Select the correct answer.
For the reaction PC15(e) + heat - PC13(e) + Cl2ce), what will happen when the temperature is decreased?
OA.
There will not be a shift in equilibrium.
OB.
There will be a shift toward the products.
OC.
There will be a shift toward the reactants.
OD. Not enough information is given.
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Answer: 1. Chemical weathering, 2. Mechanical weathering, 3. Chemical weathering, 4. Mechanical weathering, 5. Chemical weathering (all in the same order as the pick)

Explanation:

Statement 1,3 and 5 represent chemical weathering while statement 2 and 4 represent mechanical weathering.

Chemical weathering is defined as a process of breaking down of rocks which is caused by the action of rain water which reacts with the minerals present in the rock and result in it's break down.This results in formation of new minerals and salts which are soluble.

The process of chemical weathering requires water and high temperatures,so places with warm and damp climate have higher rate of chemical weathering of rocks.There are three main different types of chemical weathering:

1) solution

2) hydrolysis

3)oxidation

Chemical weathering changes the composition of rocks,weathering caused by water which is called as hydrolysis results in production of new minerals in the rock.

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According to the Arrhenius definition, Ca(OH)₂ is a Arrhenius base.

According to the Arrhenius theory, acids are those substance which gives H⁺ ion in the aqueous solution and bases are those substances which gives OH⁻ ion in the aqueous solution.

Chemical equation for the dissociation of Calcium hydroxide is:

Ca(OH)₂ → Ca²⁺ + 2OH⁻

From the above equation it is clear that Ca(OH)₂ is an Arrhenius base as it gives hydroxide ion.

Hence, Ca(OH)₂ is a Arrhenius base.

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Calcium hydroxide, Ca(OH)₂, is a base according to the Arrhenius definition, as it produces hydroxide ions (OH-) when it dissolves in water. The equation representing this is Ca(OH)₂ (aq) → Ca²⁺ (aq) + 2OH- (aq). It is considered a strong base because it dissociates completely in water.

According to the Arrhenius definition, a base is a substance that releases hydroxyl ions (OH-) when it is dissolved in water. Calcium hydroxide, Ca(OH)₂, is considered to be a base because it dissociates in water to form calcium ions (Ca²⁺) and hydroxide ions (OH-). The chemical equation representing this process is: Ca(OH)₂ (aq) → Ca²⁺ (aq) + 2OH- (aq).

This depicts that calcium hydroxide is a base since it generates hydroxide ions (OH-) upon dissolution in water, which aligns with the countenance of a base as defined by Arrhenius. Because it dissociates completely in water solutions, it is acknowledged as a strong base.

The hydroxide ions (OH-) released into the solution are capable of combining with hydrogen ions (H+) to create water molecules. This reduces the solution's acidity and the concentration of free H+ ions, further signifying the behavior of a base.

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Answer:

Ba(OH)2 + 2HClO4 —> Ba(ClO4)2 + 2H2O

The coefficient of H2O is 2

Explanation:

Ba(OH)2 + HClO4 —> Ba(ClO4)2 + H2O

Now let us balance the equation as shown below:

There are 2 atoms of Cl on the right and 1 atom on the left. It can be balanced by putting 2 in front of HClO4 as shown below:

Ba(OH)2 + 2HClO4 —> Ba(ClO4)2 + H2O

Now, there are a total of 4 atoms of H on the left and 2 on the right. It is balanced by putting 2 in front of H2O as shown below

Ba(OH)2 + 2HClO4 —> Ba(ClO4)2 + 2H2O

Now, the equation is balanced. From the balanced equation, the coefficient of H2O is 2

The balanced molecular equation for the reaction of barium hydroxide (Ba(OH)₂) with perchloric acid (HClO₄) is:

Ba(OH)₂ + 2HClO₄ -> Ba(ClO₄)₂ + 2H₂O

In this equation, the coefficient of H₂O is 2.

A balanced equation is a chemical equation in which the number of atoms of each element is equal on both sides of the equation. It represents a chemical reaction by showing the reactants on the left side and the products on the right side, with appropriate coefficients to balance the equation.

In a balanced equation, the total mass and the total charge of the reactants are equal to the total mass and total charge of the products. This ensures that the law of conservation of mass and the law of conservation of charge are satisfied.

