Physical properties such as melting point, boiling point, and solubility are all dependent on the type of interparticle forces a substance experiences. Identify the type of interparticle force that has the greatest influence on the physical properties for each substance. Cl2, NH2OH, PCl3, CH4, CaCl2, KI

Two of the substances in Part 1 are ionic. Which factors will result in a stronger ionic bond overall?

1. larger ions2. greater absolute charges3. similarity of ionic sizes4. smaller ions

Answers

Answer 1
Final answer:

The type of interparticle force that has the greatest influence on the physical properties of each substance are identified. Factors that result in a stronger ionic bond overall are listed.

Explanation:

The type of interparticle force that has the greatest influence on the physical properties of each substance are as follows:

Cl2: van der Waals forcesNH2OH: hydrogen bondingPCl3: dipole-dipole forcesCH4: van der Waals forcesCaCl2: ionic forcesKI: ionic forces

The factors that result in a stronger ionic bond overall are:

larger absolute chargesgreater absolute chargessmaller ions

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Answer 2
Final answer:

Cl2 and CH4 experience London dispersion forces, NH2OH has hydrogen bonding, PCl3 has dipole-dipole interactions, and CaCl2 and KI demonstrate ionic bonding. Greater absolute charges and smaller ion sizes boost the strength of ionic bonds.

Explanation:

The substances listed – Cl2, NH2OH, PCl3, CH4, CaCl2, and KI – have different types of interparticle forces that affect their physical properties. Cl2 and CH4 are nonpolar with London dispersion forces; NH2OH has hydrogen bonding; PCl3 has dipole-dipole interactions. CaCl2 and KI are ionic compounds, where the primary interparticle force is ionic bonding.

The factors that enhance the strength of ionic bonds are usually the greater absolute charges on the ions and the smaller size of the ions. Larger charges mean that the electrostatic attraction between the ions is stronger, leading to a stronger ionic bond. Smaller ions, on the other hand, can get closer together, which also intensifies the electrostatic attraction and hence increases the strength of the ionic bond.

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Related Questions

A solution is prepared by mixing 93.0 mL of 5.00 M HCl and 37.0 mL of 8.00 M HNO3. Water is then added until the final volume is 1.00 L. Calculate [H ], [OH -], and the pH for this solution.

Answers

Answer:

[tex][H^{+}] = 0.761 \frac{mol}{L}[/tex]

[tex][OH^{-}]=1.33X10^{-14}\frac{mol}{L}[/tex]

[tex]pH = 0.119[/tex]

Explanation:

HCl and HNO₃ both dissociate completely in water. A simple method is to determine the number of moles of proton from both these acids and dividing it by the total volume of solution.

[tex]n_{H^{+} } from HCl = [HCl](\frac{mol}{L}). V_{HCl}(L) \\ n_{H^{+} } from HNO_{3} = [HNO_{3}](\frac{mol}{L}). V_{HNO_{3}}(L)[/tex]

Here, n is the number of moles and V is the volume. From the given data moles can be calculated as follows

[tex]n_{H^{+} } from HCl = (5.00)(0.093)[/tex]

[tex]n_{H^{+} } from HCl = 0.465 mol[/tex]

[tex]n_{H^{+} } from HNO_{3} = (8.00)(0.037)[/tex]

[tex]n_{H^{+} } from HNO_{3} = 0.296 mol[/tex]

[tex]n_{H^{+}(total) } = 0.296 + 0.465[/tex]

[tex]n_{H^{+}(total) } = 0.761 mol[/tex]

For molar concentration of hydrogen ions:

[tex][H^{+}] = \frac{n_{H^{+}}(mol)}{V(L)}[/tex]

[tex][H^{+}] = \frac{0.761}{1.00}[/tex]

[tex][H^{+}] = 0.761 \frac{mol}{L}[/tex]

From dissociation of water (Kw = 1.01 X 10⁻¹⁴ at 25°C) [OH⁻] can be determined as follows

[tex]K_{w} = [H^{+} ][OH^{-} ][/tex]

[tex][OH^{-}]=\frac{Kw}{[H^{+}] }[/tex]

[tex][OH^{-}]=\frac{1.01X10-^{-14}}{0.761 }[/tex]

[tex][OH^{-}]=1.33X10^{-14}\frac{mol}{L}[/tex]

The pH of the solution can be measured by the following formula:

[tex]pH = -log[H^{+} ][/tex]

[tex]pH = -log(0.761)[/tex]

[tex]pH = 0.119[/tex]

When two moles of ethane react completely with oxygen, how many moles of carbon dioxide will be produced?A. 2.B. 4.C. 8.D. Unknown number.

Answers

Answer:

Option B.

Explanation:

As any reaction of combustion, the O₂ is a reactant and the products are CO₂ and H₂O. Combustion reaction for ethane is:

2C₂H₆  +  7O₂   →   4CO₂  +  6H₂O

So 2 moles of ethane react with 7 moles of oxygen to make 4 moles of dioxide and 6 moles of water.

Then 2 moles of ethane will produce 4 moles of CO₂

Ammonia (NH3) can be synthesized from nitrogen gas (N2) and hydrogen gas (H2) by the following reaction.
N2(g) + 3 H2(g) → 2 NH3(g)
If the theoretical yield of ammonia is 383 g and the actual yield is 253 g, calculate the percent yield of ammonia.

