In the hydrogenation of ethylene using a nickel catalyst, the initial concentration of ethylene is 1.50 mol * L−1 and its rate constant (k) is 0.0016 mol * L−1 * s−1.
a. Determine the rate of reaction if it follows a zero-order reaction mechanism.

Answer:

Answers explained below

Explanation:

(a)Given,

Molecular formula of the complex = [Ni(NH3)x(H2O)y]Clz

(i) Ni is in +2 oxidation state in the complex.

(ii) NH3 and H2O are the neutral ligands but Cl  is the negatively charged ligand.

(iii) complex is neutral

So, to make the nickel complex in +2 oxidation with neutral charge, we requires 2 Cl-.

Hence, form the above statements, we can say that here in the complex

z=2

(b) Molarity of HCl = 0.2005M

Volume of HCl used = 20.02mL = 20.02*10-3 L

Weight of the nickel(II) ammonia complex = 0.1550g

Reaction of HCl with Ammonia,

HCl (aq) + NH3 (aq) -> NH4Cl (aq)

HCl reacts with ammonia in 1:1 ratio to form ammonium salt (NH4Cl). That means 1 mol of HCl reacts with 1 mol of NH3.

So, we have to find number of moles of HCl used.

No. of moles of HCl used = Molarity of HCl * Volume of HCl used (L)

= 0.2005M * 20.02*10-3 L = 4.014*10-3 moles

Hence no. of moles of ammonia in the complex = No. of moles of HCl used = 4.014*10-3 mol

So, Experimental Equivalent Weight = Weight of the nickel(II) ammonia complex/ No. of moles of NH3

= 0.1550g / 4.014*10-3 mol

= 38.615 g/mol

Hence, Experimental Equivalent Weight = 38.615 g/mol

(c) Given,

x+y=< 6

Molar mass of [Ni(NH3)x(H2O)y]Clz = 58.69 + x(14.00+3*1) + y(16+2*1)+z(35.45)

= (58.69 + 17x + 18y + 35.45z) g/mol

Case1 x=6, y=0 and z=2

Molar mass of [Ni(NH3)6(H2O)0]Cl2   = (58.69 + 17*6 + 18*0 + 35.45*2) g/mol

= 58.69+102+70.90 = 231.59 g/mol

Experimental Equivalent Weight = 233.59/6 = 38.598 g/mol

So, This experimental equivalent weight is equal to the calculated experimental equivalent weight.

Hence the molecular formula of the complex is [Ni(NH3)6]Cl2 where x=6, y=0 and z=2.

Note: You can try other combination but in every case you will find lower or higher calculated experimental equivalent weight.

Answer:

a. 100:11

Explanation:

M+1 peak is observed due to the presence of an isotope of an atom in a molecule. Decane has the molecular formula C₁₀H₂₂, so the probability of having 13C atom in this molecule increases ten times. This gives the ratio between M+ and M+1 peak 100:11.

It should be noted that the decane molecule also contains hydrogen atoms whose isotope deuterium (2H) can also be present in the molecule and give M+1 peak. But its relative abundance to protium (1H) is low i.e., 0.015, so its effect can be neglected.

A simple formula for the estimation of the relative peak height of M+1 in a molecule that contains C, H, N, O, F, Si, P, and S is:

[tex][M+1] = (number of C X 1.1) + (number of H X 0.015) + (number of N X 0.37) + (number of O X 0.04) + (number of S X 0.8) + (number of Si X 5.1)[/tex]

PS: remove the element from the formula which is not present in the molecule

Answer:

0.102 cal/g.°C

Explanation:

According to the law of conservation of energy, the sum of the heat released by the electric burner (Qb) and the heat absorbed by the water (Qw) is zero.

Qb + Qw = 0

Qb = -Qw

Both heats can be calculated using the following expression.

Q = c × m × ΔT

where,

c: specific heat

m: mass

ΔT: change in the temperature

Then,

Qb = -Qw

cb × mb × ΔTb = - cw × mw × ΔTw

cb = - cw × mw × ΔTw / mb × ΔTb

cb = - (1 cal/g.°C) × 552.0 g × (80.3°C - 23.2°C) / 683.0 g × (23.2°C - 477.6°C)

cb = 0.102 cal/g.°C

Answer: The formula of the compound formed between rubidium and fluorine is RbF

Explanation:

Ionic bond is defined as the bond which is formed by complete transfer of electrons from one atom to another atom.

