Predict the products for each of the following Diels–Alder reactions: (a) COOH HOOC + (b) HOOC CN + (c) O O + (d) S O O O + (e) CN NC + (f ) O O O O S MeO OMe + 16.43

Answers

Answer 1

Answer:

see explanation below

Explanation:

You are not putting all the structures correctly. Luckily I found the question on another place, so the complete structures you can see them in picture 1.

Now, according to the picture 1, we have all the six reactions. The general mechanism is the same for all and then, if you can have the possibility to rearrange the molecule, you can do that too.

Now, the general mechanism as I stated earlier is the same. The double bond from the diene (The one with one double bond at least) attacks the dienophyle (The first double bond), this bond do resonance to the conjugate bond, and the other double bond attacks the diene, and form a new product.

According to this, the product for each reaction, you can see it in picture 2 and 3:

Predict The Products For Each Of The Following DielsAlder Reactions: (a) COOH HOOC + (b) HOOC CN + (c)
Predict The Products For Each Of The Following DielsAlder Reactions: (a) COOH HOOC + (b) HOOC CN + (c)
Predict The Products For Each Of The Following DielsAlder Reactions: (a) COOH HOOC + (b) HOOC CN + (c)
Answer 2
Final answer:

In Diels-Alder reactions, a diene reacts with a dienophile to form a cyclic compound. Only reactions (b) and (e) will result in Diels-Alder adducts.

Explanation:

In order to predict the products of the given Diels-Alder reactions, we need to identify the diene and dienophile components. The diene is usually a compound containing two double bonds, while the dienophile is a compound with a double bond. The reaction between the diene and dienophile will form a cyclic compound known as the Diels-Alder adduct. Let's examine each reaction:

(a) COOH + HOOC: Neither COOH nor HOOC contain diene or dienophile functionality, so no Diels-Alder reaction will occur.

(b) HOOC + CN: This reaction involves a diene (HOOC) and a dienophile (CN). The Diels-Alder adduct will be formed.

(c) O + O: Neither O nor O contain diene or dienophile functionality, so no Diels-Alder reaction will occur.

(d) S + OOO: Both S and OOO contain diene functionality, but no dienophile. Therefore, a Diels-Alder reaction will not occur.

(e) CN + NC: This reaction involves a diene (CN) and a dienophile (NC). The Diels-Alder adduct will be formed.

(f) OOO S MeO OMe: Neither OOO nor S MeO OMe contain diene or dienophile functionality, so no Diels-Alder reaction will occur.


Related Questions

Sulfuric acid is essential to dozens of important industries from steelmaking to plastics and pharmaceuticals. More sulfuric acid is made than any other industrial chemical, and world production exceeds per year. The first step in the synthesis of sulfuric acid is usually burning solid sulfur to make sulfur dioxide gas. Suppose an engineer studying this reaction introduces of solid sulfur and of oxygen gas at into an evacuated tank. The engineer believes for the reaction at this temperature. Calculate the mass of solid sulfur he expects to be consumed when the reaction reaches equilibrium. Round your answer to significant digits.

Answers

The question is incomplete, here is the complete question:

Sulfuric acid is essential to dozens of important industries from steel making to plastics and pharmaceuticals. More sulfuric acid is made than any other industrial chemical, and world production exceeds [tex]2.0\times 10^{11}[/tex] per year.

The first step in the synthesis of sulfuric acid is usually burning solid sulfur to make sulfur dioxide gas. Suppose an engineer studying this reaction introduces 4.4 kg of solid sulfur and 6.90 atm of oxygen gas at 950°C into an evacuated 50.0 L tank. The engineer believes [tex]K_p=0.71[/tex] for the reaction at this temperature.

Calculate the mass of solid sulfur he expects to be consumed when the reaction reaches equilibrium. Round your answer to 2 significant digits.

Answer: The mass of sulfur that is expected to be consumed is 0.046 kg

Explanation:

We are given:

Initial partial pressure of oxygen gas = 6.90 atm

The chemical equation for the formation of sulfur dioxide follows:

                  [tex]S(s)+O_2(g)\rightleftharpoons SO_2(g)[/tex]

Initial:                  6.90  

At eqllm:             6.90-x         x

The expression of [tex]K_p[/tex] for above equation follows:

[tex]K_p=\frac{p_{SO_2}}{p_{O_2}}[/tex]

We are given:

[tex]K_p=0.71[/tex]

Putting values in above equation, we get:

[tex]0.71=\frac{x}{(6.9-x)}\\\\x=2.9[/tex]

So, equilibrium partial pressure of sulfur dioxide = x = 2.9 atm

To calculate the number of moles, we use the equation given by ideal gas, which follows:

PV = nRT

where,

P = pressure of sulfur dioxide gas = 2.9 atm

V = volume of the container = 50.0 L

n = number of moles of sulfur dioxide gas = ?

R = [tex]0.0821\text{ L. atm }mol^{-1}K^{-1}[/tex]

T = temperature of the container = [tex]950^oC=[950+273]K=1223K[/tex]

Putting values in above equation, we get:

[tex]2.9\times 50.0=n\times 0.0821\times 1223\\\\n=\frac{2.9\times 50.0}{0.0821\times 1223}=1.44mol[/tex]

Moles of sulfur dioxide = 1.44 moles

By Stoichiometry of the reaction:

1 mole of sulfur dioxide is produced from 1 mole of sulfur

So, 1.44 moles of sulfur dioxide will be produced from [tex]\frac{1}{1}\times 1.44=1.44mol[/tex] of sulfur

To calculate the mass of a substance, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]

Moles of sulfur = 1.44 moles

Molar mass of sulfur = 32 g/mol

Putting values in above equation, we get:

[tex]1.44mol=\frac{\text{Mass of sulfur}}{32g/mol}\\\\\text{Mass of sulfur}=(1.44mol\times 32g/mol)=46.08g=0.046kg[/tex]

Hence, the mass of sulfur that is expected to be consumed is 0.046 kg

The pH of a 0.23M solution of acrylic acid HC3H3CO2 is measured to be 2.44. Calculate the acid dissociation constant Ka of acrylic acid. Round your answer to 2 significant digits. Step by step would be helpful...

Answers

Answer:

Kₐ =  5.7 x 10⁻⁵

Explanation:

The equilbrium for this acid is

HC₃H₃CO₂ + H2O    ⇄ H₃O⁺  +   C₃H₃CO₂ ⁻  ,

and the equilibrium constant for acrylic acid is given by the expression:

Kₐ = [ H₃O⁺][ C₃H₃CO₂⁻ ] / [ HC₃H₃CO₂ ]

Since  the pH of the 0.23 M solution is known , we can calculate [ H₃O⁺].

The ][ C₃H₃CO₂⁻ ]  is equal to  [ H₃O⁺] from the above equilibria (1:1)

Finally [ HC₃H₃CO₂ ] is known.

pH = - log  [ H₃O⁺]

taking antilog to both sides of the equation

10^-pH =  [ H₃O⁺]

Substituting

10^-2.44 =  [ H₃O⁺]  = 3.6 x 10⁻³

[ C₃H₃CO₂⁻ ] = 3.6 x 10⁻³

Kₐ = ( 3.6 x 10⁻³ ) /0 .23 = 5.7 x 10⁻⁵

Final answer:

To find the Ka of acrylic acid, we use the measured pH to find [H+], set up an ICE table for the dissociation equilibrium, and solve for Ka, which is approximately 5.8 x 10^{-5} when rounded to two significant digits.