Answers

Answer:

                      %age Yield  =  66.05 %

Explanation:

                     In order to check the efficiency of a reaction the %age is calculated so that it can be concluded that either the conditions provided for certain reactions are favourable or not because at large scales reactions with greater %age yields are favoured as it results in high product quantity and hence, greater economical advantages.

                   The percent yield is given as;

                  %age Yield  =  Actual Yield / Theoretical Yield × 100

Putting values,

                   %age Yield  =  253 g / 383 g × 100

                   %age Yield  =  66.05 %

Hence, for the given reaction the success of the reaction is only 65% hence, steps can be made to improve this yield by modifying the reaction conditions.

spontaneously form membranes when mixed in water and most likely were one of the first organic compounds formed on Earth?

Answers

Answer:

phospholipids

Explanation:

As regards the lipid membrane of the first protocells, it is most likely that it initially consisted of simpler fatty acids than the phospholipids that make up the current membranes (see appendix). If the modern membranes are bilayers of glycerol phospholipids, the primitive membranes would probably be made up of simpler, single-chain molecules, also amphiphilic in nature (with a soluble part and another insoluble in water), such as monocarboxylic acids or alcohols. The origin of these compounds could be multiple. On the one hand, it has been seen that they are very abundant in meteorites of the type of carbonaceous chondrites, so they could have arrived on Earth already formed from outer space. But it is also possible that they were formed abioticly on the primitive Earth by the reaction of CO and hydrogen to give rise to various hydrocarbons, a reaction that would be viable at high temperatures in the presence of ferric catalysts, on the surface of montmorillonite clays and also in hydrothermal conditions. Regardless of the origin, the result would be the presence of fatty acids initially very diluted in an aqueous solution, but which would be concentrated by successive evaporation cycles, or by the formation of small aerosolized drops that would also transfer those vesicles to points distant from the place where The first organic membrane compounds that formed on Earth were formed and would be.

Suppose we want to charge a flask with 1.9 g of sugar. We put the empty flask on a balance and it is determined to weigh 450 g. Enter the weight we would expect to see on the balance when we're done adding the sugar.

Answers

Answer: 451.9g

Explanation:

Weight of empty flask= 450g

Weight of sugar= 1.9g

Weight of sugar+flask=450+1.9=451.9g

The sum of the massed of both the sugar and the flask is the mass the balance will read after the addition of the sugar.

You wish to prepare 0.13 M HNO3 from a stock solution of nitric acid that is 16.6 M. How many milliliters of the stock solution do you require to make up 1.00 L of 0.13 M HNO3?

Answers

Answer:

0.0078 L of the stock solution is required to make up 1.00 L of 0.13 M [tex]HNO_{3}[/tex]

Explanation:

According to laws of equivalence, [tex]C_{1}V_{1}=C_{2}V_{2}[/tex]

where, [tex]C_{1}[/tex] and [tex]C_{2}[/tex] are initial and final concentration respectively. [tex]V_{1}[/tex] and [tex]V_{2}[/tex] are initial and final volume respectively.

Here, [tex]C_{1}=16.6M[/tex], [tex]C_{2}=0.13M[/tex] and [tex]V_{2}=1.00L[/tex]

So, [tex]V_{1}=\frac{C_{2}V_{2}}{C_{1}}[/tex]

or, [tex]V_{1}=\frac{(0.13M)\times (1.00L)}{(16.6M)}[/tex]

or, [tex]V_{1}=0.0078L[/tex]

Hence 0.0078 L of the stock solution is required to make up 1.00 L of 0.13 M [tex]HNO_{3}[/tex]

The production capacity for acrylonitrile (C3H3N) in the United States exceeds 2 million pounds per year. Acrylonitrile, the building block for polyacrylonitrile fibers and a variety of plastics, is produced from gaseous propylene, ammonia, and oxygen. 2 C3H6(g) + 2 NH3(g) + 3 O2(g) â 2 C3H3N(g) + 6 H2O(g)
(a) What mass of acrylonitrile can be produced from a mixture of 1.16 kg of propylene (C3H6), 1.65 kg of ammonia, and 1.78 kg of oxygen, assuming 100% yield?
(b) What mass of water is produced?
(c) What mass of oxygen is left in excess?

Answers

Answer:

Explanation:

This question we will solve by calculations based on the stoichiometry of the balanced chemical equation which gives us all the information required to know the quantities produced and reacted based on their molar ratios.

First we will need the molecular weights of the reactants to calculate the number of moles of each reactant and determine if there is a limiting reagent, and from there we can learn about the moles and masses of the products.

2 C3H6(g) + 2 NH3(g) + 3 O2(g) ⇒ 2 C3H3N(g) + 6 H2O(g)

MW C3H6 : 42.08 g/mo                    MW C3H3N : 53.06 g/mol

MW  NH3 : 17.03 g/mol                      MW  H2O : 18.02 g/mol

MW  O2: 32 g/mol

Moles of reactants:

Convert the masses given to grams since we have the molar masses in grams. The number of moles, n, is calculated by dividing the mass into the molecular weight.

n C3H6 = ( 1.16 Kg x 1000 g/ Kg ) / 42.08 g/mol = 27.56 mol

n NH3 = ( 1.65 kg x 1000 g/ /Kg ) / 17.03 g/mol   = 96.89 mol

n O2 =  ( 1.78 Kg x 1000 g/ Kg ) /  32 g/mol = 55.63 mol

from the stoichiometry of the reaction we know propylene and ammonia react  2: 2  so  propylene is the limiting reagent:

( 2 mol NH3 / 2 mol C3H6 )x  27.56 mol C3H6 = 27.56 mol NH3 (required to react with the 27.56 mol C3H6 and we have plenty ( 96.98 mol )

The stoichiometry of the reaction also confirms that O2 is in excess:

(  3 mol O2 / 2 mol C3H6 ) x 27.56 mol C3H6 = 41.34 mol O2  (required to react completely with 27.56 mol C3H6 ).