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Answer:

20m

Explanation:

mark brainliest

Final answer:

To calculate the mass of water present, we can use the formula Q = mcΔT, where Q is the heat energy (0.899 J), m is the mass of water, c is the specific heat capacity of water (4.184 J/g °C), and ΔT is the temperature change (0.692 °C). Rearranging the formula to solve for m, we find that the mass of water is approximately 0.307 g.

Explanation:

To calculate the mass of water present, we can use the formula:

Q = mcΔT

Where:

Q is the heat energy (0.899 J)

m is the mass of water

c is the specific heat capacity of water (4.184 J/g °C)

ΔT is the temperature change (0.692 °C)

Rearranging the formula to solve for m, we get:

m = Q / (cΔT)

Substituting the given values:

m = 0.899 J / (4.184 J/g °C * 0.692 °C)

Calculating m gives us:

m ≈ 0.307 g

Answer:

10.4 moles

Explanation:

Given parameters:

Number of moles of oxygen = 5.2moles

Number of moles of nitrogen monoxide = ?

Solution:

To solve this problem, we need to work from the known to the unknown specie according to the reaction.

Oxygen gas is known and we can estimate the amount of mole of nitrogen monoxide;

Let us write the balanced reaction equation;

                N₂    +      O₂          →          2NO

  according to this reaction;

       1 mole of oxygen gas will produce 2 mole of NO

       5.2 moles of oxygen gas will produce  (5.2 x 2)moles  = 10.4moles

Answer:

10.4 moles

Explanation:

The equation of the reaction between oxygen and nitrogen to produce nitrogen monoxide is,

N₂(g) + O₂ (g)→ 2NO (g)

1        :   1         :   2

This mean 1 mole of nitrogen gas react with 1 mole of oxygen gas to give 2 moles of nitrogen monoxide

In this case the if 5.2 moles of Oxygen react, it will give 2 moles of NO

5.2*2=10.4

its the oceam which is blue in color so

Answer:

m= −21

Explanation:

Solve for m by simplifying both sides of the equation, then isolating the variable. m= −21

Answer: Mass of diborane that would react with 7.5 mole of O2 is 70g

Explanation: The explanation is contained in the picture attached.

Answer:

Empirical formula is CH₂O.

Molecular formula = C₆H₁₂O₆

Explanation:

Given data:

Mass of hydrogen = 3.36 g

Mass of carbon = 20.00 g

Mass of oxygen = 26.64 g

Molar mass of compound = 180.156 g/mol

Empirical formula = ?

Molecular formula = ?

Solution:

Empirical formula:

It is the simplest formula gives the ratio of atoms of different elements in small whole number

Number of gram atoms of H = 3.36 / 1.01 = 3.3

Number of gram atoms of O = 26.64 / 16 = 1.7

Number of gram atoms of C = 20 / 12 = 1.7

Atomic ratio:

            C                      :        H            :         O

           1.7/1.7                :     3.3/1.7       :       1.7/1.7

              1                     :           2          :        1

C : H : O = 1 : 2 : 1

Empirical formula is CH₂O.

Molecular formula:

Molecular formula = n (empirical formula)

n = molar mass of compound / empirical formula mass

Empirical formula mass = CH₂O = 12×1 + 2× + 16

Empirical formula mass = 30

n = 180.156 / 30

n = 6

Molecular formula = n (empirical formula)

Molecular formula = 6 (CH₂O)

Molecular formula = C₆H₁₂O₆

The correct option is C. Some of the absorbed energy is converted to potential energy and some is converted to kinetic energy

Explanation:

Thus by considering this above explanation it is clear that Option C can be consider as the opt answer

The new volume is 38 ml.

Explanation:

At NTP,

P1  = 760 mm,

P2 = 800 mm,

V1 = 40 ml

Boyle's law states that when a gas is held at a constant temperature and mass in a closed container, the volume and pressure vary inversely.

By applying Boyle's law,

                       P1  V 1  = P2  V2

where P1, P2 represents the pressure of a gas,

           V1, V2 represents the volume of a gas.

                        P1  V 1  = P2  V2

​              760×40 = 800×V  2

                          V 2   =  (760×40)  / 800

                           V2  = 38 mL.

The new volume of the gas at the increased pressure, while maintaining the same temperature, is 38 ml.