Explanation:

To calculate the acid dissociation constant (Ka) of acrylic acid, we start by using the pH given. The pH is defined as the negative logarithm of the hydrogen ion concentration ([H+]), which can be represented as pH = -log[H+]. From the pH of 2.44, we find the concentration of hydrogen ions:

[H+] = 10^{-pH} = 10^{-2.44} ≈ 3.63 × 10^{-3} M

Given that acrylic acid (HC3H3CO2) is a weak acid and only partially dissociates in a solution, we can represent its dissociation as follows:

HC3H3CO2(aq) ⇌ H+(aq) + C3H3CO2⁻(aq)

The ICE table approach details the initial concentrations, the change in concentrations, and the final concentrations. For acrylic acid, we get:

Initial: [HC3H3CO2] = 0.23 M, [H+] = 0, [C3H3CO2⁻] = 0Change: [HC3H3CO2] decreases by x, [H+] increases by x, [C3H3CO2⁻] increases by xEquilibrium: [HC3H3CO2] = 0.23-x M, [H+] = x , [C3H3CO2⁻] = x

Since the pH corresponds to the hydrogen ion concentration at equilibrium, we also know that x (the increase in [H+]) is equal to 3.63 × 10^{-3} M. Now we can calculate the Ka using the equilibrium expressions:

Ka = \frac{[H+][C3H3CO2⁻]}{[HC3H3CO2]}

Assuming x is small compared to the initial concentration, we can simplify [HC3H3CO2] to be approximately equal to 0.23 M:

Ka ≈ \frac{(3.63 × 10^{-3})^2}{0.23}

Thus, Ka ≈ 5.76 × 10^{-5}. Rounded to two significant digits, Ka ≈ 5.8 × 10^{-5}.

Below is the Lewis structure of the hydrogen peroxide (H202) molecule. H: O:O:H Count the number of bonding pairs and the number of lone pairs around the right oxygen atom. bonding pairs:

Answers

Idek what would be the point

The two bonding pairs and two lone pairs on each oxygen atom in the Lewis structure of hydrogen peroxide (H₂O₂) molecule.

What is the lewis electron dot diagram?

A lewis structure can be used to represent the number of chemical bonds, the bonding atoms, and the lone pairs reaming on the atoms in a given molecule.

Lines are used to showing the bonds between atoms that are bonded to one another and lone pairs are depicted as dot pairs and are placed next to the respective atoms. As the valence electrons of each oxygen atom are equal to six from the electronic configuration of the oxygen atom.

From the lewis structure of hydrogen peroxide, we can see that each oxygen atom form one bond with a hydrogen atom and another bond with an oxygen atom. The two lone pairs are still present on each oxygen atom in the molecule.

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By titration, it is found that 65.5 mL of 0.117 M NaOH ( aq ) is needed to neutralize 25.0 mL of HCl ( aq ) . Calculate the concentration of the HCl solution.

Answers

Answer:

0.30 M  

Explanation:

In case of titration , the following formula can be used -

M₁V₁ = M₂V₂

where ,

M₁ = concentration of acid ,  

V₁ = volume of acid ,  

M₂ = concentration of base,  

V₂ = volume of base .

from , the question ,

M₁ = ? M

V₁ = 25.0 mL

M₂ = 0.117 M

V₂ = 65.5 mL

Using the above formula , the molarity of acid , can be calculated as ,

M₁V₁ = M₂V₂

Putting the respective values  -

M₁ * 25.0mL =  0.117 M  * 65.5 mL  

M₁ = 0.30 M

What mass (in g) of KIO3 is needed to prepare 50.0 mL of 0.20 M KIO3? b) What volume (in mL) of 0.15 m H2SO4 is needed to prepare 50.0 mL of 0.080 M H2SO4?

Answers

Final answer:

To prepare a 0.20 M KIO3 solution, 2.14 g of KIO3 is required for 50.0 mL. For the 0.080 M H2SO4 solution, 26.7 mL of 0.15 M H2SO4 is needed to dilute to 50.0 mL.

Explanation:

To calculate the mass (in g) of KIO3 needed to prepare 50.0 mL of a 0.20 M solution, use the formula:

mass = molarity × volume × molar mass

We begin by calculating the moles of KIO3 needed:

Moles of KIO3 = Molarity × Volume (in L)

= 0.20 mol/L × 0.0500 L = 0.010 moles of KIO3

The molar mass of KIO3 is K (39.10 g/mol) + I (126.90 g/mol) + 3×O (3× 16.00 g/mol) = 214.00 g/mol.

Now calculate the mass:

Mass of KIO3 = Moles × Molar Mass

= 0.010 moles × 214.00 g/mol = 2.14 g

For the second part, to find the volume (in mL) of 0.15 M H2SO4 needed to prepare 50.0 mL of a 0.080 M solution, we use the dilution formula:

M1V1 = M2V2, where M is molarity and V is volume.

The initial molarity (M1) is 0.15 M, the final molarity (M2) is 0.080 M, and the final volume (V2) is 50.0 mL. We solve for V1:

V1 = (M2V2) / M1

= (0.080 M × 50.0 mL) / 0.15 M = 26.7 mL

Accordingly, you would need 26.7 mL of the 0.15 M H2SO4.

What volume of propane (C3H8) is required to produce 165 liters of water according to the following reaction? (All gases are at the same temperature and pressure.) propane (C3H8) (g) + oxygen(g)carbon dioxide (g) + water(g)

Answers

Answer:

We need 41.2 L of propane

Explanation:

Step 1: Data given

volume of H2O = 165 L

Step 2:  The balanced equation

C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(g)

Step 3: Calculate moles of H2O

1 mol = 22.4 L

165 L = 7.37 moles

Step 4: Calculate moles of propane

For 1 mol C3H8 we need 5 moles O2 to produce 3 moles CO2 and 4 moles H2O

For 7.37 moles H2O we need 7.37/4 = 1.84 moles propane

Step 5: Calculate volume of propane

1 mol = 22.4 L

1.84 moles = 41.2 L

We need 41.2 L of propane

Which type of fermentation produces CO2 bubbles in baking?

a)Homolactic fermentation
b)Oxidative phosphorylation
c)Alcoholic fermentation
d)Butanediol fermentation

Answers

Alcoholic fermentation  fermentation produces CO2 bubbles in baking.

Explanation:

The other name given for the Alcoholic Fermentation is Ethanol fermentation. In this process of fermentation, ethanol and carbon dioxide are the resultant by-products. These are formed by the conversion of fructose,sucrose and glucose to cellular energy. This type of fermentation do not require oxygen for the process to take place. Hence, these are known to be an anaerobic process

This type of fermentation has its application like ethanol fuel production, cooking of bread, etc. A dough rises  of the Ethanol fermentation. this is because, the sugars that are present in a dough are absorbed by yeast . this produces ethanol and carbon dioxide. During baking process,bubbles are formed by this carbon dioxide.

Which of the following would require the largest volume of 0.100 M sodium hydroxide solution for neutralization?:

(A) 20.0 mL of 0.0500 M nitric acid
(B) 15.0 mL of 0.0500 M hydrobromic acid
(C) 5.0 mL of 0.0100 M sulfuric acid
(D) 10.0 mL of 0.00500 M phosphoric acid

Answers

Answer:10.0 mL of 0.00500 M phosphoric acid

Explanation:

If we look at the Ka values of the acids, we will realize that phosphoric acid has a Ka of 7.1 * 10-3. It is the only acid in the list having acid dissociation constant less than 1. This means that it does not ionize easily in solution and a very large volume of base must be added to ensure that it reacts completely. Acids with Ka >1 are generally regarded as strong acids. All the acids listed have Ka>1 except phosphoric acid.