(a) Again from the balanced chemical reaction we know the mol proportions reactants to product, thus mol C3H3N ( 1: 1 ) produced:

( 2 mol C3H3N / 2 mol C3H6 ) x 27.56 mol C3H6 = 27.56 mol C3H3N

The mass of acrylonitrile will be given by multiplying the molecular weight of the mol produced assuming a 100 % yield:

55.12 g/mol x  27.56 mol  = 1,519 g = 1.51  Kg

(b) The calculation to obtain the mass of water will be performed in a similar manner:

( 6 mol H2O / 2 mol C3H6 ) x 27.56 mol C3H6 = 82.68 mol H2O produced

82.68 mol x 18 g/mol = 1,488 grams = 1.49 Kg

(c) The mass of O2 left will be obtained from the number of moles in excess:

mol O2 originally present = 1.78 x 1000 g/Kg / 32 g/mol = 55.62 mol

mol O2 in excess = mol O2 initially - mol reacted

from above we know 41.34 mol are required to react with our limiting reagent, C3H6 :

mol O2 in excess = 55.62 mol - 41.34 mol = 14.29 mol

mass oxygen in excess = 32 g/mol x 14.29 mol = 457.12 g = 0.457 Kg

Convert grams of FeCl2 to moles. Then rearrange M = n/V to solve for V: V = n/M (in Liters) What volume of a 0.01 M solution can be made using 120 grams of FeCl2?

Answers

Answer:

The answer to your question is Volume = 214.3 ml

Explanation:

Data

mass = 120 g of FeCl₂

concentration = 0.01 M

volume = ?

Formula

Molarity = [tex]\frac{number of moles}{volume}[/tex]

Solve for volume

Volume = [tex]\frac{number of moles}{molarity}[/tex]

Process

1.- Convert grams to moles

Atomic weight = 56 g

                            56 g of Fe --------------- 1 mol

                         120 g of Fe  ----------------  x

                               x = (120 x 1) / 56

                               x = 2.14 moles

2.- Calculate the volume

Volume = [tex]\frac{2.14}{0.01}[/tex]

Volume = 214.3 ml

Answer:

We need 94.67 liters if a 0.01 M solution

Explanation:

Step 1: Data given

Molarity of the solution = 0.01 M

Mass of FeCl2 = 120.0 grams

Molar mass FeCl2 = 126.75 g/mol

Step 2: Calculate moles of FeCl2

moles FeCl2 = massFeCl2 / molar mass FeCl2

Moles FeCl2 = 120.0 grams / 126.75 g/mol

Moles FeCl2 = 0.9467 moles

Step 3: Calculate  volumes FeCl2

Molarity = moles / volume

Volume = moles / molarity

Volume = 0.9467 moles /0.01 M

Volume = 94.67 L

We need 94.67 liters if a 0.01 M solution

A student conducted an experiment to determine DHrxn for the reaction between HCl(aq) and NaOH(aq). The student ran two trials using the volumes of HCl(aq) and NaOH(aq) indicated in the table above, and determined the amount of heat released. Which of the following best explains the relationship between X and Y?

Answers

Answer:

Y=X

Explanation:

The number of moles of acid and base reacting with each other is the same in both trials.

Final answer:

In the neutralization reaction between HCl and NaOH, a one-to-one mole ratio leads to a predictable enthalpy change (ΔHrxn). The temperature increase signifies an exothermic reaction, and ΔHrxn can be calculated using the formula q=mcΔT, considering the reaction's exothermic nature.

Explanation:

The relationship between X and Y refers to the amount of heat (ΔH) released during the neutralization reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH). In this reaction, a one-to-one mole ratio is observed, meaning 1 mole of HCl reacts with 1 mole of NaOH to produce 1 mole of sodium chloride (NaCl) and water (H₂O)

When calculating the enthalpy change, the student must use the temperature change, the mass of the solution, and the specific heat capacity (which is assumed to be the same as water's for this type of experiment). The amount of heat produced (ΔHrxn) can be calculated using the formula q = mcΔT, where 'm' is the mass of the solution, 'c' is the specific heat capacity, and 'ΔT' is the change in temperature.

In a typical calorimetry experiment, the student would need to carefully measure the temperature changes and use stoichiometry to relate the amounts of the reactants to the heat released. If the temperature increases, as in the example provided, it indicates that the reaction is exothermic, and the value for ΔHrxn would be negative, signifying that heat is released into the surroundings.

Complete the dissociation reaction and the corresponding Ka equilibrium expression for each of the following acids in water. (Type your answer using the format [NH4]+ for NH4+ and [Ni(CN)4]2- for Ni(CN)42-. Use the lowest possible coefficients.)
(A) HC2H3O2
HC2H3O2(aq) (twosidedarrow) [ ]H+(aq) + [ ] [ ](aq)
Ka = [ ][ ] / [ ]
(B) Co(H2O)63+
Co(H2O)63+(aq) (twosidedarrow) [ ]H+(aq) +[ ][ ](aq)
Ka = [ ][ ] / [ ]
(C) CH3NH3+
CH3NH3+(aq) (twosidedarrow) [ ]H+(aq) +[ ][ ](aq)
Ka = [ ][ ] / [ ]

Answers

Final answer:

The dissociation reactions for acetic acid, hexaaquacobalt(III) ion, and methylammonium along with their Ka equilibrium expressions show how each acid disassociates into its constituent ions in water, and how the concentration of these ions at equilibrium can be represented.