The atom which looses the electron is known as electropositive atom and the atom which gains the electron is known as electronegative atom. This bond is usually formed between a metal and a non-metal.

Rubidium is the 37th element of the periodic table having electronic configuration of [tex]1s^22s^22p^63s^23p^64s^23d^{10}4p^65s^1[/tex]

This will loose 1 electron to form [tex]Rb^+[/tex] ion

Fluoride is the 9th element of the periodic table having electronic configuration of [tex]1s^22s^22p^5[/tex]

This will gain 1 electron to form [tex]F^-[/tex] ion

To form [tex]RbF[/tex] compound, 1 rubidium ion is needed to neutralize the charge on fluoride ion

The formation of the given compounds is shown in the image below.

Explanation:

Relation between [tex]k_{f}[/tex], molality and temperature is as follows.

                 T = [tex]K_{f} \times m \times i[/tex]

It is also known as depression between freezing point where, i is the Van't Hoff factor.

Let us assume that there is 100% dissociation. Hence, the value of i for these given species will be as follows.

          i for [tex]CaCl_{2}[/tex] = 3

           i for glucose = 1

           i for NaCl = 2

Depression in freezing point will have a negative sign. Therefore, d

depression in freezing point for the given species is as follows.

        [tex]T_{CaCl_{2}} = -1.86 \times 0.45 \times 3[/tex]

                  = [tex]-2.511^{o}C[/tex]

        [tex]T_{glucose} = 1.86 \times 0.45 \times 1[/tex]

                   = [tex]-0.837^{o}C[/tex]

       [tex]T_{NaCl} = -1.86 \times 0.45 \times 2[/tex]

                    = [tex]-1.674^{o}C[/tex]

Therefore, we can conclude that given species are arranged according to their freezing point depression with the least depression first as follows.

                     Glucose < NaCl < [tex]CaCl_{2}[/tex]

Explanation:

In the previous question, you calculated the amount of CO2 that was required to heat the air in your room. Which of the following are true statements?

You didn't complete the above question, please complete the question and reupload, thanks for your anticipated cooperation.

Answer: [tex]2NaOH(aq)+MgCl_2(aq)\rightarrow NaCl(aq)+Mg(OH)_2(s)[/tex]

Explanation:

According to the law of conservation of mass, mass can neither be created nor be destroyed. Thus the mass of products has to be equal to the mass of reactants. The number of atoms of each element has to be same on reactant and product side. Thus chemical equations are balanced.

A double displacement reaction is one in which exchange of ions take place. The salts which are soluble in water are designated by symbol (aq) and those which are insoluble in water and remain in solid form are represented by (s) after their chemical formulas.

[tex]2NaOH(aq)+MgCl_2(aq)\rightarrow NaCl(aq)+Mg(OH)_2(s)[/tex]

Answer: 20%

Explanation:

Relative error = Absolute error/actual value

= 0.1/0.5

= 0.2

Hence,

Minimum % Relative error = 0.2 ×100%

= 20%

Answer:20%

Explanation:

Let us take some important definitions of some terms in the question.

What is an ABSOLUTE ERROR?.

Absolute error is the difference between the expected value and the value you got from an experimental calculations or the approximations made. It can be represented mathematically in the equation (1) below;

Absolute error= expected value - Approximated/measured value. ---------------------------------------------------------------------(1).

What is A RELATIVE ERROR?.

A relative error is the the ratio of absolute value to that of the exact value. This can be illustrated mathematically by the equation (2) below;

Relative error= absolute error/exact value. --------------------------------------(3).

From equation (2) the solutio to the question is;

Relative error= absolute error/exact value.

Relative error=[ 0.1/0.5] = 0.2.

Relative error Percentage= 0.2×100= 20 Percent.

The temperature at which zirconium becomes superconducting in degrees Celsius is approximately 272.85°C.

To convert the temperature from millikelvin (mk) to degrees Celsius (°C), we need to use the formula:

T(°C) = T(mk) - 273.15

Applying this formula to the given temperature of 546 mk:

T(°C) = 546 - 273.15 = 272.85°C

Therefore, the temperature at which zirconium becomes superconducting in degrees Celsius is approximately 272.85°C.

https://brainly.com/question/31229398

#SPJ3

Answer:

It will take 950 million years for this amount of urea to be hydrolyzed under the same conditions in the absence of urease.