Final answer:

20.0 mL of 0.0500 M nitric acid would require the largest volume of 0.100 M sodium hydroxide solution for neutralization based on calculations using molarity, volume, and the number of protons the acid can donate.

Explanation:

An acid-base neutralization reaction takes place when an acid reacts with a base to produce a salt and water. The volume of base needed to neutralize an acid depends on the molarity and volume of the acid, as well as the number of protons (H+) each acid molecule can donate.

For each option, we can calculate the number of moles of H+ using the formula: moles = Molarity * Volume(L), and then using the 1:1 stoichiometry with sodium hydroxide (NaOH) for one-proton acids, or 1:2 stoichiometry for two-proton acids.

(A) 20.0 mL of 0.0500 M nitric acid (HNO₃): 0.0500 mol/L * 0.020 L = 0.00100 mol of H+(B) 15.0 mL of 0.0500 M hydrobromic acid (HBr): 0.0500 mol/L * 0.015 L = 0.00075 mol of H+(C) 5.0 mL of 0.0100 M sulfuric acid (H₂SO₄): 2(0.0100 mol/L * 0.005 L) = 0.00010 mol of H+(D) 10.0 mL of 0.00500 M phosphoric acid (H₃PO₄): 0.00500 mol/L * 0.010 L = 0.00005 mol of H+

So, option (A) with 20.0 mL of 0.0500 M nitric acid would require the largest volume of 0.100 M sodium hydroxide solution for neutralization.

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"How would you make 100 mL of a carbonic acid buffer at 0.5 M and pH = 6.0 using 1.0 M NaHCO3 and either 1.0 M NaOH or 1.0 M HCl and water?"

Answers

Answer:

You first  start by weighing a quatity of NaHCO3 which is by calculating the molecular mass of the salt and then multiply it with the molarity given which is 0.5 M, the gram/mol gotten is then dissolve in some water, add 0.1M NaOH dropwise until the pH is 9.8. Transfer quantitatively to a 100 mL volumetric flask and dilute to the mark. Mix thoroughtly.

Explanation:

molar mass of Na HCO3= 84.01

molarity given= 0.5 M

to get the g/mol to dissolve in 1000 mL , 0.5 x 84.01 =42.005 g/mol=1 L

to get 100 mL , 42.002 divide by 10

=4.2005g/mol

Final answer:

To make a carbonic acid buffer at 0.5 M and pH 6.0, mix equal molar amounts of NaHCO3 and H2CO3. For 100 mL at 0.5 M, mix 25 mL of 1.0 M HCl with 50 mL of 1.0 M NaHCO3 and dilute to 100 mL with water.

Explanation:

To make 100 mL of a carbonic acid buffer at 0.5 M and pH = 6.0 using 1.0 M NaHCO3 and either 1.0 M NaOH or 1.0 M HCl, you first need to understand the Henderson-Hasselbalch equation:



pH = pKa + log([A-]/[HA])

For carbonic acid (pKa ≈ 6.1), when pH is 6.0:


6.0 = 6.1 + log([NaHCO3]/[H2CO3])

This suggests the ratio of [NaHCO3] to [H2CO3] should be close to 1:1. Solving for the concentrations:

log([NaHCO3]/[H2CO3]) = -0.1

[NaHCO3]/[H2CO3] ≈ 0.79

If you want a 0.5 M buffer, you'll need close to 0.25 M NaHCO3 and 0.25 M H2CO3.

To get H2CO3, you can add HCl to NaHCO3 since H2CO3 is not stable:

NaHCO3 + HCl → H2CO3 + NaCl

For 100 mL at 0.25 M, you would need 25 mmol of HCl. You would take 25 mL of 1.0 M HCl (because 25 mL × 1.0 M = 25 mmol) and add it to 50 mL of 1.0 M NaHCO3 (which provides 50 mmol NaHCO3) to keep the ratio. Then dilute to 100 mL with water.

C6H6NCl On the basis of the molecular formula, 1H NMR data, and IR data provided, propose a consistent structure.

H`NMR data: δ 300 (s, 2H), 6.57 (d, 2H), 7.05 (d, 2H)
IR data: 3400 (broad), 3250 (broad), 1590, 820 cm^(-1).

Draw your proposed structure below.

Answers

Answer:

Please refer to the attachment below.

Explanation:

Please refer to the attachment below for explanation.

Final answer:

Based on the IR and NMR data, and the molecular formula C6H6NCl, the likely structure is para-chloroaniline, which includes a benzene ring substituted with an amine group (NH2) and a chlorine atom (Cl).

Explanation:

The question involves determining the structure of a compound with the molecular formula C6H6NCl using 1H NMR and IR data. The 1H NMR data features signals at δ 300 (s, 2H), 6.57 (d, 2H), and 7.05 (d, 2H). The IR data presents broad bands at 3400 cm⁻¹ and 3250 cm⁻¹, which suggest the presence of N-H bonds, indicating an amine or amide functional group. The bands at 1590 cm⁻¹ and 820 cm⁻¹ can be indicative of an aromatic ring and substituted benzene, respectively.

Considering the molecular formula and the spectroscopy data given, a probable structure is a chloroaniline, where a benzene ring is substituted with an amine (NH2) group and a chlorine atom (Cl). The two doublets in the 1H NMR spectrum at 6.57 and 7.05 ppm suggest a para-substituted benzene ring, with each set of doublets representing the protons on either side of the substituted positions. The chemical shift at δ 300 ppm is not standard and is assumed to be a typo. Typically, for aromatic protons, shifts are in the range of 6-8 ppm. Thus, the illustrated doublets fit the pattern of para-substituted benzene.

For the data set: 0.09, 0.10, 0.11, 0.13, 0.09, 0.11, 0.10, 0.07 To obtain information of the precision of the data set the standard deviation would be:

a. 0.018
b. 0.022
c. 0.0166
d. 0.01

Answers

Answer:

Option A is correct (0.018)

S.D≅0.018

Explanation:

Option A is correct (0.018)

General Formula for Standard Deviation is:

[tex]Standard\ Deviation=\sqrt{\frac{\sum_{i=1}^{n}(x_{i}-\bar x)^2}{n-1}}[/tex]

Where:

[tex]x_{i}[/tex] is the data value

[tex]\bar x[/tex] is the mean/average of data

n is the total number of data elements

Calculating [tex]\sum_{i=1}^{n}(x_{i}-\bar x)^2}[/tex]

[tex]\bar x=\frac{0.09+0.10+ 0.11+ 0.13+ 0.09+ 0.11+ 0.10+0.07}{8} \\\bar x=0.1[/tex]

[tex]\sum_{i=1}^{n}(x_{i}-\bar x)^2}=(0.09-0.1)^2+(0.1-0.1)^2+(0.11-0.1)^2+(0.13-0.1)^2+(0.09-0.1)^2+(0.11-0.1)^2+(0.1-0.1)^2+(0.07-0.1)^2\\\sum_{i=1}^{n}(x_{i}-\bar x)^2}=2.2*10^{-3}[/tex]

Calculating n-1:

Total number of terms=8

n-1=8-1=7

Standard Deviation is:

[tex]S.D=\sqrt{\frac{2.2*10^{-3}}{7}}\\S.D=0.0177[/tex]

S.D≅0.018

A closed vessel having a volume of 1 liter holds 2.5 × 1022 molecules of carbon dioxide gas. Determine the mass of CO2 present, in kg and the number of moles, in kmol. Determine the specific volume of the CO2, in m3/kg, and the molar specific volume, in m3/kmol.