Explanation:

Completing the dissociation reaction and the Ka equilibrium expression for each of the following acids in water:

(A) Acetic acid [tex]($\text{HC}_2\text{H}_3\text{O}_2$)[/tex]

[tex]\[\text{HC}_2\text{H}_3\text{O}_2(\text{aq}) \rightleftharpoons \text{H}^+(\text{aq}) + \text{C}_2\text{H}_3\text{O}_2^-(\text{aq})\\\\K_a = \frac{[\text{H}^+][\text{C}_2\text{H}_3\text{O}_2^-]}{\text{HC}_2\text{H}_3\text{O}_2}\][/tex]

(B) Hexaaquacobalt(III) ion [tex]($\text{Co(H}_2\text{O)}_6^{3+}$)[/tex]

[tex]\[\text{Co(H}_2\text{O)}_6^{3+}(\text{aq}) \rightleftharpoons \text{H}^+(\text{aq}) + \text{Co(H}_2\text{O)}_5\text{OH}_2^+(\text{aq})\\\\K_a = \frac{[\text{H}^+][\text{Co(H}_2\text{O)}_5\text{OH}_2^+]}{\text{Co(H}_2\text{O)}_6^{3+}}\][/tex]

(C) Methylammonium[tex]($\text{CH}_3\text{NH}_3^+$)[/tex]

[tex]\[\text{CH}_3\text{NH}_3^+(\text{aq}) \rightleftharpoons \text{H}^+(\text{aq}) + \text{CH}_3\text{NH}_2(\text{aq})\\\\K_a = \frac{[\text{H}^+][\text{CH}_3\text{NH}_2]}{\text{CH}_3\text{NH}_3^+}\][/tex]

Antoine Lavoisier, the French scientist credited with first stating the law of conservation of matter, heated a mixture of tin and air in a sealed flask to produce tin oxide. Did the mass of the sealed flask and contents decrease, increase, or remain the same after the heating?

Answers

Answer:

Remain the same

Explanation:

The law of mass conservation states that matter cannot be created nor destroyed but can be converted from one form to another.

Essentially, what Lavoisier was trying to proof is that by heating the mixture, after all the change the mass still remains. That was why he used a sealed flask. If the flask was not sealed, it probably would have been that some of the mass will escape as vapor to the atmosphere which might be difficult to account for

Haley's parents bought her a used bicycle for her birthday. She was thrilled until she learned that her best friend received a brand-new bicycle for her birthday. Haley's declining satisfaction illustratesA)relative deprivation.B)the adaptation-level phenomenon.C)the catharsis hypothesis.D)the behavior feedback effect.Page 7

Answers

Answer:

A) relative deprivation

Explanation:

The given example is of the relative deprivation principle of sociology.

The Theory of Relative Deprivation. Throughout sociology, the principle of relative deprivation is a concept of societal change and campaigns, whereby people act for social changes in order to gain something (for example, privileges, prestige, or wealth) that others have and that they also feel they should have the same. Here Haley is feeling deprived of brand new bicycle as has a used one.

What is the value of the rate constant for a second order reaction if the reactant conceretation drop sform 0.657 M to 0.0981 M in 17.0 s?

Answers

Answer:

The rate constant for a second order reaction is

k = 0.51 dm-3 s-1.

Explanation:

In a regular second-order reaction the rate equation is given by v = k[A][B], if the reactant B concentration is constant then v = k[A][B] = k'[A], where k' the pseudo–first-order rate constant = k[B].

Also 1/|A| = Kt + 1/|Ao|

But Ao = 0.657 M and

A = 0.0981 M also

t = 17.0 s

Therefore

1/| 0.0981 M| =K × 17.0 s + 1/| 0.657 M|

→ 10.19/M = 17K + 1.52/M

10.19/M - 1.52/M = 8.67/M = 17K

K = 8.67M/17s = 0.51 dm-3 s-1.

k = 0.51 dm-3 s-1.

HCl(aq)+NaOH(aq)→NaCl(aq)+H2O(l)ΔH°=−57.1kJ/molrxn
The chemical equation above represents the reaction between HCl(aq) and NaOH(aq). When equal volumes of 1.00MHCl(aq) and 1.00MNaOH(aq) are mixed, 57.1kJ of heat is released. If the experiment is repeated with 2.00MHCl(aq), how much heat would be released?

Answers

Answer:

57.1 kilo Joules of heat would be released.

Explanation:

[tex]HCl(aq)+NaOH(aq)\rightarrow NaCl(aq)+H_2O(l)[/tex] ΔH°=-57.1kJ/mol

Molarity of HCl = 2.00 M

Molarity of NaOH = 1.00 M

According to reaction , 1 M of HCl reacts with 1 M of NaOH. Then 2.00 M of HCl will react with:

[tex]\frac{1}{1}\times 2.00 M= 2M [/tex] of NaOH

But according to question we only have 1.00 M NaOH .So, this means that NaOH is limiting reagent and HCl is an excessive reagent.

Heat evolved will depend upon concentration of NaOH solution :

Heat evolved when 1.00 M of NaOH reacts =

[tex]1.00\times (-57.1 kJ/mol)=-57.1 kJ[/tex]

Negative sign means that heat is released during the reaction.