Explanation:

Given that:

Urease enhances the rate of hydrolysis by = 10^14

Time taken in hydrolysis is 5 min

Time taken in hydrolysis will be = 5 min x 10^14

Now, converting minutes into years

 Time   =  (5 min x 10^14) / (60 min/hr x 24 hr/day x 365 days/year)

Time = 9.50 x 10^8 years

Time = 950 X 10^6 years

Time = 950 million years

Answer:

Explanation:

The enzyme increases the rate of urea hydrolysis by a factor of [tex]10^{14}[/tex]

So in absence of enzyme, reaction will take [tex]10^{14}[/tex] times more time for completion.

Therefore time taken,

[tex]\frac{rate catalysed}{rate uncatalysed} = 10^{14}[/tex]

[tex]\frac{t uncatalysed}{t catalysed} = 10^{14}\\\\t uncatalysed = 10^{14} * 5min\\\\t uncatalysed = 5*10^{14}min[/tex]

For more information, visit

https://brainly.com/question/14555858

Answer: e) all of these

Explanation:

Element is a pure substance which is composed of atoms of similar elements.It can not be decomposed into simpler constituents using chemical reactions.Example: Copper

Compound is a pure substance which is made from atoms of different elements combined together in a fixed ratio by mass.It can be decomposed into simpler constituents using chemical reactions. Example: water  [tex](H_2O)[/tex], carbon dioxide [tex](CO_2)[/tex]

Mixtures are not pure substances as they consist of elements and compounds combined physically and not in any fixed ratio. Example: Air

Thus all given substances are pure substances.

Final answer:

The correct answer to the example of a pure substance is e) all of these, which includes elements, compounds, water (H₂O), and carbon dioxide (CO₂).

Explanation:

An example of a pure substance can be any of the following: a) an element, b) a compound, c) H₂O (which is water, a compound), and d) carbon dioxide (also a compound). Therefore, the correct answer to the question is e) all of these.

A pure substance has a constant composition and characteristic properties. Each element is made up of one type of atom, and cannot be broken down further by chemical means. Examples include carbon and oxygen. On the other hand, a compound is constituted by two or more elements chemically bonded in a fixed ratio, such as water (H₂O) and carbon dioxide (CO₂).

Answer:

Mole fraction of [tex]CH_4O[/tex] = 0.58

Mole fraction of [tex]C_2H_6O[/tex] = 0.42

Explanation:

Let the mass of [tex]CH_4O[/tex] and [tex]C_2H_6O[/tex] = x g

Molar mass of [tex]CH_4O[/tex] = 33.035 g/mol

The formula for the calculation of moles is shown below:

[tex]moles = \frac{Mass\ taken}{Molar\ mass}[/tex]

Thus,

[tex]Moles_{CH_4O}= \frac{x\ g}{33.035\ g/mol}[/tex]

[tex]Moles_{CH_4O}=\frac{x}{33.035}\ mol[/tex]

Molar mass of [tex]C_2H_6O[/tex] = 46.07 g/mol

Thus,

[tex]Moles= \frac{x\ g}{46.07\ g/mol}[/tex]

[tex]Moles_{C_2H_6O}=\frac{x}{46.07}\ mol[/tex]

So, according to definition of mole fraction:

[tex]Mole\ fraction\ of\ CH_4O=\frac {n_{CH_4O}}{n_{CH_4O}+n_{C_2H_6O}}[/tex]

[tex]Mole\ fraction\ of\ CH_4O=\frac{\frac{x}{33.035}}{\frac{x}{33.035}+\frac{x}{46.07}}=0.58[/tex]

Mole fraction of [tex]C_2H_6O[/tex] = 1 - 0.58 = 0.42

Answer:

a) 0.046 mol/L

b) 0.016 mol

c) 271.58 g/mol

Explanation:

A nonelectrolyte solute is a solute that, when dissolved in a solvent, will not make the solution a conductor, and so the electricity will not pass through it. The osmotic pressure is a colligative property, and it's the pressure difference needed to stop the flow of a solution across a semipermeable membrane. It can be calculated by:

π = MRT

Where π is the osmotic pressure, M is the molarity of the solute (mol/L), R is the ideal gas constant, and T is the temperature (in K). For a pressure in torr, R = 62.3637 torr.L/(mol.K).

a) π = MRT , T = 25°C = 298 K

851 = M*62.3637*298

18584.3826M = 851

M = 0.046 mol/L

b) The number of moles of the solute (n) is the molar concentration (molarity) multiplied by the volume. So, for a solution of 345 mL = 0.345 L,

n = 0.046 * 0.345

n = 0.016 mol

c) The molar mass (MM) is the mass divided by the number of moles:

MM = 4.31/0.016

MM = 271.58 g/mol

Answer:

79.0 mL

Explanation:

Given data

In order to find the volume required of the concentrated solution, we will use the dilution rule.