Answers

Answer:

mass = 1.8x10⁻³ kg; number of moles = 4.1x10⁻⁵ kmol; specific volume = 0.55 m³/kg; molar specific volume = 24.4 m³/kmol

Explanation:

By the Avogadro's number, 1 mol of the matter has 6.02x10²³ molecules, thus, the number of moles (n) is the number of molecules presented divided by Avogadro's number:

n = 2.5x10²²/6.02x10²³

n = 0.041 mol

n = 4.1x10⁻⁵ kmol

The molar mass of CO₂ is 44 g/mol (12 g/mol of C + 2*16g/mol of O), and the mass is the number of moles multiplied by the molar mass:

m = 0.041 mol * 44 g/mol

m = 1.804 g

m = 1.8x10⁻³ kg

The specific volume (v) is the volume (1L = 0.001 m³) divided by the mass, and it represents how much volume is presented in each part of the mass:

v = 0.001/1.8x10⁻³

v = 0.55 m³/kg

The molar specific volume (nv) is the volume divided by the number of moles, and it represents how much volume is presented in each part of the mol:

nv = 0.001/4.1x10⁻⁵

nv = 24.4 m³/kmol

The study of the chemicals and the bonds is called chemistry.

The correct answer is 24.4

What are moles?The mole is the base unit of the amount of substance in the International System of Units. It is defined as exactly [tex]6.02214076*10^{23 [/tex] elementary entities, which may be atoms, molecules, ions, or electrons.

All the data is given is as follows:-

Mass = 1.8x10⁻³Number of moles = 4.1x10⁻⁵Specific volume= 0.55 Molar specific volume = 24.4

By the Avogadro's number, 1 mole of the matter has 6.02x10²³ molecules, thus, the number of moles (n) is the number of molecules presented divided by Avogadro's number:

n = [tex]\frac{2.5*10^{22}}{{6.02*10^{23}}} [/tex]

n = 0.041 mol

n = [tex]4.1*106^{-5[/tex] kmol

The molar mass of CO₂ is 44 g/mol ([tex]12 g/mol of C + 2*16g/mol of O[/tex]), and the mass is the number of moles multiplied by the molar mass:

m = 0.041 mol * 44 g/mol

m = 1.804 g

m = [tex]1.8x10^{-3} kg[/tex]

The specific volume (v) is the volume (1L = 0.001 m³) divided by the mass, and it represents how much volume is presented in each part of the mass:

v = [tex]\frac{0.001}{1.8*10^{-3}}[/tex]

v = 0.55 m³/kg

The molar specific volume (nv) is the volume divided by the number of moles, and it represents how much volume is presented in each part of the mol:

nv = 0.001/4.1x10⁻⁵

nv = 24.4 m³/kmol

Hence, the correct answer is 24.4.

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The Thompson analogy titled "The Carpet-Seed Children Analogy" attempts to deal with the issue of failed ____________________(A) fertilization(B) intercourse(C) conception(D) contraception

Answers

The Thompson analogy of the carpet seed children analogy has been based on the faulty contraceptive analogy for abortion. Thus, option D is correct.

Thompson's analogy of "The Carpet-Seed Children Analogy" has dealt with the failed pregnancy issues. Reproduction has been the process of the fusion of the gametes and the development of the zygote into the child.

The reproduction takes place inside the uterus of the female and has been termed pregnancy. There have been several complications with the pregnancy that leads to the abortion of the child.

The Thompson analogy of the carpet seed children analogy has been based on the faulty contraceptive analogy for abortion. Thus, option D is correct.

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The critical temperature at which steel trusses can fail from exposure to heat alone without any flames is

Answers

Answer: 1000°F

Explanation:

As heat starts to attack the steel trusses, the steel will fail without flame at 1000°F

Can you help with part B

Part A

Acetylene, C2H2, can be converted to ethane, C2H6, by a process known as hydrogenation. The reaction is

C2H2(g)+2H2(g)⇌C2H6(g)

Given the following data at standard conditions (all pressures equal to 1 atm and the common reference temperature 298 K), what is the value of Kp for this reaction?

Substance ΔG∘f
(kJ/mol)
C2H2(g) 209.2
H2(g) 0
C2H6(g) −32.89
Express your answer using two significant figures.

Kp =
2.7×1042

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Correct

Based on the magnitude of K, we know that this reaction has practically gone to completion at equilibrium.

Standard versus Nonstandard Conditions

In Part A, we saw that ΔG∘=−242.1 kJ for the hydrogenation of acetylene under standard conditions (all pressures equal to 1 atm and the common reference temperature 298 K). In Part B, you will determine the ΔG for the reaction under a given set of nonstandard conditions.

Answers

Answer:

[tex]\delta G= -261.2kg[/tex] for the reaction under a given set of nonstandard conditions.

Explanation:

[tex]C_{2}H_6(g) + 2H_2(g)\rightleftharpoons C_2H_6(g)[/tex]

[tex]Q_p = \frac{P_c_2H_6}{P_c_2H_2\timesP_H_2}[/tex]

    = [tex]\frac{3.25\times10^-2}{4.25\times4.15}[/tex]

[tex]Q_p[/tex] = [tex]4.44 \times 10^-4[/tex]

[tex]\delta G =\delta G^0 + RTlnQ_P[/tex]

     = [tex]-242.1+8.314\times10^-3\times298\timesln(4.44\times10^-4)[/tex]

     = [tex]\delta G= -261.2kg[/tex]

So,  [tex]\delta G= -261.2kg[/tex]

Student mixed 25.0 mL of 0.100 M glucose, 15.0 mL of 0.500 M NaCl and 450. mL water. What are concentrations in his solution?

Answers

The question is incomplete, here is the complete question:

Student mixed 25.0 mL of 0.100 M glucose, 15.0 mL of 0.500 M NaCl and 450. mL water. What are concentrations in his solution?

A. 5.10 mM glucose, 15.3 mM NaCl

B. 5.56 mM glucose, 16.7 mM NaCl

C. 0.556 mM glucose, 0.167 mM NaCl

D. 0.222 mM glucose, 1.11 mM NaCl

E. 0.556 mM glucose, 0.0667 mM NaCl

Answer: The concentration of glucose and NaCl in the solution is 5.10 mM and 15.3 mM respectively.

Explanation:

To calculate the number of moles for given molarity, we use the equation:

[tex]\text{Molarity of the solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (in mL)}}[/tex]    .....(1)

For glucose:

Molarity of glucose solution = 0.100 M

Volume of solution = 25.0 mL

Putting values in equation 1, we get:

[tex]0.100M=\frac{\text{Moles of glucose}\times 1000}{25.0}\\\\\text{Moles of glucose}=\frac{(0.100\times 25.0)}{1000}=0.0025mol[/tex]

For NaCl:

Molarity of NaCl solution = 0.500 M

Volume of solution = 15.0 mL

Putting values in equation 1, we get:

[tex]0.500M=\frac{\text{Moles of NaCl}\times 1000}{15.0}\\\\\text{Moles of NaCl}=\frac{(0.500\times 15.0)}{1000}=0.0075mol[/tex]

Total volume of solution = 25.0 + 15.0 + 450. = 490. mL

Now, calculating the concentration of glucose and NaCl in the solution by using equation 1:

Using conversion factor:  1 M = 1000 mM

For glucose:

Moles of glucose = 0.0025 moles

Volume of solution = 490. mL

Putting values in equation 1, we get:

[tex]\text{Concentration of glucose}=\frac{0.0025\times 1000}{490}\\\\\text{Concentration of glucose}=0.0051M=5.10mM[/tex]

For NaCl:

Moles of NaCl = 0.0075 moles

Volume of solution = 490. mL

Putting values in equation 1, we get:

[tex]\text{Concentration of NaCl}=\frac{0.0075\times 1000}{490}\\\\\text{Concentration of NaCl}=0.0153M=15.3mM[/tex]

Hence, the concentration of glucose and NaCl in the solution is 5.10 mM and 15.3 mM respectively.

his is the chemical formula for chromium(III) nitrate: . Calculate the mass percent of oxygen in chromium(III) nitrate. Round your answer to the nearest percentage.

