( l ) − ⇀ ↽ − 2 D ( s ) + 3 E ( g ) the concentrations and pressures at equilibrium are [ A ] = 9.68 × 10 − 2 M , P B = 9.54 × 10 3 Pa , [ C ] = 14.64 M , [ D ] = 10.11 M , and P E = 9.56 × 10 4 torr . Calculate the thermodynamic equilibrium constant, K.

Answers

Answer:

[tex]2.55*10^{11[/tex]

Explanation:

Equation for the heterogeneous system is given as:

[tex]2A_{(aq)} + 3 B_{(g)} + C_{(l)}[/tex]      ⇄      [tex]2D_{(s)}[/tex]    [tex]+[/tex]     [tex]3E_{(g)}[/tex]

The concentrations and pressures at equilibrium  are:

[tex][A] = 9.68*10^{-2}M[/tex]

[tex]P_B = 9.54*10^3Pa[/tex]

[tex][C]=14.64M[/tex]

[tex][D]=10.11M[/tex]

[tex]P_E=9.56*10^4torr[/tex]

If we convert both pressure into bar; we have:

[tex]P_B = 9.54*10^3Pa[/tex]

[tex]P_B = (9.54*10^3)*\frac{1}{10^5} bar[/tex]

[tex]P_B=9.54*10^{-2}bar[/tex]

[tex]P_E=9.56*10^4torr[/tex]

1 torr = 0.001333 bar

[tex]9.54*10^4 *0.001333 = 127.5 bar[/tex]

[tex]K=\frac{[P_E]^3}{[A]^2[P_B]^3}[/tex]

[tex]K=\frac{(127.5)^3}{(9.68*10^{-2})^2(9.54*10^{-2})^3}[/tex]

[tex]K=2.55*10^{11[/tex]

A chemist adds 55.0mL of a ×1.710−5/mmolL mercury(II) iodide solution to a reaction flask. Calculate the micromoles of mercury(II) iodide the chemist has added to the flask. Be sure your answer has the correct number of significant digits.

Answers

Answer:

The answer is 0.017 μmol of mercury iodide

Explanation:

To know the micromoles we must use the following conversion, 1 mmol = 1000μmol. we use a rule of three for the calculation of micromoles:

1mmol------------------1000μmol

1.7x10^-5mmol------- Xμmol

Clearing the X, we have:

X μmol = (1.7x10^-5x1000)/1 = 0.017μmol

Iron‑59 is used to study iron metabolism in the spleen. Its half‑life is 44 days. How many days would it take a 28.0 g sample of iron‑59 to decay to 0.875 g?

Answers

The radioisotope will take 219 days to decay from 28 g to 0.875 g.

Explanation:

Any radioactive isotope is tend to decay with time. So the rate of decay of the radioactive isotopes is termed as disintegration constant. Since, the initial mass of the radioactive isotope is given along with the reducing mass. In order to determine the time required to reduce the mass of the radioisotope from 28 g to 0.875 g, first the disintegration constant is need to be determined. The disintegration constant can be obtained from half life time of the isotope. As half life time is the measure of time required to reduce half of the concentration of the isotope.

Half life time = 0.6932/disintegration constant

44 = 0.6932/λ

λ = 0.6932/44=0.0158

So, with this values of disintegration constant, initial mass and final mass, the time required to reduce from initial to final mass can be obtained using law of disintegration constant as follows.

N = Noe^(-λt)

[tex]t= -\frac{1}{disintegration constant}* ln(\frac{N}{N_{0} } )\\ \\t = -\frac{1}{0.0158}*ln(\frac{0.875}{28})\\ \\t = -\frac{1}{0.0158}*ln(0.03125)\\\\t = -63.29*(-3.466)\\\\t=219 days.[/tex]

Thus, the radioisotope will take 219 days to decay from 28 g to 0.875 g.

It would take 220 days for 28.0 g sample of iron‑59 to decay to 0.875 g

The half life of a substance is the amount of time it takes to decay to half of the initial value. It is given by:

[tex]N(t)=N_o(\frac{1}{2}) ^\frac{t}{t_\frac{1}{2} } \\\\N(t)=amount\ after\ t\ years, N_o=original\ value,t_\frac{1}{2} =half\ life\\\\Given\ that:\\\\N(t)=0.875g,N_o=28g,t_\frac{1}{2} =44\ days. hence:\\\\\\0.875=28(\frac{1}{2} )^\frac{t}{44} \\\\t=220\ days[/tex]

Hence it would take 220 days for 28.0 g sample of iron‑59 to decay to 0.875 g

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Atmospheric pressure decreases as altitude increases. In other words, there is more air pushing down on you at sea level, and there is less air pressure pushing down on you when you are on a mountain.If hexane (C6H14), octane (C8H18), and octanol (C8H17OH) are heated evenly at different altitudes, rank them according to the order in which you would expect them to begin boiling.