C₁ × V₁ = C₂ × V₂

V₁ = C₂ × V₂/C₁

V₁ = 1.00 M × 790.0 mL/10.0 M

V₁ = 79.0 mL

Percent ionic character of bonds is estimated from the electronegativity difference between the bonded atoms - TiO2 has moderate ionic character, ZnTe has low, CsCl has an ionic character, InSb less ionic character and MgCl2 has significant ionic character.

The percent ionic character of the bonds in a compound can be estimated based on the electronegativity difference between the bonded atoms. Ionic character increases with the increasing difference in electronegativity, i.e., higher the electronegativity difference, higher the ionic character.

https://brainly.com/question/32093021

#SPJ3

The percent ionic character of a bond is estimated using the difference in electronegativity between the bonded atoms. For the given compounds, the calculated percent ionic characters are: TiO₂ (75%), ZnTe (9.41%), CsCl (75.15%), InSb (4%), and MgCl₂ (59.4%). This demonstrates the varying degrees of ionic versus covalent character in each compound.

The percent ionic character of a bond is determined by the difference in electronegativity between the two atoms involved. Linus Pauling proposed an empirical relation to calculate it:

Percent Ionic Character =  10.16(Δχ)²  - 2(57.9 - Δχ)²

Now, let's calculate the percent ionic character for each compound:

1. TiO2

Electronegativity of Ti (Titanium) = 1.54

Electronegativity of O (Oxygen) = 3.44

Δχ = 3.44 - 1.54 = 1.90

Using the formula, Percent Ionic Character = 1-(6-2 × (1.9)^2) x 100 = 75%

2. ZnTe

Electronegativity of Zn (Zinc) = 1.65

Electronegativity of Te (Tellurium) = 2.1

Δχ = 2.1 - 1.65 = 0.45

Using the formula, Percent Ionic Character = 9.41%

3. CsCl

Electronegativity of Cs (Caesium) = 0.79

Electronegativity of Cl (Chlorine) = 3.16

Δχ = 3.16 - 0.79 = 2.37

Using the formula, Percent Ionic Character = 75.15%

4. InSb

Electronegativity of In (Indium) = 1.78

Electronegativity of Sb (Antimony) = 2.05

Δχ = 2.05 - 1.78 = 0.27

Using the formula, Percent Ionic Character = 4%

5. MgCl2

Electronegativity of Mg (Magnesium) = 1.31

Electronegativity of Cl (Chlorine) = 3.16

Δχ = 3.16 - 1.31 = 1.85

Using the formula, Percent Ionic Character = 59.4%

The Haber process increased agricultural productivity and human support through the large-scale production of fertilizers, but it also enabled the creation of harmful chemical weapons and resulted in environmental issues such as algal blooms and dead zones.

The Haber process, developed by Fritz Haber in the early 20th century, had both positive and negative effects. The positive effects of this process include the mass production of nitrogen fertilizers, which increased agricultural productivity and the sustainable support of human populations. An example of this is the jump in the number of humans per hectare that arable land could support, increasing from 1.9 in 1908 to 4.3 by 2008.

However, there are also negative consequences associated with the Haber process. It enabled the creation of harmful chemical weapons during the World War, marking a dark turn in its utilization. Also, the excessive use of nitrogen-based fertilizers, majorly produced through this process, has led to detrimental environmental consequences such as algal blooms, red tides, and dead zones in water bodies. These effects end up destroying marine life and disrupting ecosystems.

https://brainly.com/question/26667299

#SPJ3

B. The salt bridge will become weaker.

Therefore, the salt bridge will become weaker, so option B is correct.

Find more information about "Salt bridge" here:

brainly.com/question/18066138

The salt bridge between glutamic acid and histidine will be unaffected as the pH increases from pH 6.9 to pH 7.5.

The salt bridge between glutamic acid and histidine will be unaffected as the pH increases from pH 6.9 to pH 7.5.