Answers

Mass percent is a technique of expressing or defining a concentration or a component in a combination. The mass percent of oxygen in chromium(III) nitrate is approximately 60.5%.

To calculate the mass percent of oxygen in chromium(III) nitrate (Cr(NO₃)₃), we need to determine the molar mass of the compound and the molar mass of the oxygen atoms in the compound.

The molar mass of Cr(NO₃)₃ can be calculated by adding the molar masses of the individual atoms in the compound:

Molar mass of Cr(NO₃)₃ = (1 x molar mass of Cr) + (3 x molar mass of N) + (9 x molar mass of O)

Molar mass of Cr(NO₃)₃ = (1 x 52.00 g/mol) + (3 x 14.01 g/mol) + (9 x 16.00 g/mol)

Molar mass of Cr(NO₃)₃ = 238.03 g/mol

The molar mass of the oxygen atoms in Cr(NO₃)₃ can be calculated by multiplying the molar mass of oxygen by the number of oxygen atoms in the compound:

Molar mass of O in Cr(NO₃)₃ = 16.00 g/mol x 9

Molar mass of O in Cr(NO₃)₃ = 144.00 g/mol

To calculate the mass percent of oxygen in Cr(NO₃)₃, we can use the formula:

The mass percent of oxygen = (mass of O in compound / molar mass of compound) x 100%

Mass percent of oxygen = (144.00 g/mol / 238.03 g/mol) x 100%

The mass percent of oxygen ≈ 60.5%

Therefore, the mass percent of oxygen in chromium(III) nitrate is approximately 60.5%.

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Final answer:

To calculate the mass percent of oxygen in chromium(III) nitrate, we need to determine the molar mass of the compound and the molar mass of oxygen. The molar mass of Cr(NO3)3 is calculated to be 291.97 g/mol. The mass percent of oxygen in chromium(III) nitrate is approximately 55.24%.

Explanation:

To calculate the mass percent of oxygen in chromium(III) nitrate, we need to determine the molar mass of the compound and the molar mass of oxygen. The formula for chromium(III) nitrate is Cr(NO3)3.



The molar mass of Cr(NO3)3 can be calculated as follows:
Molar mass of Cr = 51.996 g/mol
Molar mass of N = 14.007 g/mol
Molar mass of O = 15.999 g/mol

Molar mass of Cr(NO3)3 = (51.996 g/mol) + 3*(14.007 g/mol) + 9*(15.999 g/mol) = 291.97 g/mol



The molar mass of oxygen is 15.999 g/mol. The mass percent of oxygen in chromium(III) nitrate can be calculated as:
Mass percent of O = (mass of O / molar mass of Cr(NO3)3) * 100%
Mass percent of O = (9*(15.999 g/mol) / 291.97 g/mol) * 100% = 55.24%

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A student wants to make a 0.150 M aqueous solution of silver nitrate, AgNO3, and has a bottle containing 11.27 g of silver nitrate. What should be the final volume of the solution

Answers

Answer:

V = 0.44 L

Explanation:

Moles is denoted by given mass divided by the molecular mass ,

Hence ,

n = w / m

n = moles ,

w = given mass ,

m = molecular mass .

From the question ,

w = 11.27 g

m ( for AgNO₃ ) =  169.87 g/mol

Hence , the moles can be calculated as -

n = w / m

n = 11.27 g / 169.87 g/mol

n = 0.066 mol

Molarity -

Molarity of a substance , is the number of moles present in a liter of solution .

M = n / V

M = molarity

V = volume of solution in liter ,

From the question ,

M = 0.150 M

n = 0.066 mol ( calculated above )

The final volume of the solution can be calculated by using the above equation ,

M = n / V  

0.150 M = 0.066 mol / V

V = 0.44 L

The correct final volume of the solution is 1.00 L.

To find the final volume of the solution, we need to use the formula for molarity (M), which is given by:

[tex]\[ M = \frac{\text{moles of solute}}{\text{liters of solution}} \][/tex]

 First, we calculate the moles of silver nitrate (AgNO3) using the given mass and the molar mass of AgNO3. The molar mass of AgNO3 is 169.87 g/mol, which is the sum of the atomic masses of silver (Ag, 107.87 g/mol), nitrogen (N, 14.01 g/mol), and three times the atomic mass of oxygen (O, 16.00 g/mol):

[tex]\[ \text{moles of AgNO3} = \frac{\text{mass of AgNO3}}{\text{molar mass of AgNO3}} \][/tex]

[tex]\[ \text{moles of AgNO3} = \frac{11.27 \text{ g}}{169.87 \text{ g/mol}} \][/tex]

[tex]\[ \text{moles of AgNO3} = 0.0664 \text{ mol} \][/tex]

 Now, we want to make a 0.150 M solution, so we set up the equation for molarity with the moles of AgNO3 we have and solve for the volume (V):

[tex]\[ M = \frac{\text{moles of solute}}{V} \][/tex]

[tex]\[ 0.150 \text{ M} = \frac{0.0664 \text{ mol}}{V} \][/tex]

[tex]\[ V = \frac{0.0664 \text{ mol}}{0.150 \text{ M}} \][/tex]

[tex]\[ V = 0.4427 \text{ L} \][/tex]

 However, we want the final volume to be in liters and to have a reasonable number of significant figures. Since the mass of AgNO3 is given to four decimal places, we can have four significant figures in our volume. Thus, we round the volume to 0.4427 L, which is equivalent to 442.7 mL.

 To make the solution up to 1 L, as is common practice in the lab, we would transfer the 442.7 mL of the AgNO3 solution to a 1 L volumetric flask and add distilled water to the mark on the neck of the flask, which indicates the volume is exactly 1 L. This ensures that the final concentration of the solution is 0.150 M.

 Therefore, the final volume of the solution should be 1.00 L to achieve the desired molarity of 0.150 M.

In which of the following pure substances would hydrogen bonding be expected?

a. cyclobutane
b. propanoic acid
c. acetone
d. All of the Above

Answers

Final answer:

Hydrogen bonding typically involves a hydrogen atom attached to a highly electronegative atom. In the given choices, only b- propanoic acid, which contains a hydrogen bound to an oxygen atom in a carboxylic acid group, meets this criterion.

Explanation:

In considering which of the following pure substances would hydrogen bonding be expected, you need to examine the molecular structure. Hydrogen bonding typically occurs when a hydrogen atom attached to a highly electronegative atom like nitrogen, oxygen or fluorine is in the vicinity of another electronegative atom.

cyclobutane does not have any such atoms, so it would not be expected to exhibit hydrogen bonding. Propanoic acid, on the other hand, contains a carboxylic acid group (COOH) which consists of a hydrogen atom bound to an oxygen atom, so it should display hydrogen bonding. Acetone, however, while it does contain oxygen, doesn't have hydrogen directly bonded to the oxygen, reducing its ability to form hydrogen bonds.

Therefore, out of cyclobutane, propanoic acid, and acetone, only propanoic acid would be expected to exhibit hydrogen bonding.

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The compound chromium(II) nitrate is a strong electrolyte. Write the reaction when solid chromium(II) nitrate is put into water:

Answers

Final answer:

Solid chromium(II) nitrate dissolves in water and dissociates into chromium ions and nitrate ions, indicating its strong electrolyte nature.