57.1 kilo Joules of heat would be released.

The heat released during the repeated experiment with 2 mole of HCl is 57.1 kJ.

The given reaction,

[tex]\bold {HCl(aq)+NaOH(aq)\rightarrow NaCl(aq)+H_2O(l) \ \ \ \ \ \ \ \ \ \Delta H = - 57.1\ kJ/mol}[/tex]

Concentration of HCl is 2 mole.

So, 2 mole of HCl react with 2 mole of NaOH but only mole of NaOH is available.

So, NaOH is a Limiting factor in the reaction and HCl is excessive factor.

Only, 1mole of HCl will react with available 1 mole of NaOH,

Therefore, the heat released during the repeated experiment with 2 mole of HCl is 57.1 kJ.

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For the most part, biological pH is slightly basic. However, the stomacłh is very acidic, and its contents must be swiftly neutralized by basic bicarbonate ions upon entering the small intestine, which has a basic pH. How many liters of 2 M Ba(OH)2 are needed to titrate a 4 Lsolution of 6 M H3PO4?
a) 1.33 L
b) 12L
c) 18 L
d) 56 L

Answers

Answer:

Vb = 18 L option c)

Explanation:

First, we need to write the titration reaction between the base and the acic, which is the following:

Ba(OH)₂ + H₃PO₄ <-------> Ba₃(PO₄)₂ + H₂O

However this equation is not balanced, we need to balance the equation adding some coefficients to the agents so:

3Ba(OH)₂ + 2H₃PO₄ <-------> Ba₃(PO₄)₂ + 6H₂O

Now that the equation is balanced, as we know this is an acid base titration, we need to calculate the mole ratio between the base and acid so:

moles B / moles A = 3/2

2 moles B = 3 moles A (1)

This is taken from the balanced reaction.

Now, finally we use the relation in titration which is:

moles A = moles B

or simply MaVa = MbVb

If we replace this in the ratio of this reaction we have:

2MbVb = 3MaVa (2)

And from there, we solve for Vb which is the volume of the base:

2 * 2 * Vb = 3 * 4 * 6

4Vb = 72

Vb = 72/4

Vb = 18 L

This is the volume of the base required to titrate this acid

The melting points of ionic compounds are typically high and those of molecular compounds are typically low. What would the melting point be for potassium chloride (KCl)?

Answers

Answer:

The answer to your question is  "It will be a high melting point"

Explanation:

Process

1.- Identify the kind of compounds that is Potassium chloride.

Ionic compounds are composed of a metal and a nonmetal.

Covalent compounds are composed of 2 nonmetals.

Potassium chloride is composed of a metal and a nonmetal so, it is  an ionic compound.

2.- Conclude, Potassium chloride has a high melting point because is an ionic compound".

Answer:

High melting point.

Explanation:

Potassium chloride is an ionic compound  so the melting point will be  high.

What type of base is defined as a substance that forms hydroxide ions (OH-) in water?


A. Brønsted-Lowry base

B. Arrhenius base

C. neutralization base

D. Lewis base

Answers

Answer:

A.Brønsted-Lowry base

Explanation:

Answer:

B:Arrhenius base

Explanation:

Acccording  to Svante Arrhenius a base is a substance the dissociates in water to form hydroxide ion.In other words a base is that substance which when dissolved in water,increases the concentration of hydroxide ion.The examples of Arrhenius bases are given below;

NaOH ,KOH,LiOH etc

Dissociation of NaOH in aqueous solution is given as;

NaOH=>Na+ + OH-

The standard internal energy change for a reaction can be symbolized as Δ U ∘ rxn or Δ E ∘ rxn . For each reaction equation, calculate the energy change of the reaction at 25 ∘ C and 1.00 bar . Sn ( s ) + 2 Cl 2 ( g ) ⟶ SnCl 4 ( l ) Δ H ∘ rxn = − 511.3 kJ/mol

Answers

The final answer is:

[tex]\[ \Delta S^\circ_{\text{rxn}} = 1716.72 \, \text{J/mol-K} \][/tex]

Let's calculate the energy change of the reaction using the given data:

Reaction equation:

[tex]\[ \text{Sn}(s) + 2\text{Cl}_2(g) \rightarrow \text{SnCl}_4(l) \][/tex]

Given:

[tex]\[ \Delta H^\circ_{\text{rxn}} = -511.3 \, \text{kJ/mol} \]\\Temperature (\( T \)) = \( 25^\circ \text{C} \) = \( 298.15 \, \text{K} \)\\Pressure (\( P \)) = \( 1.00 \, \text{bar} \)\\\\[/tex]

First, we convert[tex]\( \Delta H^\circ_{\text{rxn}} \)[/tex] from kJ/mol to J/mol:

[tex]\[ \Delta H^\circ_{\text{rxn}} = -511.3 \, \text{kJ/mol} \times 1000 \, \text{J/kJ} = -511300 \, \text{J/mol} \][/tex]

Next, we use the formula for Gibbs Free Energy [tex](\( \Delta G^\circ_{\text{rxn}} \)):[/tex]

[tex]\[ \Delta G^\circ_{\text{rxn}} = \Delta H^\circ_{\text{rxn}} - T \Delta S^\circ_{\text{rxn}} \][/tex]

At standard conditions [tex](\( 25^\circ \text{C} \) and \( 1.00 \, \text{bar} \)), \( \Delta G^\circ_{\text{rxn}} \)[/tex] is equal to zero:

[tex]\[ 0 = -511300 \, \text{J/mol} - (298.15 \, \text{K}) \times \Delta S^\circ_{\text{rxn}} \][/tex]

Solving for[tex]\( \Delta S^\circ_{\text{rxn}} \):[/tex]

[tex]\[ \Delta S^\circ_{\text{rxn}} = \frac{-(-511300 \, \text{J/mol})}{298.15 \, \text{K}} \]\[ \Delta S^\circ_{\text{rxn}} = 1716.72 \, \text{J/mol-K} \][/tex]

So, the final answer is:

[tex]\[ \Delta S^\circ_{\text{rxn}} = 1716.72 \, \text{J/mol-K} \][/tex]

1. Convert [tex]\( \Delta H^\circ_{\text{rxn}} \)[/tex]  from kJ/mol to J/mol.

2. Use the formula [tex]\( \Delta G^\circ_{\text{rxn}} = \Delta H^\circ_{\text{rxn}} - T \Delta S^\circ_{\text{rxn}} \) and solve for \( \Delta S^\circ_{\text{rxn}} \) at standard conditions where \( \Delta G^\circ_{\text{rxn}} = 0 \).[/tex]

Complete Question:

The standard internal energy change for a reaction can be symbolized as Δ U ∘ rxn or Δ E ∘ rxn . For each reaction equation, calculate the energy change of the reaction at 25 ∘ C and 1.00 bar . Sn ( s ) + 2 Cl 2 ( g ) ⟶ SnCl 4 ( l ) Δ H ∘ rxn = − 511.3 kJ/mol

The standard internal energy change for the reaction is approximately [tex]\( -511.3 \text{ kJ/mol} \).[/tex]

The standard internal energy change for the given reaction at 25°C and 1.00 bar can be calculated using the standard enthalpy change, H°rxn, provided that the reaction occurs at constant pressure and the only work done is pressure-volume work. Under these conditions, the change in internal energy (U°rxn) can be approximated by the change in enthalpy (Hrxn), because the difference between H°rxn and U°rxn is the product of the pressure, volume change, and the number of moles of gas, which is often small for reactions that do not involve a significant amount of gas.

 The reaction is as follows:

[tex]\[ \text{Sn (s)} + 2\text{Cl}_2 \text{(g)} \rightarrow \text{SnCl}_4 \text{(l)} \][/tex]

 Given:

[tex]\[ \Delta H^\circ_{\text{rxn}} = -511.3 \text{ kJ/mol} \][/tex]

At constant pressure (1.00 bar) and temperature (25°C), the relationship between Hrxn and U°rxn is given by:

[tex]\[ \Delta H^\circ_{\text{rxn}} = \Delta U^\circ_{\text{rxn}} + P\Delta V \][/tex]

 For reactions involving gases, the term [tex]\( P\Delta V \)[/tex] represents the work done by the system on the surroundings due to volume change against the constant external pressure \( P \). Since the number of moles of gas decreases during the reaction (2 moles of Cl2 gas are consumed to form 1 mole of SnCl4 liquid), \( \Delta V \) is negative, and thus \( P\Delta V \) is also negative.

However, for condensed phases (solids and liquids), the volume change is typically small, and the [tex]\( P\Delta V \)[/tex] term is often negligible compared to the enthalpy change. Therefore, for the reaction given, which involves a solid reactant and a liquid product, we can assume that [tex]\( \Delta H^\circ_{\text{rxn}} \approx \Delta U^\circ_{\text{rxn}} \).[/tex]

 Thus, the standard internal energy change for the reaction is approximately equal to the standard enthalpy change:

[tex]\[ \Delta U^\circ_{\text{rxn}} \approx \Delta H^\circ_{\text{rxn}} \][/tex]

[tex]\[ \Delta U^\circ_{\text{rxn}} \approx -511.3 \text{ kJ/mol} \][/tex]

 Therefore, the standard internal energy change for the reaction is approximately [tex]\( -511.3 \text{ kJ/mol} \).[/tex]

 In conclusion, the energy change of the reaction at 25°C and 1.00 bar is:

[tex]\[ \boxed{\Delta U^\circ_{\text{rxn}} \approx -511.3 \text{ kJ/mol}} \][/tex]

This value is a good approximation for the standard internal energy change of the reaction under the given conditions.

 The answer is: [tex]\Delta U^\circ_{\text{rxn}} \approx -511.3 \text{ kJ/mol}.[/tex]

ATP labeled with 32P a radioactive isotope of phosphorus at the gamma phosphate is added to a crude extract of a tissue rich in the enzymes of glycolysis along with glucose. What is the first intermediate of glycolysis that will no longer be radioactive?

Answers

Answer:

Piruvate

Explanation:

Glucose + ATP32 --------> Glucose-6-P32 ----->Fructose-6-P32

Fructose-6-P32 + ATP32 ---------> Fructose-1,6 bi-P32

Fructose-1,6 bi-P32 ----------> Glyceraldehyde-3-P32 + Dihydroxiacetone Phosphate32 (that are in equilibrium)

Glyceraldehyde-3-P32 +NADH +Pi (non radioactive) -----> Glyceraldehyde-1,3-P32 (1,3 biphosphoglycerate where only in C3, there is a P32)

After that, the phosphorus in Carbon1 is donated to ADP to for ATP (non radioactive), and we have 3-Phosphoglycerate (radioactive because its P32), then it's converted to 2-Phosphoglycerate (radioactive), then Phosphoenolpiruvate (radioactive), that donates its P32 to ADP to produce ATP, remaining Piruvate as end product at the end of glucolysis

There are three major isotopes of silicon: silicon-28, silicon-29, and silicon-30. Given the average atomic mass of silicon is 28.10 amu, estimate the percent abundance of the most abundant isotope of silicon.