Glutamic acid has a pKa of 4.2, meaning that at pH 6.9, the glutamic acid side chain will be in its deprotonated form, which is negatively charged. Histidine has a pKa of 6.5, so at pH 6.9, the histidine side chain will be in its protonated form, which is positively charged.

As the pH increases to 7.5, both glutamic acid and histidine will become less charged, but the relative charges of the two side chains will remain the same, thus the salt bridge between them will be unaffected.

Answer:

The student should use 156.7 g of solution

Explanation:

31.9 %w solution of acetic acid in ethanol means 100 g of solution contains 31.9 g of acetic acid.

So, 450. g of solution contains [tex](\frac{31.9\times 450.}{100})g[/tex] of acetic acid or 143.55 g of acetic acid

Alternatively, 143.55 g of acetic acid is present in 450. g of solution

So, 50.00 g of acetic acid is present in [tex](\frac{450.\times 50.00}{143.55})g[/tex] solution or 156.7 g of solution

Hence the student should use 156.7 g of solution

LED light bulbs exhibit the highest energy efficiency among incandescent, fluorescent, and LED bulbs due to their ability to produce a significant amount of light energy while minimizing heat energy dissipation.

Looking at the graph, it is evident that LED light bulbs exhibit the highest efficiency among the three types. This conclusion can be drawn from the fact that LED bulbs produce a significant amount of light energy while minimizing heat energy dissipation. LEDs achieve this by converting a higher proportion of electrical energy into visible light, making them more energy-efficient than incandescent and fluorescent counterparts.

On the other hand, incandescent bulbs, characterized by the highest heat output on the graph, are the least efficient. This is because a substantial portion of the electrical energy is transformed into heat, contributing to energy loss rather than useful light output.

The claim that fluorescent bulbs are the most energy-efficient due to a balanced distribution of light and heat is not supported by the graph. While fluorescents fare better than incandescents, they fall short of the high efficiency demonstrated by LED bulbs. Therefore, the correct conclusion is that LED light bulbs provide superior energy efficiency by generating more light energy and less heat energy compared to incandescent and fluorescent alternatives.

Complete Question:

To aid in the prevention of tooth decay, it is recommended that drinking water contain 0.800 ppm fluoride. How many grams of F− must be added to a cylindrical water reservoir having a diameter of 2.02 × 102 m and a depth of 87.32 m?

Answer:

2.23x10⁶ g

Explanation:

The concentration of the fluoride (F⁻) must be 0.800 ppm, which is 0.800 parts per million, so the water must have 0.800 g of F⁻/ 1000000 g of the solution. The density of the water at room temperature is 997 kg/m³ = 997x10³ g/m³. So, the concentration of the fluoride will be:

0.800 g of F⁻/ 1000000 g of the solution * 997x10³ g/m³

0.7976 g/m³

The volume of the reservoir is the volume of the cylinder: area of the base * depth. The base is a circumference, which has an area:

A = πR², where R is the radius = 1.01x10² m (half of the diameter)

A = π*(1.01x10²)²

A = 32047 m²

The volume is then:

V = 32047 * 87.32

V = 2.7983x10⁶ m³

The mass of the F⁻ is the concentration multiplied by the volume:

m = 0.7976 * 2.7983x10⁶

m = 2.23x10⁶ g

The question is incomplete, here is the complete question:

A chemist measures the amount of bromine liquid produced during an experiment. She finds that 766.g of bromine liquid is produced. Calculate the number of moles of bromine liquid produced. Round your answer to 3 significant digits.

Answer: The amount of liquid bromine produced is 4.79 moles.

Explanation:

To calculate the number of moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]

We are given:

Given mass of liquid bromine = 766. g

Molar mass of liquid bromine, [tex](Br_2)[/tex] = 159.8 g/mol

Putting values in above equation, we get:

[tex]\text{Moles of liquid bromine}=\frac{766.g}{159.8g/mol}=4.79mol[/tex]

Hence, the amount of liquid bromine produced is 4.79 moles.

Answer: It will occupy [tex]4.45\times 10^3ml[/tex] at the same temperature and 475 mm Hg.

Explanation:

Boyle's Law: This law states that pressure is inversely proportional to the volume of the gas at constant temperature and number of moles.