The correct formula to use in this situation is Boyle's Law, which states that for a given mass of gas at constant temperature, the pressure of the gas is inversely proportional to its volume. Mathematically, this can be expressed as:

[tex]\[ P_1V_1 = P_2V_2 \][/tex]

where [tex]\( P_1 \)[/tex] and [tex]\( V_1 \)[/tex] are the initial pressure and volume, and [tex]\( P_2 \)[/tex] and [tex]\( V_2 \)[/tex] are the final pressure and volume.

Given:

- Initial pressure, [tex]\( P_1 = 760 \)[/tex] mm Hg

- Final pressure, [tex]\( P_2 = 800 \)[/tex] mm Hg

- Initial volume, [tex]\( V_1 = 40 \)[/tex] ml

We want to find the final volume [tex]\( V_2 \)[/tex].

Using Boyle's Law:

[tex]\[ P_1V_1 = P_2V_2 \][/tex]

[tex]\[ 760 \times 40 = 800 \times V_2 \][/tex]

[tex]\[ V_2 = \frac{760 \times 40}{800} \][/tex]

[tex]\[ V_2 = \frac{30400}{800} \][/tex]

[tex]\[ V_2 = 38 \text{ ml} \][/tex]

Answer:

The temperature remains

Explanation:

The temperature of a boiling substance remains the same because the extra energy is used in phase transition, that is to break the bonds between the molecules that hold them close together in the liquid state. With increased energy the molecules gain enough kinetic energy to overcome inter-molecular   forces and change state from liquid to gas

The mass of water that should be added to 22.0 g of KCl to make a 5.50% by mass solution is 488.9 g.

To calculate the mass of water to be added, we can use the concept of mass percent. The mass percent is the mass of the solute divided by the mass of the solution, multiplied by 100%. We can set up the following equation:
Mass of KCl / (Mass of KCl + Mass of Water) = 5.50%
Let's solve for the mass of water:
Mass of Water = Mass of KCl / (0.055 - 1)
Mass of Water = 22.0 g / 0.045
Mass of Water = 488.9 g
Therefore,

488.9 g of water

should be added to 22.0 g of KCl to make a 5.50% by mass solution.

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Answer:

D alpha particles

Explanation:

Radioactive U-238 will decay into Thorium -232 by emitting alpha particles in the process of nuclear fission.

Nuclear fission is the radioactive decay process in which a heavy nucleus spontaneously disintegrates into two lighter ones and several other particles with a large release of energy.

     U-238      →     Th-232 + alpha particles +  2 neutrons + energy

This way the mass and atomic numbers are conserved;

Answer:

The equation is balanced

Explanation:

Before a equation can be said to be balanced the number of mole at the reaction side must be equal to number mole at the product side

Let's start with Zn at the reactant side 4 moles of Zn reacts and 4 moles of Zn was obtained from the product side which makes it balanced

Let's take HNO3

For H,10 moles react and 10 moles was obtained in the product side

For N,10 moles react and 8 moles was obtained initially and 2 moles was obtained as well which makes it 10 moles and it makes it balanced

For O,30 moles react and after calculating the total amount of O at the product side it was observed to be 30 which indicates that the equation is balanced...

The equation is absolutely well balanced

Answer:

Calcium oxide is ionic in nature. The Ca-O bond in CaO is formed by the transfer of electron from highly electropositive Ca to the highly electronegative oxygen atom.  The electronegativity difference should be high for the formation of ionic bond.

Explanation:

The ionic compound contains one highly electronegative atom and one highly electropositive atom. The ionic bond is formed by the transfer of electron from the more electropositive atom to electronegative atom.

In calcium oxide , Calcium is alkaline earth metal and it is highly electropositive atom while oxygen is highly electronegative atom. Calcium will transfer its 2 valence electrons to the oxygen atom. The electronegativity difference between calcium and oxygen is greater than 2.0. Hence, the bond in CaO is found to be ionic in nature.

CaO contains an ionic bond because calcium loses electrons to form a cation, and oxygen gains these electrons to form an anion. This electron transfer creates a strong attraction between the ions due to their opposite charges.

The compound CaO contains an ionic bond because of the difference in electronegativity between calcium (Ca) and oxygen (O). Calcium has a low electronegativity and tends to lose its two valence electrons easily, forming a [tex]Ca^{2+[/tex]  cation. Oxygen, having a much higher electronegativity, readily attracts these two electrons to complete its valence shell, forming an [tex]O^{2-[/tex] anion.