Answers

Answer:

Silicon-28

Explanation:

To estimate the isotope with the highest percentage of abundance, we look at which of the isotopes have the closest resemblance to the value of the final atomic mass.

From what is given, it can be observed that the isotope with the highest value is that of the 28 because it can be seen that it is large enough to have affected the value of the isotope near it.

How many moles of CO2 are in 116.3 g?

Answers

Answer:

5118.30485 moles

Explanation:

There are approximately 44.0095 moles of CO2 in 1 gram. So just multiply 44.0095 by  116.3.

answer: 5118.30485 moles

__________ are typically organic materials. They are usually good electrical and thermal insulators and generally have very good strength-to-weight ratios. They are generally not suitable for high temperature applications.
a. Polymers
b. Metals and Alloys
c. Ceramics
d. Semiconductors

Answers

Answer:

a

Explanation:

What mass of ethanol (C2H5OH(ℓ)) must be burned to supply 500 kJ of heat? The standard enthalpy of combustion of ethanol at 298 K is −1368 kJ · mol−1

Answers

Answer:

16.8 g

Explanation:

We are told than burning one mol of ethanol releases 1368 kJ. Now we are trying to find how much ethanol has to be burned, in grams, to release 500 kJ

We use ratios

-1368 kJ : 1 mole

-500 kJ :      x

Then you cross multiply

-1368x = -500

       x = 0.3655 mol

mass = number of moles * molar mass

        = 0.3655 mol * 46.07 g/mol

        = 16.8 g

The mass of ethanol ([tex]C_2H_5OH_{(l)}[/tex]) that must be burned to supply 500 kJ of heat is 16.84 grams.

Given the following data:

Standard enthalpy of combustion of ethanol = −1368 kJ/mol.Temperature = 298 K

We know that the molar mass of ethanol ([tex]C_2H_5OH_{(l)}[/tex]) is equal to 46.07 g/mol.

To calculate the mass of ethanol ([tex]C_2H_5OH_{(l)}[/tex]) that must be burned to supply 500 kJ of heat:

By stoichiometry:

1 mole of ethanol = 1368 kJ of heat

X mole of ethanol = 500 kJ

Cross-multiplying, we have:

[tex]1368 \times X = 500\\\\X = \frac{500}{1368}[/tex]

X = 0.3655 moles

Now, we can determine the mass of ethanol required:

[tex]Mass = molar \;mass \times number\;of\;moles\\\\Mass = 46.07 \times 0.3655[/tex]

Mass = 16.84 grams

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High-density polyethylene is composed of:_______.
a) a mixture of polyethylene and polystyrene.
b) primarily linear, unbranched chains of polyethylene in a close packing arrangement.
c) polyethylene with high density plasticizers added to increase density.
d) primarily highly branched, non-linear chains of polyethylene in a diffuse packing arrangement.

Answers

Answer:

c. ) polyethylene with high density plasticizers added to increase density.

Explanation:

High - density polyethylene -

Polyethylene is a crystalline structure , which have a very wide area of application , it is a type of thermoplastic polymer .

It is produced in huge tons every year due to its wide range of application.

Commercially it is produced by the very famous , the Ziegler - Natta catalysts .

In the polyethylene , a high - density polyethylene is added in order increase its density , and hence this type of polyethylene is referred to as high - density polyethylene .

Final answer:

High-density polyethylene (HDPE) is composed of primarily linear, unbranched chains of polyethylene in a close packing arrangement. This structure gives HDPE a higher tensile strength and makes it suitable for stronger and more rigid products.

Explanation:

High-density polyethylene (HDPE) is composed of primarily linear, unbranched chains of polyethylene in a close packing arrangement. Therefore, the correct answer is b). HDPE has a relatively low degree of branching, which allows the polymer chains to pack closely together, resulting in stronger intermolecular forces and a higher tensile strength compared to more highly branched polymers like low-density polyethylene (LDPE). HDPE's characteristics make it suitable for use in products that require strength and rigidity, such as detergent bottles, milk jugs, and water pipes.

In contrast, LDPE has a higher degree of branching, which prevents the polymer chains from packing as tightly, leading to a more flexible material with a lower tensile strength. This type of polyethylene is used for products that need to be more flexible, such as beach balls and plastic bags. HDPE and LDPE are both types of polyethylene, but they have different properties due to their molecular structure and how the polymer chains pack together.

Read the statement. ________ is the energy that transfers from one object to another due to a difference in __________. Which option correctly describes how to complete this statement?

Answers

Answer:

a. Heat Energy

b. Temperature

Explanation: Heat energy are transferred from one point to another due to difference in temperature

Identify the true statement. Choose one: A. The expansion of ice sheets at the end of the Pleistocene caused glacial rebound in northern Canada. B. Regions covered by glacial ice are termed periglacial environments. C. Glaciers move by basal sliding as friction between the ice and its substrate increases. D. The Antarctic ice sheet has been calving off huge icebergs over the last few decades.