[tex]P\propto \frac{1}{V}[/tex]     (At constant temperature and number of moles)

[tex]P_1V_1=P_2V_2[/tex]    (At constant temperature and number of moles)

where,

[tex]P_1[/tex] = initial pressure of gas = 760 mm Hg

[tex]P_2[/tex] = final pressure of gas = 475 mm Hg

[tex]V_1[/tex] = initial volume of gas = [tex]2.78\times 10^3ml[/tex]

[tex]V_2[/tex]  = final volume of gas = ?

Putting in the values:

[tex]760mm Hg\times 2.78\times 10^3ml=475 mm Hg\times V_2[/tex]

[tex]V_2=4.45\times 10^3ml[/tex]

Thus it will occupy [tex]4.45\times 10^3ml[/tex] at the same temperature and 475 mm Hg

The volume that it will occupy at the same temperature is 4448mL

According to Boyle's law, the pressure of a given mass of gas is inversely proportional to the volume. It is expressed mathematically as:

[tex]P\alpha\frac{1}{V}\\P=\frac{k}{V}\\PV=k[/tex]

This can be expressed as [tex]P_1V_1=P_2V_2[/tex]

Given the following parameters

P₁ = 760mmHg

V₁ = 2.78 x 10³ mL

P₂ = 475mmHg

V₂ = ?

Substitute the given parameters into the formula

[tex]V_2=\frac{P_1V_1}{P_2}\\V_2=\frac{760\times 2780}{475}\\V_2= 4448mL[/tex]

Hence the volume that it will occupy at the same temperature is 4448mL

learn more here: https://brainly.com/question/1696010

The alkyl bromide used is Tertiary-Butyl Bromide and the alcohol used is Methanol. The reaction involves reacting Tertiary-Butyl Bromide with Sodium Methoxide to form methyl t-butyl ether and Sodium Bromide as a byproduct.

The alkyl bromide and alcohol used to make methyl t-butyl ether using the Williamson ether synthesis are:

Alkyl Bromide: Tertiary-Butyl Bromide (C4H9Br)

Alcohol: Methanol (CH3OH)

Step 1: React Tertiary-Butyl Bromide (C4H9Br) with Sodium Methoxide (CH3ONa).

Step 2: Heating the reaction mixture will result in the formation of methyl t-butyl ether (MTBE) and Sodium Bromide (NaBr) as byproduct.

For more such questions on methyl t-butyl, click on:

https://brainly.com/question/33650659

#SPJ6

Answer:

Mass of heptane = 102g

Vapor pressure of heptane = 454mmHg

Molar mass of heptane = 100.21

No of mole of heptane = mass/molar mass = 102/100.21

No of mole of heptane = 1.0179

Therefore the partial pressure of heptane = no of mole heptane *Vapor pressure of heptane

Partial pressure of heptane = 1.0179*454mmHg

Partial pressure of heptane = 462.1096 = 462mmHg

the partial pressure of heptane vapor above this solution = 462mmHg

The partial pressure of the heptane vapor above the solution is calculated using Raoult's law as 214.5 mmHg.

In order to calculate the partial pressure, we will use Raoult's law, which states that the partial pressure of a component in a mixture is equal to the vapor pressure of the pure component multiplied by its mole fraction in the mixture. First, we need to calculate the mole fraction, which is calculated as:

moles of component/total moles in the mixture.

We first need to determine the number of moles of heptane and chloroform, using their respective molecular weights (C₇H₁₆ is approximately 100.21 g/mol, CHCl₃ is about 119.38 g/mol).

Moles of C₇H₁₆ = 102 g / 100.21 g/mol = 1.018 mol

Moles of CHCl₃= 135 g / 119.38 g/mol = 1.131 mol

To determine the mole fraction of the heptane, we take the moles of heptane and divide by the total moles.

X_C₇H₁₆ = 1.018 mol / (1.018 mol + 1.131 mol) = 0.473

Applying Raoult's law, the partial pressure of heptane P_C₇H₁₆ = X_C₇H₁₆ ₓ P(C₇H₁₆, pure) = 0.473 ₓ 454 mmHg = 214.5 mmHg.

So, the partial pressure of heptane vapor above the solution is 214.5 mmHg.

https://brainly.com/question/35280352

#SPJ2

Answer:

344 nm is the longest wavelength of radiation with enough energy to break carbon-carbon bonds.