Explanation:

The question pertains to the dissolution of chromium(II) nitrate in water and its behavior as a strong electrolyte. When solid chromium(II) nitrate is placed in water, it will undergo the process of dissolution and dissociation since it is a strong electrolyte. This can be represented by the following chemical reaction:

Cr(NO3)2(s) → Cr2+(aq) + 2NO3−(aq)

Here, solid chromium(II) nitrate dissolves in water, producing chromium ions and nitrate ions, which are uniformly dispersed throughout the aqueous solution. The reaction showcases the strong electrolytic nature of chromium(II) nitrate, which allows it to completely dissociate in solution and conduct electricity.

The reaction is- [tex]\[ \text{Cr(NO}_3\text{)}_2(s) \rightarrow \text{Cr}^{2+}(aq) + 2\text{NO}_3^-(aq) \][/tex]

The reaction when solid chromium(II) nitrate [tex](Cr(NO\(_3\))\(_2\))[/tex] is dissolved in water can be represented by the following equation:

[tex]\[ \text{Cr(NO}_3\text{)}_2(s) \rightarrow \text{Cr}^{2+}(aq) + 2\text{NO}_3^-(aq) \][/tex]

When a strong electrolyte like chromium(II) nitrate dissolves in water, it dissociates completely into its constituent ions. Chromium(II) nitrate consists of the chromium(II) cation, [tex]Cr\(^{2+}\)[/tex], and the nitrate anion, [tex]NO\(_3\)\(^-\)[/tex]. The solid compound, represented by the (s) notation, separates into its ions in aqueous solution, as indicated by the (aq) notation.

The compound dissociates into one chromium(II) ion for every molecule of chromium(II) nitrate and two nitrate ions per molecule, as indicated by the stoichiometric coefficients in the balanced equation. The nitrate ion has a charge of -1, and since the chromium(II) ion has a charge of +2, two nitrate ions are required to balance the charge, resulting in a neutral compound. When dissolved, these ions are solvated by water molecules, but this aspect is not explicitly shown in the reaction equation.

Assuming that all the H comes from HCl, how many grams of sodium hydrogen carbonate will totally neutralize the stomach acid?

Answers

The question is incomplete, here is the complete question:

Assuming that all the [tex]H^+[/tex] comes from HCl, how many grams of sodium hydrogen carbonate will totally neutralize the stomach acid? Volume = 500 mL pH= 2

Answer: The mass of sodium hydrogen carbonate needed to completely neutralize stomach acid is 0.42 grams

Explanation:

To calculate the hydrogen ion concentration of the solution, we use the equation:

[tex]pH=-\log[H^+][/tex]

We are given:

pH = 2

Putting values in above equation, we get:

[tex]2=-\log[H^+][/tex]

[tex][H^+]=10^{-2}M[/tex]

To calculate the number of moles for given molarity of solution, we use the equation:

[tex]\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}[/tex]

Molarity of hydrogen ions = 0.01 M

Volume of solution = 500 mL = 0.5 L   (Conversion factor:  1 L = 1000 mL)

Putting values in above equation, we get:

[tex]0.01M=\frac{\text{Moles of hydrogen ions}}{0.5L}\\\\\text{Moles of hydrogen ions}=(0.01mol/L\times 0.5L)=0.005mol[/tex]

The chemical equation for the reaction of HCl and sodium hydrogen carbonate follows:

[tex]HCl+NaHCO_3\rightarrow NaCl+H_2CO_3[/tex]

By Stoichiometry of the reaction:

1 mole of HCl reacts with 1 mole of sodium hydrogen carbonate

So, 0.005 moles of HCl will react with = [tex]\frac{1}{1}\times 0.005=0.005mol[/tex] of sodium hydrogen carbonate

To calculate the number of moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]

Moles of sodium hydrogen carbonate = 0.005 moles

Molar mass of sodium hydrogen carbonate = 84 g/mol

Putting values in above equation, we get:

[tex]0.005mol=\frac{\text{Mass of sodium hydrogen carbonate}}{84g/mol}\\\\\text{Mass of sodium hydrogen carbonate}=(0.005mol\times 84g/mol)=0.42g[/tex]

Hence, the mass of sodium hydrogen carbonate needed to completely neutralize stomach acid is 0.42 grams

Final answer:

To determine the grams of sodium hydrogen carbonate needed to neutralize the stomach acid, we need to use the concept of stoichiometry.

Explanation:

To determine the grams of sodium hydrogen carbonate needed to neutralize the stomach acid, we need to use the concept of stoichiometry. The balanced equation for the neutralization reaction is:

2HCl(aq) + NaHCO3(s) → NaCl(aq) + H2CO3(aq)

From the equation, we can see that 2 moles of HCl react with 1 mole of NaHCO3. Therefore, the number of moles of HCl can be calculated using the given volume and concentration, and then converted to moles of NaHCO3. Finally, the moles of NaHCO3 can be converted to grams using its molar mass.

Consider the Williamson ether synthesis between 2-naphthol and 1-bromobutane in strong base. A reaction was performed in which 0.51 g of 2-naphthol was reacted with a slight excess of 1-bromobutane to make 0.29 g of 2-butoxynaphthalene. Calculate the theoretical yield and percent yield for this reaction.Figure:Chemical bonds

Answers

Answer:

0.70 g

41 %

Explanation:

We can write the Williamson ether synthesis in a general form as:

R-OH + R´-Br ⇒  R-O-R´

where R-OH is an alcohol and R´-Br is an alkyl bromide.

We then see that the reaction occurs in a 1:1 mole ratio to produce 1 mol product.

Therefore what we need to calculate the theoretical yield and percent yield is to compute the theoretical number of moles of   2-butoxynaphthalene produced from 0.51 g 2-naphthol, and from there we can calculate the percent yield.

molar mass  2-naphthol = 144.17 g/mol

moles 2-naphthol  = 0.51 g / 144.17 g/mol = 0.0035 mol 2-naphthol

The number of moles of  produced:

= 0.0035 mol 2-naphthol  x ( 1 mol 2-butoxynaphthalene /mol 2-naphthol )

= 0.0035 mol  2-butoxynaphthalene

The theoretical yield will be

= 0.0035 mol 2-butoxynaphthalene  x  molar mass 2-butoxynaphthalene

= 0.0035 mol x  200.28 g/ mol = 0.70 g

percent yield=  ( 0.29 g / 0.70 ) g  x 100 = 41 %

Final answer:

The theoretical yield of 2-butoxynaphthalene in the reaction between 2-naphthol and 1-bromobutane can be calculated by comparing the number of moles of the limiting reagent to the number of moles of the product. The percent yield of the reaction can be determined by dividing the actual yield by the theoretical yield and multiplying by 100.

Explanation:

In the Williamson ether synthesis reaction between 2-naphthol and 1-bromobutane in a strong base, 0.51 g of 2-naphthol reacted with a slight excess of 1-bromobutane to produce 0.29 g of 2-butoxynaphthalene. To calculate the theoretical yield, we need to compare the number of moles of the limiting reagent, which is 2-naphthol, to the number of moles of the product. The molar masses of 2-naphthol and 2-butoxynaphthalene are calculated and the theoretical yield is determined to be 0.348 g.

The percent yield of the reaction can be calculated by dividing the actual yield (0.29 g) by the theoretical yield (0.348 g) and multiplying by 100. The percent yield for this reaction is approximately 83.3%.

"Synthesis gas" is a mixture of carbon monoxide and water vapor. At high temperature synthesis gas will form carbon dioxide and hydrogen, and in fact this reaction is one of the ways hydrogen is made industrially.