This transfer of electrons from calcium to oxygen results in the formation of ions, which attract each other due to opposite charges, resulting in a strong ionic bond that holds the CaO compound together. This bond is characteristic of the interaction between a metal like calcium (with low electronegativity) and a non-metal like oxygen (with high electronegativity).

Peloponnese: The mountainous southern peninsula of Greece, connected to central Greece by the Isthmus of Corinth. Greek name Pelopónnisos.

Answer:

A Peninsula

Explanation:

The Peloponnese is a peninsula and geographic region in southern Greece. It is connected to the central part of the country by the Isthmus of Corinth land bridge which separates the Gulf of Corinth from the Saronic Gulf. During the late Middle Ages and the Ottoman era, the peninsula was known as the Morea, a name still in colloquial use in its demotic form.

The peninsula is divided among three administrative regions: most belongs to the Peloponnese region, with smaller parts belonging to the West Greece and Attica regions.

Answer:

322.1262g

Explanation:

This question is mole to mole reaction but the answer should be in gram.

4moles of Al gives 2 moles of Al2O3

3.1581 moles of Al gives x moles of Al2O3

Cross multiply

4x= 3.1581×2

4x=6.3162

X=6.3162/4

X=1.57905moles

To convert to gram

Moles ×molar mass

Molar mass of Al2O3 is 204g

Which means 1.57905×204= 322.1262g

Answer:

B

Explanation:

The sun can be dangerous but it also helps our Earth in a lot of ways

Final answer:

Answer C is true: The sun is critical for life on Earth, affecting natural cycles and providing necessary energy, but its UV rays can also be harmful to health and influence Earth's climate.

Explanation:

The correct answer is C: The sun is very important, but its rays can also be harmful. The sun radiates light and heat which are essential for the existence of life on Earth. It plays a crucial role in various natural cycles, such as those that regulate climate and weather, and it has enabled the development of all life forms as we know them. However, it is also true that the sun can be dangerous due to its intense ultraviolet (UV) rays, which can cause skin cancer, cataracts, and other health issues. Moreover, changes in the sun's energy can influence Earth's climate, potentially leading to warming or cooling periods.

Answer: 120.15

Explanation:

Answer:

120.15

Explanation:

Look at the periodic table

The net force is the vector sum of all the forces acting on an object. If the net force is not zero, it means the forces are unbalanced. In this case, the net force is 303 N.

The net force is the vector sum of all the forces acting on an object. If the net force is zero, it means the forces are balanced and there is no change in the object's motion. If the net force is not zero, it means the forces are unbalanced and there will be an acceleration or deceleration of the object.

In this case, we have two forces given - 128 N and 175 N. To determine if the net force is balanced or unbalanced, we need to find the sum of these forces. Adding 128 N and 175 N gives us a net force of 303 N. Since the net force is not zero, the forces are unbalanced.

Final answer:

To calculate the standard reduction potential for each metal and organize them into a standard reduction table, we can use the formula Ecell = Ered - Eox. The standard potential for Q is -0.38V and for G is +0.72V.

Explanation:

To calculate the standard reduction potential for each metal, we can use the formula Ecell = Ered - Eox. Given the reduction potentials for Q and G, we can assume the reduction potential for Q is +0.38V and the reduction potential for G is -0.72V. Since Q is oxidized when connected to the standard hydrogen electrode, its standard potential is negative (-0.38V). On the other hand, since G is reduced when connected to the standard hydrogen electrode, its standard potential is positive (+0.72V).

Organizing the metals into a standard reduction table:

MetalStandard Reduction Potential (E°)Q-0.38VG+0.72V

Metal B has the highest standard reduction potential (0.85 V), and metal E follows closely (0.63 V). B-E galvanic cell would yield the highest potential due to their strong reduction tendencies.

To calculate the standard reduction potential for each metal, you can use the Nernst equation:

[tex]E_{\text {cell }}^{\circ}=E_{\text {cathode }}^{\circ}-E_{\text {anode }}^{\circ}[/tex]

where [tex]E_{\text {cell }}^{\circ}[/tex] is the standard cell potential, [tex]E_{\text {cathode }}^{\circ}[/tex] is the standard reduction potential of the cathode, and [tex]E_{\text {anode }}^{\circ}[/tex] is the standard oxidation potential of the anode.