Explanation:

[tex]C-C(g)\rightarrow 2C(g)[/tex] ,ΔH = 348 kJ/mol

Energy required to break 1 mole of C-C bond = 348 kJ

Energy required to break 1 C-C bond = E

[tex]E = \frac{348,000J}{6.022\times 10^{23}}=5.779\times 10^{-19} J[/tex]

Energy related with the wavelength of light is given by Planck's equation:

[tex]E=\frac{hc}{\lambda }[/tex]

[tex]\lambda =\frac{hc}{E}[/tex]

[tex]=\frac{6.626\times 10^{-34} Js\times 3\times 10^8 m/s}{5.779\times 10^{-19} J}[/tex]

[tex]\lambda =3.44\times 10^{-7} m = 344 nm[/tex]

[tex]1 m =10^9 nm[/tex]

344 nm is the longest wavelength of radiation with enough energy to break carbon-carbon bonds.

Ultraviolet radiation and radiation of shorter wavelengths can break carbon-carbon bonds within biological molecules. The longest wavelength that can break carbon-carbon bonds is approximately 1.72 x 10^-6 meters or 1720 nm.

Ultraviolet radiation and radiation of shorter wavelengths can damage biological molecules because they carry enough energy to break bonds within the molecules. A carbon-carbon bond requires 348 kJ/mol to break. To find the longest wavelength of radiation with enough energy to break carbon-carbon bonds, we can use the equation E = hc/λ, where E is the energy, h is Planck's constant (6.626 x 10^-34 J·s), c is the speed of light (3.00 x 10^8 m/s), and λ is the wavelength. Rearranging the equation to solve for λ, we get λ = hc/E. Substituting the given energy of 348 kJ/mol (which is equivalent to 348,000 J/mol) and solving for λ, we find that the longest wavelength is approximately 1.72 x 10^-6 meters or 1720 nm.

https://brainly.com/question/4075566

#SPJ12

Answer:

The mass of xenon in the compound is 2.950 grams

Explanation:

Step 1: Data given

Mass of XeF4 = 4.658 grams

Molar mass of XeF4 = 207.28 g/mol

Step 2: Calculate moles of XeF4

Moles XeF4 = mass XeF4 / molar mass XeF4

Moles XeF4 = 4.658 grams / 207.28 g/mol

Moles XeF4 = 0.02247 moles

Step 3: Calculate moles of xenon

XeF4 → Xe + 4F-

For 1 mol xenon tetrafluoride, we have 1 mol of xenon

For 0.02247 moles XeF4 we have 0.02247 moles Xe

Step 4: Calculate mass of xenon

Mass xenon = moles xenon * molar mass xenon

Mass xenon = 0.02247 moles * 131.29 g/mol

Mass xenon = 2.950 grams

The mass of xenon in the compound is 2.950 grams

To calculate the number of grams of xenon in 4.658 g of xenon tetrafluoride, we need to determine the molar mass of XeF4 and convert grams to moles. The molar mass of XeF4 is 207.282 g/mol. Using this molar mass, we find that there are 0.0225 moles of XeF4, which corresponds to 2.968 grams of xenon.

To calculate the number of grams of xenon in 4.658 g of xenon tetrafluoride, we need to first determine the molar mass of xenon tetrafluoride (XeF4) and then use it to convert grams to moles. The molar mass of XeF4 is calculated as follows:

Molar mass of Xe = 131.293 g/mol

Molar mass of F = 18.998 g/mol

Molar mass of XeF4 = (131.293 g/mol) + 4 * (18.998 g/mol) = 207.282 g/mol

Now, we can use the molar mass to convert grams to moles:

Moles of XeF4 = (4.658 g) / (207.282 g/mol) = 0.0225 mol

Finally, we can convert moles of XeF4 to grams of xenon:

Grams of xenon = (0.0225 mol) * (131.293 g/mol) = 2.968 g

https://brainly.com/question/30096298

#SPJ11

Answer: The millimoles of sodium carbonate the chemist has added to the flask are 256

Explanation:

Molarity is defined as the number of moles dissolved per liter of the solution.

To calculate the number of moles for given molarity, we use the equation:

[tex]\text{Molarity of the solution}=\frac{\text{milli moles of solute}}{\text{Volume of solution in ml}}[/tex]     .....(1)

Molarity of [tex]BaCl_2[/tex] solution = 1.42 M

Volume of solution = 180.0 mL

Putting values in equation 1, we get:

[tex]1.42M=\frac{\text{milli moles of }BaCl_2}{180.0ml}\\\\\text{milli moles of }BaCl_2}={1.42M\times 180.0ml}=256milli mol[/tex]

Thus the millimoles of sodium carbonate the chemist has added to the flask are 256.