Answers

Explanation:

Boiling point is the temperature at which vapor pressure of a liquid becomes equal to the atmospheric pressure.

So, more is the number of carbon atoms present in a compound that are linearly attached to each other more will be its boiling point. This is because then there are more intermolecular forces present in it and also it occupies more surface area.

Hence, in order to break these intermolecular forces more heat is required. As a result, boiling point of the compound increases.

Therefore, we can conclude that given compounds are ranked according to the increasing order in which you would expect them to begin boiling as follows.

    Hexane at high altitude < Octane at high altitude < Octane at sea level  < Octanol at sea level      

The compound responsible for the characteristic smell of garlic is allicin, C 6H 10OS 2. The mass of 1.00 mol of allicin, rounded to the nearest integer, is ________ g. 34 162 86 61 19

Answers

Answer: The answer is 162g.

Explanation: To calculate the mass of a molecule, you have to find the molar mass of each element of the molecule.

Molar mass of C = 12g/mol

Molar mass of H = 1g/mol

Molar mass of O = 16g/mol

Molar mass of S = 32g/mol

From the allicin's formula, there are:

6 C = 6.12 = 72

10 H = 10.1 = 10

1 O = 1.16 = 16

2 S = 2.32 = 64

Adding them up:

C6H10OS2 = 72+10+16+64 = 162g/mol.

As it is requested 1 mol of allicin, it has 162g.

Answer:

162 g/mol

Explanation:

This problem requires us to calculate the molar mass of allicin, grs/mol. So with the atomic weights of the atoms in this compound, the molar mass will be the sum of the atomic weight multiplied by the number of atoms in the formula.

atomic weights ( g/mol )

C : 12.01 g/mol

H :  1.00 g/mol

O: 16.00 g/mol

S : 32.06 g/mol

Molar mass C₆H₁₀Os₂ (g/mol ) = 6 x 12.01 + 10 x 1.00 + 1 x 16 +2 x 32.06

                                                  = 162 g/mol  (rounded to the nearest integer)

Consider the reaction N2(g) + 2O2(g)2NO2(g) Using standard thermodynamic data at 298K, calculate the entropy change for the surroundings when 1.90 moles of N2(g) react at standard conditions. S°surroundings =

Answers

Final answer:

To calculate the entropy change for the surroundings during the reaction of N2(g) and O2(g) to form NO2(g), the standard enthalpy change of the reaction must be known. This value can be used with the equation ΔS° = -ΔH°/T to find the entropy change of the surroundings.

Explanation:

The student is asking to calculate the entropy change for the surroundings (ΔS°surroundings) when 1.90 moles of N2(g) react with O2(g) to form NO2(g) according to the reaction N2(g) + 2O2(g) → 2NO2(g) at standard conditions of 298 K.

To find this, we'll first need the standard enthalpy change (ΔH°) for the reaction, which can be obtained from standard thermodynamic tables. We then apply the equation ΔS° = -ΔH°/T, which relates the entropy change of the surroundings to the enthalpy change of the system at a constant temperature (T).

Given that the standard enthalpy change for the formation of NO2(g) is 33.2 kJ/mol, and the reaction produces 2 moles of NO2 for 1 mole of N2, the standard enthalpy change for the reaction when 1.90 moles of N2 react is (1.90 moles * 33.2 kJ/mol * 2). We'll convert kJ to J by multiplying by 1,000 and then calculate ΔS°surroundings.

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Final answer:

The standard entropy change for the reaction N2(g) + 2O2(g) → 2NO2(g) at 298K can be calculated using the equation: ΔS° = 2∙S°(NO2) - [S°(N2) + 2∙S°(O2)]. The entropy change is -198.3 J/mol K.

Explanation:

The standard entropy change for the reaction N2(g) + 2O2(g) → 2NO2(g) at 298K can be calculated using the equation: ΔS° = 2∙S°(NO2) - [S°(N2) + 2∙S°(O2)].

Using the standard entropy values at 298K from the reference table, we can substitute the values and calculate the entropy change:

ΔS° = 2∙192.5 - [191.5 + 2∙130.6]

ΔS° = -198.3 J/mol K

what is the job of a scientist?
A) To ignore facts that do not support his or her theory.
B) To answer ethical questions.
C) To ask and answer scientific questions.
D) To write laws based on his or knowlege.

Answers

Answer:

c i believe, not sure

Explanation:

Answer is C
Because they have to do experiments and hypothesis and do science
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