First, let's assign oxidation numbers and write the balanced half-reactions for each cell:

1. [tex]\mathrm{A}(\mathrm{s})+\mathrm{B}^{2+}(\mathrm{aq}) \rightarrow \mathrm{A}^{2+}(\mathrm{aq})+\mathrm{B}(\mathrm{s})[/tex]

Reduction half-reaction: [tex]\mathrm{B}^{2+}(\mathrm{aq})+2 e^{-} \rightarrow \mathrm{B}(\mathrm{s})[/tex]

[tex]E_{\text {cathode }}^{\circ}[/tex] = 0.85

[tex]E_{\text {anode }}^{\circ}[/tex] = 0

2. [tex]\mathrm{B}^{2+}(\mathrm{aq})+\mathrm{C}(\mathrm{aq}) \rightarrow \mathrm{B}(\mathrm{s})+\mathrm{C}^{2+}(\mathrm{aq})[/tex]

Reduction half-reaction: [tex]\mathrm{C}(\mathrm{aq})+2 e^{-} \rightarrow \mathrm{C}^{2+}(\mathrm{aq})[/tex]

[tex]E_{\text {cathode }}^{\circ}[/tex] = −0.24

[tex]E_{\text {anode }}^{\circ}[/tex] = 0

3. [tex]2 \mathrm{D}^{+}(\mathrm{aq})+\mathrm{C}(\mathrm{s}) \rightarrow 2 \mathrm{D}(\mathrm{s})+\mathrm{C}^{2+}(\mathrm{aq})[/tex]

Reduction half-reaction: [tex]\mathrm{C}(\mathrm{s})+2 e^{-} \rightarrow \mathrm{C}^{2+}(\mathrm{aq})[/tex]

[tex]E_{\text {cathode }}^{\circ}[/tex] = 0

[tex]E_{\text {anode }}^{\circ}[/tex] = 0.58

4. [tex]\mathrm{B}(\mathrm{s})+\mathrm{B}^{2+}(\mathrm{aq}) \rightarrow \mathrm{B}^{2+}(\mathrm{aq})+\mathrm{B}(\mathrm{s})[/tex]

Reduction half-reaction: [tex]\mathrm{B}^{2+}(\mathrm{aq})+2 e^{-} \rightarrow \mathrm{B}(\mathrm{s})[/tex]

[tex]E_{\text {cathode }}^{\circ}[/tex] = 0

[tex]E_{\text {anode }}^{\circ}[/tex] = 0

5. [tex]\mathrm{B}(\mathrm{s})+\mathrm{E}^{2+}(\mathrm{aq}) \rightarrow \mathrm{B}^{2+}(\mathrm{aq})+\mathrm{E}(\mathrm{s})[/tex]

Reduction half-reaction:  [tex]\mathrm{E}^{2+}(\mathrm{aq})+2 e^{-} \rightarrow \mathrm{E}(\mathrm{s})[/tex]

[tex]E_{\text {cathode }}^{\circ}[/tex] = 0.63

[tex]E_{\text {anode }}^{\circ}[/tex] = 0

Now, let's calculate the standard reduction potentials for each metal:

[tex]\begin{aligned}& E_{\mathrm{B}}^{\circ}=0.85-0=0.85 \\& E_{\mathrm{C}}^{\circ}=-0.24-0=-0.24 \\& E_{\mathrm{D}}^{\circ}=0-0.58=-0.58 \\& E_{\mathrm{B}}^{\circ}=0 \\& E_{\mathrm{E}}^{\circ}=0.63-0=0.63\end{aligned}[/tex]

The two metals that would produce the highest cell potential in a galvanic cell are the ones with the highest standard reduction potentials. In this case, metals B and E have the highest reduction potentials, so a galvanic cell composed of B and E would have the highest cell potential. The reason is that a higher standard reduction potential indicates a stronger tendency to be reduced, and therefore, a higher cell potential in a galvanic cell.

Answer:

The volume of the sample of the gas is found to be 12.90 L.