A chemical engineer studying this reaction fills a 200.mL flask at 12.°C with 1.3atm of carbon monoxide gas and 3.6atm of water vapor. He then raises the temperature considerably, and when the mixture has come to equilibrium determines that it contains 0.82atm of carbon monoxide gas, 3.12atm of water vapor and 0.48atm of carbon dioxide.

The engineer then adds another 0.43atm of carbon monoxide, and allows the mixture to come to equilibrium again. Calculate the pressure of hydrogen after equilibrium is reached the second time. Round your answer to 2 significant digits.

Answers

Answer:

0.56 atm

Explanation:

The equilibrium occurs when, in a reversible reaction, the velocity of the formation of the products is equal to the velocity of the formation of the reactants. In this scenario, the partial pressures and the concentration of the components remains constant.

The equilibrium can be characterized by the equilibrium constant, which can be calculated by the concentration (Kc), or by the partial pressure (Kp). In the expression of Kc, solids and pure liquids are not put, and in the expression of Kp, only gases are considered.

The constant is calculated by the product of the concentration, or pressure, of the products, elevated by their coefficients, divided by the product of the concentration, or pressure, of the reactants, elevated by their coefficients. Its value only changes with the temperature.

So, for the reaction given:

CO(g) + H₂O(g) ⇄ CO₂(g) + H₂(g)

1.3 atm 3.6 atm 0 0 Initial

-x -x +x +x Reacts (stoichiometry is 1:1:1:1)

1.3-x 3.6-x x x Equilibrium

At equilibrium:

pCO = 1.3 - x = 0.82

x = 1.3 - 0.82 = 0.48 atm

pH₂O = 3.12 atm

pCO₂ = 0.48 atm

pH₂ = 0.48 atm

Thus,

Kp = pCO₂*pH₂/(pCO*pH₂O)

Kp = 0.48*0.48/(0.82*3.12)

Kp = 0.090

When more carbon monoxide (CO) is added, the equilibrium will shift to the right, and more products will be formed, is order to reestablish the equilibrium (Le Chatelier's pricniple), so:

CO(g) + H₂O(g) ⇄ CO₂(g) + H₂(g)

0.82 atm 3.12 atm 0.48 atm 0.48 atm 1st equilibrium

1.25 3.12 0.48 0.48 After the CO addition

-x -x +x +x Reacts

1.25-x 3.12-x 0.48 +x 0.48+x New equilibrium

Because the temperature is the same, Kp = 0.090

0.090 = (0.48+x)*(0.48+x)/[(1.25-x)*(3.12-x)]

0.090 = (0.2304 + 0.96x + x²)/(3.9 - 4.37x + x²)

0.2304 + 0.96x + x² = 0.351 - 0.3933x + 0.09x²

0.91x² + 1.3533x - 0.1206 = 0

Solving this 2nd grade equation at a graphic calculator, for x > 0 and x < 1.25

x = 0.084 atm

pH₂ = 0.48 + 0.084

pH₂ = 0.56 atm

For the reaction below, calculate the number of moles of NH3 that would be formed when 5.5 moles of N2H4 reacts completely:3N2H4 --> 4NH3 + N2

Answers

Answer:

7.33 moles of NH₃ are produced in the reaction.

Explanation:

The reaction is this:

3 N₂H₄  →  4NH₃ +  N₂

Ratio is 3:4

So 3 moles of N₂H₄ were needed to produce 4 moles of ammonia

5.5 moles of N₂H₄ would produce (5.5  . 4 ) / 3 = 7.33 moles of NH₃

This alkene can be prepared via Wittig reaction. Draw structural formulas for the aldehyde and the Wittig reagent.

Answers

Final answer:

In a Wittig reaction, the structure of the desired alkene determines the structure of your starting aldehyde and Wittig reagent. The one (aldehyde or ketone) contains the carbonyl group that will form one half of the carbon-carbon double bond in the alkene, and the other (Wittig reagent) provides the rest of the alkene structure.

Explanation:

The

Wittig reaction

is a method used in organic chemistry to create carbon-carbon double bonds (alkenes) from carbonyl compounds (such as aldehydes or ketones) and phosphonium ylides (a compound of a phosphorus cation and an organometallic compound). So, if you have a desired alkene you want to produce, you can actually reverse engineer what ingredients you need for this reaction. The carbon skeleton of the aldehyde and the Wittig reagent are directly related to the resulting alkene. The aldehyde or ketone compound will contain the carbonyl group (C=O) which will form one side of the carbon-carbon double bond in the alkene. The remainder of the alkene structure will be derived from the phosphonium ylide, the Wittig reagent. As an example, if you wanted to prepare 1-hexene, you would use hexanal as your aldehyde and methylenetriphenylphosphorane as your Wittig reagent.

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Final answer:

The Wittig Reaction is used to synthesize alkenes from aldehydes using a reagent known as a Wittig reagent. The Wittig reagent reacts with the aldehyde to create an intermediate molecule that eventually forms the alkene after the expulsion of a leaving group.

Explanation:

The Wittig reaction is a chemical reaction used to synthesize alkenes from aldehydes or ketones using a triphenyl phosphonium ylide, commonly known as a Wittig reagent.

In the most basic form of this reaction, an aldehyde is converted into an alkene through a series of steps. First, the Wittig reagent is prepared from a phosphonium salt, which when deprotonated by a base, forms a ylide or Wittig reagent. This reagent then reacts with the aldehyde in what's known as a [2+2] cycloaddition to form an oxaphosphetane intermediate, which then undergoes a reaction known as a retro-[2+2] cycloaddition to expel triphenylphosphine oxide, resulting in the formation of the alkene.

Without the exact structure of the desired alkene, it is impossible to provide the exact structures for the aldehyde and Wittig reagent, but hopefully, this general explanation of the reaction can assist you in figuring it out for your specific case.

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Calculate the volume in liters of a 0.360 mol/l barium acetate solution that contains 100.g of barium acetate (Ba(C2H3O2)2) . Round your answer to 3 significant digits.

Answers

Answer:

1.08 liters is the volume of 100 g of Ba(CH₃COO)₂

Explanation:

This data is a sort of concentration (Molarity) → 0.360 M [Ba(CH₃COO)₂]

It means that 0.36 moles of solute are contained in 1L of solution.

We should determine the moles of salt, that corresponds to 100 g of solute.

Mass / Molar mass

Ba(CH₃COO)₂ molar mass = 255.3 g/m

100 g / 255.3 g/m = 0.391 moles

So, we can apply a rule of three to calculate the volume of salt.

0.360 moles of solute are contained in 1L of solution

0.391 would be contained in (0.391 .1) / 0.360 = 1.08 liters

If 0.060 faraday is passed through an electrolytic cell containing a solution of In3+ ions, the maximum number of moles of In that could be deposited at the cathode isA) 0.010 mole
B) 0.020 mole
C) 0.030 mole
D) 0.060 mole
E) 0.18 mole

Answers

Answer: option B. 0.020 mole

Explanation:Please see attachment for explanation

The maximum number of moles of In that could be deposited at the cathode is 0.02 mole.

The given parameters;

number of ions, n = +3 ionscharge passed through the electrolytes, Q = 0.06 F

The maximum number of moles of In that could be deposited at the cathode is calculated as follows;

3 ions = 3 F

3 F  ----------------------- 1 mole of the ion

0.06 F ---------------------- ? mole of the ion

[tex]= \frac{0.06\ F \times 1}{3 \ F } \\\\= 0.02 \ mole[/tex]

Thus, the maximum number of moles of In that could be deposited at the cathode is 0.02 mole.