Answers

Answer:

Option (D)

Explanation:

Antarctica is located in the south pole and covers a large area of ice-covered region. It is an extremely cold environment, having a low freezing temperature. The glaciers and ice-bergs of this region has been constantly affected due to the increasing global surface temperature. This rise in the surface temperature of the earth is due to the increasing concentration of CO₂ in the atmosphere. One of the reasons for this temperature increase is also due to the introduction of the industrial revolution, which is responsible for the emission of a large number of harmful gases, including carbon into the atmosphere. Due to this global climate change, these glaciers are melting at a faster rate, resulting in the rise of the sea level.

Thus, the Antarctic ice sheets have been calving off large pieces of icebergs over the last few decades.

Hence, the correct answer is option (D), which is the true statement.

In some vintage science fiction movies, space travelers find themselves on a planet orbiting a distant star in which there are curious forms of life based on silicon instead of carbon. Although the story clearly is sci-fi, there is an aura of plausibility in the choice of silicon, an atom with 14 protons, in place of carbon as this alien life-form's central atom. The reason is that silicon:

Answers

Answer:

yes because it is a great planet

Explanation:

because of the reason for silicon

Which stratigraphic principle states the fact that sedimentary rocks are deposited in layers perpendicular to the direction of gravity?

Answers

Answer:

omework Help. Steno's laws of stratigraphy describe the patterns in which rock layers are deposited. The four laws are the law of superposition, law of original horizontality, law of cross-cutting relationships, and law of lateral continuity.

Explanation:

If 0.40 mol of H2 and 0.15 mol of O2 were to react as completely as possible to produce H2O what mass of reactant would remain?

Answers

Answer : The mass of reactant [tex]H_2[/tex] remain would be, 0.20 grams.

Solution : Given,

Moles of [tex]H_2[/tex] = 0.40 mol

Moles of [tex]O_2[/tex] = 0.15 mol

Molar mass of [tex]H_2[/tex] = 2 g/mole

First we have to calculate the limiting and excess reagent.

The balanced chemical reaction is,

[tex]2H_2+O_2\rightarrow 2H_2O[/tex]

From the balanced reaction we conclude that

As, 1 mole of [tex]O_2[/tex] react with 2 mole of [tex]H_2[/tex]

So, 0.15 moles of [tex]O_2[/tex] react with [tex]0.15\times 2=0.30[/tex] moles of [tex]H_2[/tex]

From this we conclude that, [tex]H_2[/tex] is an excess reagent because the given moles are greater than the required moles and [tex]O_2[/tex] is a limiting reagent and it limits the formation of product.

The moles of reactant [tex]H_2[/tex] remain = 0.40 - 0.30 = 0.10 mole

Now we have to calculate the mass of reactant [tex]H_2[/tex] remain.

[tex]\text{ Mass of }H_2=\text{ Moles of }H_2\times \text{ Molar mass of }H_2[/tex]

[tex]\text{ Mass of }H_2=(0.10moles)\times (2g/mole)=0.20g[/tex]

Therefore, the mass of reactant [tex]H_2[/tex] remain would be, 0.20 grams.

Answer:

The remaining mass of [tex]\rm H_2[/tex] in the reaction is 0.20 grams.

Explanation:

The balanced equation for the reaction will be:

[tex]\rm 2\; H_2 \; + O_2 \rightarrow\; 2\; H_2O[/tex]

1 mole of [tex]\rm O_2[/tex] reacts with 2 moles of [tex]\rm H_2[/tex] to gives 2 moles of [tex]\rm H_2O[/tex].

0.15 moles of [tex]\rm O_2[/tex] reacts with 2 * 0.15 = 0.30 moles of [tex]\rm H_2[/tex]

We have 0.40 moles of [tex]\rm H_2[/tex]

So remaining [tex]\rm H_2[/tex]= 0.40 moles - 0.30 moles

                         = 0.10 moles

Mass = moles * molar mass

Molar mass of [tex]\rm H_2[/tex] = 2 g/mol

Mass of [tex]\rm H_2[/tex] remained in the reaction = 0.10 moles * 2 g/mole

                                                            = 0.20 grams.

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sample of copper(II) sulfate pentahydrate, CuSO4⋅5H20 , is heated to remove the water of hydration from the crystals. The mass of the original sample before heating was 50.00 grams. If the mass of the cool, dry sample after heating is 34.95 grams, find the experimental percentage of water in the hydrate.

Answers

Answer:

30.10%

Explanation:

The mass of water is:

50.00 g − 34.95 g = 15.05 g

So the percentage of water is:

15.05 g / 50.00 g × 100% = 30.10%

Final answer:

The experimental percentage of water in copper(II) sulfate pentahydrate, after heating a sample and measuring the mass loss, is calculated to be 30.10%.

Explanation:

Experimental Percentage of Water in a Hydrate

The question involves calculating the percentage of water in a hydrate, specifically copper(II) sulfate pentahydrate, which is a classic chemistry experiment. To determine the percentage of water, you have to compare the mass of water lost upon heating to the original mass of the hydrate.

First, calculate the loss of mass due to heating: 50.00 grams (initial mass) - 34.95 grams (final mass) = 15.05 grams of water lost.

Percentage of water in the hydrate is found by the formula:
Mass% of H₂O = (Mass of water lost / Original mass of hydrate) * 100%.
Substituting the known values gives us: Mass% of H₂O = (15.05 g / 50.00 g) * 100% = 30.10%.

The experimental percentage of water in the copper(II) sulfate pentahydrate is therefore 30.10%, which is determined by this experimental process of heating and weighing.

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