Explanation:

Given pressure of the gas = P = 1.10 atm

Number of moles of gas = n = 0.6000 mole

Temperature = T = 288.15 K

Assuming the volume of the gas to be V liters

The ideal gas equation is shown below

[tex]\textrm{PV} =\textrm{nRT} \\1.10 \textrm{ atm}\times V \textrm{ L} = 0.6000 \textrm{ mole}\times 0.0821 \textrm{ L.atm.mol}^{-1}.K^{-1}\times 288.5\textrm{K} \\\textrm{V} = 12.90 \textrm{ L}[/tex]

Volume occupied by gas = 12.90 L

Answer:

V = 479.6 mL

Explanation:

assuming ideal gas:

∴ T = 25.2°C ≅ 298.2 K.........remains constant

∴ P1 = 637 torr = 0.8382 atm

∴ V1 = 536 mL = 0.536 L

∴ R = 0.082 atm.L/K.mol

⇒ n = (P1V1)/(RT) = ((0.8382 atm)*(0.536 L))/((0.082 atmL/Kmol)*(298.2K))

⇒ n = 0.0184 mol......remains constant

∴ P2 = 712 torr = 0.936842 atm

⇒ V2 = RTn/P2 = [(0.082atmL/Kmol)*(298.2K)*(0.0184mol)]/(0.936842atm)

⇒ V2 = 0.4796 L

Boyle's Law can be applied in this situation to show that when pressure on a gas sample increases, its volume decreases, assuming a constant temperature. By substituting the given values into the Boyle's Law formula, we find that the new volume, with increased pressure, is approximately 478 mL.

The volume of gas changing with pressure can be explained by Boyle's Law, which states that the pressure and volume of a gas have an inverse relationship when temperature is held constant. In this case, we can set up an equation based on Boyle's Law (P1V1 = P2V2), where P1 and V1 represent the initial pressure and volume, and P2 and V2 represent the final pressure and volume.

To solve for V2, you can rearrange the formula to: V2 = (P1V1) / P2. Substituting the given values into the formula:
V2 = (637 torr * 536 mL) / 712 torr =  478 mL approximately.

So, if the pressure is increased to 712 torr, the volume of the gas decreases to roughly 478 ml.

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Answer: A

Explanation:

Balancing a chemical reaction, we must take into consideration every element both at the reactant and products side.

Since we were told propane reacts with oxygen to produce steam and carbon dioxide, we already have an idea of how the equation would be just remaining balancing the stoichiometry of the equation.

C3H8 + 5O2 =====》 3CO2 + 4H20

From the equation above,

3 atoms of carbon is present at reactant side and 3 carbon is also at the product side.

8 Hydrogen at reactant = 4 * 2 Hydrogen at product.

10 Oxygen at reactant = 3*2 + 4 oxygen at product

The equation must be balanced because law of conservation of matter must take place in every chemical reaction, matter can neither be created nor destroyed but can change form.

Answer:

A

Explanation:

Propane burns in oxygen to produce carbon dioxide and steam. The chemical equation is written with chemical symbols below:

C3H8 + O2  CO2 + H2O

There are three carbon atoms on the left side, but only one on the right, so we need to put a 3 in front of the carbon dioxide molecule to give three carbons on each side:

C3H8 + O2  3CO2 + H2O

There are eight hydrogen atoms on the left side and two on the right side, so we need to place a 4 in front of the water molecules on the right side:

C3H8 + O2  3CO2 + 4H2O

There are 2 oxygen atoms on the left side and 10 on the right side, so we need to place a 5 in front of the oxygen molecule on the left side:

C3H8 + 5O2  3CO2 + 4H2O

The equation has been balanced.

Answer:

aluminum

Explanation:

i took the test

Answer:How it indicates the health of the environment is when the less food, shelter, and mates cause population reduction and if nothing done to stop (or reduce) the amount of thing being taken away they could go extincted.

Explanation:           Read above    /\

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Magnesium and calcium are more reactive with oxygen in the air than aluminum.

Magnesium and calcium are more reactive with oxygen in the air than aluminum.

Magnesium reacts with oxygen to form magnesium oxide (MgO), while calcium reacts with oxygen to form calcium oxide (CaO). Aluminum also reacts with oxygen, but it forms a thin layer of aluminum oxide (Al2O3) on its surface, which acts as a protective barrier to further reaction. This layer prevents aluminum from reacting as readily with oxygen compared to magnesium and calcium. Therefore, magnesium and calcium are more reactive with oxygen in the air than aluminum.

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