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Draw the Lewis structure for the disulfur monoxide molecule. Be sure to include all resonance structures that satisfy the octet rule.

Answers

Final answer:

The Lewis structure for disulfur monoxide, S2O, involves establishing eighteen valence electrons from the two sulfur atoms and the oxygen atom. The resulting structure shows each sulfur atom bonded to the central oxygen atom in a resonance structure, with each atom satisfying the octet rule.

Explanation:

To draw the Lewis structure for disulfur monoxide (S2O), we begin by determining the total number of valence electrons. Sulfur has six, and with two sulfur atoms, that gives us twelve. Oxygen also has six valence electrons. So, the total is eighteen.

Next, we arrange the atoms to show the skeletal structure. For S2O, both sulfur atoms are bonded to the oxygen atom in the center. This behaves as a resonance structure. We then distribute the remaining electrons so each sulfur has eight: S-S=O

Note that each sulfur atom ends up with eight electrons (an octet), and the oxygen atom also has eight electrons.

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Final answer:

The Lewis structure of disulfur monoxide (S2O) has two sulfur atoms at the center, each connected by a single bond and an oxygen atom connected to a sulfur atom by a single bond. All elements fulfill the octet rule with the current structure and thus no resonance structure is required.

Explanation:

The question is asking about the Lewis structure for the molecule disulfur monoxide (S2O). To create the Lewis structure, first count the number of valence electrons. Sulfur has 6 and oxygen has 6, so there is a total of 18 valence electrons in the molecule. We place sulfur atoms as the central atoms connected by a single bond and then place the oxygen atom adjacent to one of the sulfur atoms, also connected by a single bond.

Then, let's distribute remaining electrons to each atom to satisfy the octet rule. If there are too many electrons in the structure, make multiple bonds between S and O. However, in this case, S2O molecule can fully satisfy the octet rule with just single bonds. Double bonds are not needed. Similarly, there are no resonance structures for S2O according to the octet rule, as all the atoms achieve their necessary eight electrons with the initial structure.

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An air stream enters a variable area channel at a velocity of 30 m/s with a pressure of 120 kPa and a temperature of 10°C. At a certain point in the channel, the velocity is found to be 250 m/s. Using Bernoulli’s equation (i.e., p + rhoV2 /2 = constant), which assumes incompressible flow, find the pressure at this point. In this calculation, use the density evaluated at the inlet conditions. If the temperature of the air is assumed to remain constant, evaluate the air density at the point in the flow where the velocity is 250 m/s. Compare this density with the density at the inlet to the channel. Based on this comparison, do you think that the use of Bernoulli’s equation is justified

Answers

Answer:

P₂= 74 kPa under constant density and ρ₂ = 1.06 kg/m³ (-38.6% of error compared with incompresible assumption) . Thus Bernoulli’s equation should not be applied

Explanation:

Assuming ideal gas behaviour of air , then

P*V= n*R*T = m / M * R *T

since

ρ= m/V = P*M /( R *T)

where

n= moles , V= volume , m= mass

ρ= density

P= pressure = 120 kPa= 120000 Pa

M= molecular weight of air = 0.21*32+0.79*28= 28.24 gr/mol = 0.02824 kg/mol

T= absolute temperature = 10°C + 273 = 283 K

R= ideal gas constant = 8.314 J/mol K

solving for ρ

ρ=  P*M /( R *T) = 120000 Pa*0.02824 kg/mol/(8.314 J/mol K*283 K) = 1.47 kg/m³

then from Bernoulli's equation

P₁ + ρ*v₁²/2 = P₂ + ρ*v₂²/2

where 1 denotes inlet and 2 denotes other point , p = pressure and v= velocity . Then solving for p₂

P₁ + ρ*v₁²/2 = P₂ +ρ*P₂²/2

P₂=  P₁ +ρ*v₁²/2 - ρ*v₂²/2  = P₁ +ρ/2*(v₁² - v₂²)

replacing values

P₂= P₁ +ρ/2*(v₁² - v₂²) = 120000 Pa + 1.47 kg/m³/2*[(30 m/s)²-(250 m/s)²] = 74724 Pa = 74 kPa

P₂= 74 kPa

then if the temperature remains constant

ρ₁= P₁*M /( R *T) and ρ₂= P₂*M /( R *T)

dividing both equations

ρ₂/ρ₁ = P₂/ P₁

ρ₂ = (P₂/ P₁)*ρ₁

then from Bernoulli's equation

P₁ + ρ₁*v₁²/2 = P₂ + ρ₂*v₂²/2

P₂ = P₁ + ρ₁*v₁²/2 - ρ₂*v₂²/2

therefore

ρ₂ = (P₂/ P₁)*ρ₁ = (P₁ + ρ₁*v₁²/2 - ρ₂*v₂²/2 ) /P₁ *ρ₁

P₁ * ρ₂  = P₁ *ρ₁  + ρ₁²*v₁²/2 - ρ₂*ρ₁ * v₂²/2

P₁ * ρ₂ + ρ₂*ρ₁ * v₂²/2  = P₁ *ρ₁  + ρ₁²*v₁²/2

ρ₂* (P₁ + ρ₁ * v₂²/2) = P₁ *ρ₁  + ρ₁²*v₁²/2

ρ₂ = (P₁ *ρ₁  + ρ₁²*v₁²/2)/(P₁ + ρ₁ * v₂²/2) =  (P₁ + ρ₁*v₁²/2)/(P₁/ρ₁ + v₂²/2)

replacing values

ρ₂ = ( 120000 Pa + 1.47 kg/m³/2*(30 m/s)²)/(120000 Pa/1.47 kg/m³+1/2*(250 m/s)²)

ρ₂ = 1.06 kg/m³

the error of assuming constant ρ would be

e = (ρ₂ - ρ)/ρ₂=  1- ρ/ρ₂= 1- 1.47 kg/m³/1.06 kg/m³ = -0.386 (-38.6%)

thus Bernoulli’s equation should not be applied

Which of the following pieces of glassware would be best to choose for the following tasks?

For each task, select either the volumetric flask, Erlenmeyer flask, beaker, volumetric pipet, or graduate cylinder and explain why it would be the best choice.

a. Accurately deliver 15.00 mL of solution

b. Heat a reaction mixture on a hot plate

c. Accurately make a diluted solution to four significant figures

d. Approximately deliver 15 mL of solution

Answers

a) For accurately deliver 15.00 mL of solution- volumetric flask should be used.

b)For heating a reaction mixture on a hot plate- beaker should be used.

c)For accurately make a diluted solution to four significant figures- volumetric pipet should be used.

d) For approximately deliver 15 mL of solution- graduate cylinder should be used.

A graduated cylinder is a common piece of laboratory equipment used to measure the volume of a liquid.A volumetric flask is a type of laboratory flask, calibrated to contain a precise volume at a certain temperature.A beaker is generally a cylindrical container with a flat bottom.A volumetric pipette allows extremely accurate measurement (to four significant figures) of the volume of a solution

Learn more:

brainly.com/question/10826387

Final answer:

For accurately delivering 15.00 mL, use a volumetric pipet; for heating, an Erlenmeyer flask; for making a precise diluted solution, a volumetric flask; and for approximate delivery of 15 mL, a graduated cylinder.

Explanation:

To choose the appropriate piece of glassware for each task, we must consider the accuracy and precision required, as well as the suitable functionality of each option.

d. Approximately deliver 15 mL of solution: A graduated cylinder can be used for this purpose as it is designed to deliver variable volumes of liquid with reasonable accuracy but does not require the high precision of a volumetric pipet or flask.

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