In order to calculate the millimoles of sodium carbonate added to the flask, one must rearrange the formula for molarity, convert the volume from milliliters to liters, substitute, solve, then, finally, convert the solution from moles to millimoles. This results in an approximate 255.6mmol of sodium carbonate.

The chemist added 180.0 mL of a 1.42M sodium carbonate (Na2CO3) solution. Molarity (M) is defined as the number of moles of solute (Na2CO3 in this case) per liter of solution. Therefore, to find the number of millimoles, you would use the equation:

M = moles/volume(L)

Rearrange the formula to solve for moles:

moles = M x volume (L)

Next, convert the volume from milliliters to liters: 180.0 mL = 0.180 L. Substituting into the equation gives:

moles = 1.42M x 0.180 L = 0.2556 moles

To convert moles to millimoles, you'll need to know that 1 mole = 1000 millimoles. Therefore, 0.2556 moles x 1000 = 255.6 millimoles rounded to three significant digits.

https://brainly.com/question/31815736

#SPJ3

The question is incomplete, here is the complete question:

In the Minnesota Department of Health set a health risk limit for methanol in groundwater of 4.00 μg/L. Suppose an analytical chemist receives a sample of groundwater with a measured volume of 76.0 mL.

Calculate the maximum mass in milligrams of methanol which the chemist could measure in this sample and still certify that the groundwater from which it came met Minnesota Department of Health standards. Be sure your answer has the correct number of significant digits.

Answer: The risk limit of methanol in the given amount of methanol is [tex]3.04\times 10^{-4}mg[/tex]

Explanation:

We are given:

Risk limit for methanol in groundwater = 4.00 μg/L = 0.004 mg/L    (Conversion factor:  [tex]1mg=1000\mu g[/tex] )

Volume of groundwater that is to be measured = 76.0 mL

We know that:

1 L = 1000 mL

Applying unitary method:

In 1000 mL of groundwater, the risk limit of methanol is 0.004 mg

So, in 76.0 mL of groundwater, the risk limit of methanol will be = [tex]\frac{0.004}{1000}\times 76.0=3.04\times 10^{-4}mg[/tex]

Hence, the risk limit of methanol in the given amount of methanol is [tex]3.04\times 10^{-4}mg[/tex]

Answer:

Density of CO₂ at STP = 1.96 g/L

Explanation:

1 mol of any gas at STP occupies 22.4L of volume.

The rule for the Ideal gases.

Assume 1 mol of CO₂, we know that has 44 grams of mass.

Density = mass / volume

44 g/ 22.4L = 1.96 g/L

Answer: 1.96g/L

Explanation:

1mole of CO2 contains 22.4L at stp.

1mole of CO2 = 12 + ( 2x16) = 12 + 32 = 44g

Density = Mass /volume

Density = 44g /22.4L

Density = 1.96g/L

Answer:

the final temperature T final = 83.863 °C

Explanation:

Assuming that no heat is absorbed from the container , then all the heat absorbed by the water Q water comes from the heat released by the quartz (-Q quatz), since

Q water + Q quatz = Q surroundings =0

denoting w as water and q as quartz then

Q water = mw * cpw * (Tfinal - T initial w)

Q quartz = mq * cpq * (Tfinal - T initial q)

where

m= mass

cp= specific heat capacity at constant pressure

T final = final temperature

T initial w and T initial q = initial temperature of water and quartz respectively

then

mw * cpw * (Tfinal - T initial w) + mq * cpq * (Tfinal - T initial q) = 0

mw * cpw * Tfinal + mq * cpq * Tfinal = mw * cpw *T initial w + mq * cpq * T initial q

Tfinal = (mw * cpw *T initial w+ mq * cpq * T initial q)/(mw * cpw +mq * cpq)

replacing values and assuming cpw= 1 cal/gr°C = 4.186 J/g°C

Tfinal = (200 g * 4.186 J/g°C * 85 °C + 17g * 0.730 J/g°C * 7.2 °C)/(200 g * 4.186 J/g°C + 17g * 0.730 J/g°C) = 83.863 °C

Tfinal = 83.863 °C